An organic additive assisting with high ionic conduction and dendrite resistance of polymer electrolytes
High-performance polymer electrolytes are desirable for developing solid-state lithium (Li) metal batteries (SSLMBs) with enhanced safety and high energy density; however, their applications are hindered by low ionic conductivity and uncontrolled Li-dendrite growth. Here, a poly(vinylidene fluoride)...
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| Veröffentlicht in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2022-11, Vol.1 (45), p.24269-24279 |
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| creator | Guan, Shundong Wen, Kaihua Liang, Ying Xue, Chuanjiao Liu, Sijie Yu, Jinyao Zhang, Zheng Wu, Xinbin Yuan, Haocheng Lin, Zhiyuan Yu, Haijun Li, Liangliang Nan, Ce-Wen |
| description | High-performance polymer electrolytes are desirable for developing solid-state lithium (Li) metal batteries (SSLMBs) with enhanced safety and high energy density; however, their applications are hindered by low ionic conductivity and uncontrolled Li-dendrite growth. Here, a poly(vinylidene fluoride) (PVDF)-based polymer electrolyte with an organic additive, 2-acrylamido-2-methylpropane sulfonic acid (AMPS), is synthesized. First, AMPS improves the Li
+
conduction by reducing the crystallinity of PVDF and immobilizing the anions. Second, AMPS assists with the formation of a LiF/Li
2
S
x
/Li
2
SO
3
/Li
3
N-rich interface between Li metal and the AMPS-PVDF polymer electrolyte (AP-PE), which effectively suppresses the growth of Li dendrites. Consequently, the AP-PE with a thickness of ∼28 μm shows a high ionic conductivity of 2.2 × 10
−4
S cm
−1
at 26 °C, corresponding to an ultrahigh areal conductance of 78.6 mS cm
−2
. Meanwhile, the AP-PE shows a large Li
+
transference number of ∼0.49, good electrochemical stability against a Li metal anode, and improved cycling stability in LiFePO
4
- and LiCoO
2
-based SSLMBs.
2-Acrylamido-2-methylpropane sulfonic acid (AMPS) is used as an organic additive for poly(vinylidene fluoride) (PVDF)-based polymer electrolytes to assist with the fast Li-ion conduction and formation of a stable interface. |
| doi_str_mv | 10.1039/d2ta04229k |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_d2ta04229k</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2738424870</sourcerecordid><originalsourceid>FETCH-LOGICAL-c211t-b5b27382c13691fcf754ec7da909322cddadf8057bb1d1bf57737e722f0025043</originalsourceid><addsrcrecordid>eNpFkM1LAzEQxYMoWGov3oWAN2F1kt1tNsdSP7HgpZ6XbD52U9ukJqnS_95dK3UuMw9-8x48hC4J3BLI-Z2iSUBBKf84QSMKJWSs4NPT411V52gS4wr6qQCmnI9QN3PYh1Y4K7FQyib7pbGI0cZkXYu_bepwZ9sOWz8g0ju1k6kXWDiFlXYq2KRx0MOHcFJjb_DWr_cbHbBea5lCL5KOF-jMiHXUk789Ru-PD8v5c7Z4e3qZzxaZpISkrCkbyvKKSpJPOTHSsLLQkinBgeeUSqWEMhWUrGmIIo0pGcuZZpQaAFpCkY_R9cF3G_znTsdUr_wuuD6yHowLWlQMeurmQMngYwza1NtgNyLsawL1UGZ9T5ez3zJfe_jqAIcoj9x_2fkPaC9yBQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2738424870</pqid></control><display><type>article</type><title>An organic additive assisting with high ionic conduction and dendrite resistance of polymer electrolytes</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Guan, Shundong ; Wen, Kaihua ; Liang, Ying ; Xue, Chuanjiao ; Liu, Sijie ; Yu, Jinyao ; Zhang, Zheng ; Wu, Xinbin ; Yuan, Haocheng ; Lin, Zhiyuan ; Yu, Haijun ; Li, Liangliang ; Nan, Ce-Wen</creator><creatorcontrib>Guan, Shundong ; Wen, Kaihua ; Liang, Ying ; Xue, Chuanjiao ; Liu, Sijie ; Yu, Jinyao ; Zhang, Zheng ; Wu, Xinbin ; Yuan, Haocheng ; Lin, Zhiyuan ; Yu, Haijun ; Li, Liangliang ; Nan, Ce-Wen</creatorcontrib><description>High-performance polymer electrolytes are desirable for developing solid-state lithium (Li) metal batteries (SSLMBs) with enhanced safety and high energy density; however, their applications are hindered by low ionic conductivity and uncontrolled Li-dendrite growth. Here, a poly(vinylidene fluoride) (PVDF)-based polymer electrolyte with an organic additive, 2-acrylamido-2-methylpropane sulfonic acid (AMPS), is synthesized. First, AMPS improves the Li
