Anion vacancy correlated photocatalytic CO to CO conversion over quantum-confined CdS nanorods under visible light
Surface vacancies in II-VI semiconductors have been confirmed as active sites for photocatalytic CO 2 reduction. Here we take quantum-confined CdS nanorod as a model photocatalyst to correlate anion vacancies with photocatalytic CO 2 reduction performance. In terms of electronic structure change, Cd...
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| Veröffentlicht in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2023-02, Vol.11 (8), p.3937-3941 |
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| container_issue | 8 |
| container_start_page | 3937 |
| container_title | Journal of materials chemistry. A, Materials for energy and sustainability |
| container_volume | 11 |
| creator | Guo, Qing Xia, Shu-Guang Xin, Zhi-Kun Wang, Yang Liang, Fei Nan, Xiao-Lei Lin, Zhe-Shuai Li, Xu-Bing Tung, Chen-Ho Wu, Li-Zhu |
| description | Surface vacancies in II-VI semiconductors have been confirmed as active sites for photocatalytic CO
2
reduction. Here we take quantum-confined CdS nanorod as a model photocatalyst to correlate anion vacancies with photocatalytic CO
2
reduction performance. In terms of electronic structure change, CdS nanorods with more surface S vacancies give enhanced CO generation rates, which were confirmed by deliberately introducing S vacancies
via
a post-treatment.
In terms of electronic structure change, surface anion vacancies in II-VI semiconductors could promote CO generation rates, which have been confirmed as active sites for photocatalytic CO
2
reduction. |
| doi_str_mv | 10.1039/d2ta09451g |
| format | Article |
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2
reduction. Here we take quantum-confined CdS nanorod as a model photocatalyst to correlate anion vacancies with photocatalytic CO
2
reduction performance. In terms of electronic structure change, CdS nanorods with more surface S vacancies give enhanced CO generation rates, which were confirmed by deliberately introducing S vacancies
via
a post-treatment.
In terms of electronic structure change, surface anion vacancies in II-VI semiconductors could promote CO generation rates, which have been confirmed as active sites for photocatalytic CO
2
reduction.</description><identifier>ISSN: 2050-7488</identifier><identifier>EISSN: 2050-7496</identifier><identifier>DOI: 10.1039/d2ta09451g</identifier><ispartof>Journal of materials chemistry. A, Materials for energy and sustainability, 2023-02, Vol.11 (8), p.3937-3941</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Guo, Qing</creatorcontrib><creatorcontrib>Xia, Shu-Guang</creatorcontrib><creatorcontrib>Xin, Zhi-Kun</creatorcontrib><creatorcontrib>Wang, Yang</creatorcontrib><creatorcontrib>Liang, Fei</creatorcontrib><creatorcontrib>Nan, Xiao-Lei</creatorcontrib><creatorcontrib>Lin, Zhe-Shuai</creatorcontrib><creatorcontrib>Li, Xu-Bing</creatorcontrib><creatorcontrib>Tung, Chen-Ho</creatorcontrib><creatorcontrib>Wu, Li-Zhu</creatorcontrib><title>Anion vacancy correlated photocatalytic CO to CO conversion over quantum-confined CdS nanorods under visible light</title><title>Journal of materials chemistry. A, Materials for energy and sustainability</title><description>Surface vacancies in II-VI semiconductors have been confirmed as active sites for photocatalytic CO
2
reduction. Here we take quantum-confined CdS nanorod as a model photocatalyst to correlate anion vacancies with photocatalytic CO
2
reduction performance. In terms of electronic structure change, CdS nanorods with more surface S vacancies give enhanced CO generation rates, which were confirmed by deliberately introducing S vacancies
via
a post-treatment.
In terms of electronic structure change, surface anion vacancies in II-VI semiconductors could promote CO generation rates, which have been confirmed as active sites for photocatalytic CO
2
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2
reduction. Here we take quantum-confined CdS nanorod as a model photocatalyst to correlate anion vacancies with photocatalytic CO
2
reduction performance. In terms of electronic structure change, CdS nanorods with more surface S vacancies give enhanced CO generation rates, which were confirmed by deliberately introducing S vacancies
via
a post-treatment.
In terms of electronic structure change, surface anion vacancies in II-VI semiconductors could promote CO generation rates, which have been confirmed as active sites for photocatalytic CO
2
reduction.</abstract><doi>10.1039/d2ta09451g</doi><tpages>5</tpages></addata></record> |
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| identifier | ISSN: 2050-7488 |
| ispartof | Journal of materials chemistry. A, Materials for energy and sustainability, 2023-02, Vol.11 (8), p.3937-3941 |
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| source | Royal Society Of Chemistry Journals 2008- |
| title | Anion vacancy correlated photocatalytic CO to CO conversion over quantum-confined CdS nanorods under visible light |
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