Quantitative evaluation of the actual hydrogen atom donating activities of O-H bonds in phenols: structure-activity relationship

The H-donating activity of phenol and the H-abstraction activity of phenol radicals have been extensively studied. In this article, the second-order rate constants of 25 hydrogen atom transfer (HAT) reactions between phenols and PINO and DPPH radicals in acetonitrile at 298 K were studied. Thermo-ki...

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Veröffentlicht in:	RSC advances 2023-01, Vol.13 (5), p.3295-335
Hauptverfasser:	Fu, Yan-Hua, Zhang, Yanwei, Wang, Fang, Zhao, Ling, Shen, Guang-Bin, Zhu, Xiao-Qing
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Chemistry Hydrogen atoms Kinetic equations Magnetic methods Parameters Phenols Radicals Rate constants
Online-Zugang:	Volltext
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