+
conduction by reducing the crystallinity of PVDF and immobilizing the anions. Second, AMPS assists with the formation of a LiF/Li
2
S
x
/Li
2
SO
3
/Li
3
N-rich interface between Li metal and the AMPS-PVDF polymer electrolyte (AP-PE), which effectively suppresses the growth of Li dendrites. Consequently, the AP-PE with a thickness of ∼28 μm shows a high ionic conductivity of 2.2 × 10
−4
S cm
−1
at 26 °C, corresponding to an ultrahigh areal conductance of 78.6 mS cm
−2
. Meanwhile, the AP-PE shows a large Li
+
transference number of ∼0.49, good electrochemical stability against a Li metal anode, and improved cycling stability in LiFePO
4
- and LiCoO
2
-based SSLMBs.
2-Acrylamido-2-methylpropane sulfonic acid (AMPS) is used as an organic additive for poly(vinylidene fluoride) (PVDF)-based polymer electrolytes to assist with the fast Li-ion conduction and formation of a stable interface.</description><identifier>ISSN: 2050-7488</identifier><identifier>EISSN: 2050-7496</identifier><identifier>DOI: 10.1039/d2ta04229k</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Anions ; Conduction ; Conductivity ; Dendrites ; Electrochemistry ; Electrolytes ; Ion currents ; Ions ; Lithium ; Polymers ; Polyvinylidene fluorides ; Stability ; Sulfonic acid ; Vinylidene fluoride</subject><ispartof>Journal of materials chemistry. A, Materials for energy and sustainability, 2022-11, Vol.1 (45), p.24269-24279</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c211t-b5b27382c13691fcf754ec7da909322cddadf8057bb1d1bf57737e722f0025043</citedby><cites>FETCH-LOGICAL-c211t-b5b27382c13691fcf754ec7da909322cddadf8057bb1d1bf57737e722f0025043</cites><orcidid>0000-0003-0204-9943 ; 0000-0003-2176-6403 ; 0000-0001-7808-7052 ; 0000-0003-0487-7611</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Guan, Shundong</creatorcontrib><creatorcontrib>Wen, Kaihua</creatorcontrib><creatorcontrib>Liang, Ying</creatorcontrib><creatorcontrib>Xue, Chuanjiao</creatorcontrib><creatorcontrib>Liu, Sijie</creatorcontrib><creatorcontrib>Yu, Jinyao</creatorcontrib><creatorcontrib>Zhang, Zheng</creatorcontrib><creatorcontrib>Wu, Xinbin</creatorcontrib><creatorcontrib>Yuan, Haocheng</creatorcontrib><creatorcontrib>Lin, Zhiyuan</creatorcontrib><creatorcontrib>Yu, Haijun</creatorcontrib><creatorcontrib>Li, Liangliang</creatorcontrib><creatorcontrib>Nan, Ce-Wen</creatorcontrib><title>An organic additive assisting with high ionic conduction and dendrite resistance of polymer electrolytes</title><title>Journal of materials chemistry. A, Materials for energy and sustainability</title><description>High-performance polymer electrolytes are desirable for developing solid-state lithium (Li) metal batteries (SSLMBs) with enhanced safety and high energy density; however, their applications are hindered by low ionic conductivity and uncontrolled Li-dendrite growth. Here, a poly(vinylidene fluoride) (PVDF)-based polymer electrolyte with an organic additive, 2-acrylamido-2-methylpropane sulfonic acid (AMPS), is synthesized. First, AMPS improves the Li
+
conduction by reducing the crystallinity of PVDF and immobilizing the anions. Second, AMPS assists with the formation of a LiF/Li
2
S
x
/Li
2
SO
3
/Li
3
N-rich interface between Li metal and the AMPS-PVDF polymer electrolyte (AP-PE), which effectively suppresses the growth of Li dendrites. Consequently, the AP-PE with a thickness of ∼28 μm shows a high ionic conductivity of 2.2 × 10
−4
S cm
−1
at 26 °C, corresponding to an ultrahigh areal conductance of 78.6 mS cm
−2
. Meanwhile, the AP-PE shows a large Li
+
transference number of ∼0.49, good electrochemical stability against a Li metal anode, and improved cycling stability in LiFePO
4
- and LiCoO
2
-based SSLMBs.
