Rh()-catalyzed site-selective hydroacylation of alkenyl-bearing allylic alcohols with non-chelating aldehydes controlled by generated carbonyl group

A rhodium( i )-catalyzed regioselective hydroacylation of alkenyl-bearing allylic alcohols with simple aldehydes for the preparation of diverse 1,5-diketones is described. Mechanistic investigation suggests that this transformation might proceed through redox isomerization of the allylic alcohol fol...

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Veröffentlicht in:	New journal of chemistry 2022-10, Vol.46 (41), p.1982-1987
Hauptverfasser:	Wang, Fu-Gang, Gong, Fei-Yuan, Cao, Juan, Wang, Ji-Cong, Tian, Kai-Qiang, Zhao, Jinbo, Li, Hong-Shuang
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