Strong circularly polarized luminescence intramolecular excited-state symmetry-breaking charge separation

Trans -1,2-di(1-pyrenylamino)cycloxexane was found to display circularly polarized excimer emission ( g lum = 0.016) both in polar and non-polar solvents that is assigned to charge separation symmetry breaking on the basis of its large transition state dipole moment (12.1 D). Unexpected excited-stat...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2023-06, Vol.59 (51), p.7963-7966
Hauptverfasser:	Álvaro-Martins, Maria João, Billiaux, Chloé, Godard, Pascale, Oda, Reiko, Raffy, Guillaume, Bassani, Dario M
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