integration of a cocatalyst and heterojunction to a WO photoanode with enhanced photoelectrochemical performance phosphatization

A novel ternary NiP x /NiWO 4 /WO 3 photoanode with the cooperation effect of a heterojunction and cocatalyst was successfully fabricated by an in situ phosphatization process. The NiWO 4 layer forms a heterojunction with WO 3 to improve the separation and transfer of electron-hole pairs. NiP x acts...

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Veröffentlicht in:New journal of chemistry 2023-01, Vol.47 (4), p.162-1624
Hauptverfasser: Zhan, Faqi, Zhao, Haiyan, Wen, Guochang, Ma, Zhiqing, Liu, Yisi, Zhu, Min, Zheng, Yuehong, Chen, Dalin, La, Peiqing
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container_end_page 1624
container_issue 4
container_start_page 162
container_title New journal of chemistry
container_volume 47
creator Zhan, Faqi
Zhao, Haiyan
Wen, Guochang
Ma, Zhiqing
Liu, Yisi
Zhu, Min
Zheng, Yuehong
Chen, Dalin
La, Peiqing
description A novel ternary NiP x /NiWO 4 /WO 3 photoanode with the cooperation effect of a heterojunction and cocatalyst was successfully fabricated by an in situ phosphatization process. The NiWO 4 layer forms a heterojunction with WO 3 to improve the separation and transfer of electron-hole pairs. NiP x acts as a cocatalyst for accelerating the surface water oxidation reaction. A 2.55-fold improvement in photocurrent density at 1.23 V vs. RHE was achieved compared with the pristine WO 3 film. In situ integration of a cocatalyst and heterojunction to a WO 3 photoanode with enhanced photoelectrochemical performance via phosphatization.
doi_str_mv 10.1039/d2nj04818c
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title integration of a cocatalyst and heterojunction to a WO photoanode with enhanced photoelectrochemical performance phosphatization
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