2-Acrylamido-2-methylpropane sulfonic acid (AMPS) is used as an organic additive for poly(vinylidene fluoride) (PVDF)-based polymer electrolytes to assist with the fast Li-ion conduction and formation of a stable interface.</description><subject>Anions</subject><subject>Conduction</subject><subject>Conductivity</subject><subject>Dendrites</subject><subject>Electrochemistry</subject><subject>Electrolytes</subject><subject>Ion currents</subject><subject>Ions</subject><subject>Lithium</subject><subject>Polymers</subject><subject>Polyvinylidene fluorides</subject><subject>Stability</subject><subject>Sulfonic acid</subject><subject>Vinylidene fluoride</subject><issn>2050-7488</issn><issn>2050-7496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpFkM1LAzEQxYMoWGov3oWAN2F1kt1tNsdSP7HgpZ6XbD52U9ukJqnS_95dK3UuMw9-8x48hC4J3BLI-Z2iSUBBKf84QSMKJWSs4NPT411V52gS4wr6qQCmnI9QN3PYh1Y4K7FQyib7pbGI0cZkXYu_bepwZ9sOWz8g0ju1k6kXWDiFlXYq2KRx0MOHcFJjb_DWr_cbHbBea5lCL5KOF-jMiHXUk789Ru-PD8v5c7Z4e3qZzxaZpISkrCkbyvKKSpJPOTHSsLLQkinBgeeUSqWEMhWUrGmIIo0pGcuZZpQaAFpCkY_R9cF3G_znTsdUr_wuuD6yHowLWlQMeurmQMngYwza1NtgNyLsawL1UGZ9T5ez3zJfe_jqAIcoj9x_2fkPaC9yBQ</recordid><startdate>20221122</startdate><enddate>20221122</enddate><creator>Guan, Shundong</creator><creator>Wen, Kaihua</creator><creator>Liang, Ying</creator><creator>Xue, Chuanjiao</creator><creator>Liu, Sijie</creator><creator>Yu, Jinyao</creator><creator>Zhang, Zheng</creator><creator>Wu, Xinbin</creator><creator>Yuan, Haocheng</creator><creator>Lin, Zhiyuan</creator><creator>Yu, Haijun</creator><creator>Li, Liangliang</creator><creator>Nan, Ce-Wen</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7ST</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope><scope>L7M</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0003-0204-9943</orcidid><orcidid>https://orcid.org/0000-0003-2176-6403</orcidid><orcidid>https://orcid.org/0000-0001-7808-7052</orcidid><orcidid>https://orcid.org/0000-0003-0487-7611</orcidid></search><sort><creationdate>20221122</creationdate><title>An organic additive assisting with high ionic conduction and dendrite resistance of polymer electrolytes</title><author>Guan, Shundong ; Wen, Kaihua ; Liang, Ying ; Xue, Chuanjiao ; Liu, Sijie ; Yu, Jinyao ; Zhang, Zheng ; Wu, Xinbin ; Yuan, Haocheng ; Lin, Zhiyuan ; Yu, Haijun ; Li, Liangliang ; Nan, Ce-Wen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c211t-b5b27382c13691fcf754ec7da909322cddadf8057bb1d1bf57737e722f0025043</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Anions</topic><topic>Conduction</topic><topic>Conductivity</topic><topic>Dendrites</topic><topic>Electrochemistry</topic><topic>Electrolytes</topic><topic>Ion currents</topic><topic>Ions</topic><topic>Lithium</topic><topic>Polymers</topic><topic>Polyvinylidene fluorides</topic><topic>Stability</topic><topic>Sulfonic acid</topic><topic>Vinylidene fluoride</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guan, Shundong</creatorcontrib><creatorcontrib>Wen, Kaihua</creatorcontrib><creatorcontrib>Liang, Ying</creatorcontrib><creatorcontrib>Xue, Chuanjiao</creatorcontrib><creatorcontrib>Liu, Sijie</creatorcontrib><creatorcontrib>Yu, Jinyao</creatorcontrib><creatorcontrib>Zhang, Zheng</creatorcontrib><creatorcontrib>Wu, Xinbin</creatorcontrib><creatorcontrib>Yuan, Haocheng</creatorcontrib><creatorcontrib>Lin, Zhiyuan</creatorcontrib><creatorcontrib>Yu, Haijun</creatorcontrib><creatorcontrib>Li, Liangliang</creatorcontrib><creatorcontrib>Nan, Ce-Wen</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guan, Shundong</au><au>Wen, Kaihua</au><au>Liang, Ying</au><au>Xue, Chuanjiao</au><au>Liu, Sijie</au><au>Yu, Jinyao</au><au>Zhang, Zheng</au><au>Wu, Xinbin</au><au>Yuan, Haocheng</au><au>Lin, Zhiyuan</au><au>Yu, Haijun</au><au>Li, Liangliang</au><au>Nan, Ce-Wen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An organic additive assisting with high ionic conduction and dendrite resistance of polymer electrolytes</atitle><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle><date>2022-11-22</date><risdate>2022</risdate><volume>1</volume><issue>45</issue><spage>24269</spage><epage>24279</epage><pages>24269-24279</pages><issn>2050-7488</issn><eissn>2050-7496</eissn><abstract>High-performance polymer electrolytes are desirable for developing solid-state lithium (Li) metal batteries (SSLMBs) with enhanced safety and high energy density; however, their applications are hindered by low ionic conductivity and uncontrolled Li-dendrite growth. Here, a poly(vinylidene fluoride) (PVDF)-based polymer electrolyte with an organic additive, 2-acrylamido-2-methylpropane sulfonic acid (AMPS), is synthesized. First, AMPS improves the Li
+
conduction by reducing the crystallinity of PVDF and immobilizing the anions. Second, AMPS assists with the formation of a LiF/Li
2
S
x
/Li
2
SO
3
/Li
3
N-rich interface between Li metal and the AMPS-PVDF polymer electrolyte (AP-PE), which effectively suppresses the growth of Li dendrites. Consequently, the AP-PE with a thickness of ∼28 μm shows a high ionic conductivity of 2.2 × 10
−4
S cm
−1
at 26 °C, corresponding to an ultrahigh areal conductance of 78.6 mS cm
−2
. Meanwhile, the AP-PE shows a large Li
+
transference number of ∼0.49, good electrochemical stability against a Li metal anode, and improved cycling stability in LiFePO
4
- and LiCoO
2
-based SSLMBs.
2-Acrylamido-2-methylpropane sulfonic acid (AMPS) is used as an organic additive for poly(vinylidene fluoride) (PVDF)-based polymer electrolytes to assist with the fast Li-ion conduction and formation of a stable interface.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2ta04229k</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0003-0204-9943</orcidid><orcidid>https://orcid.org/0000-0003-2176-6403</orcidid><orcidid>https://orcid.org/0000-0001-7808-7052</orcidid><orcidid>https://orcid.org/0000-0003-0487-7611</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2050-7488 |
| ispartof | Journal of materials chemistry. A, Materials for energy and sustainability, 2022-11, Vol.1 (45), p.24269-24279 |
| issn | 2050-7488 2050-7496 |
| language | eng |
| recordid | cdi_rsc_primary_d2ta04229k |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Anions Conduction Conductivity Dendrites Electrochemistry Electrolytes Ion currents Ions Lithium Polymers Polyvinylidene fluorides Stability Sulfonic acid Vinylidene fluoride |
| title | An organic additive assisting with high ionic conduction and dendrite resistance of polymer electrolytes |
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