Atom-economical, catalyst-free hydrosulfonation of densely functionalized alkenes: access to oxindole-containing sulfones
An atom-economical hydrosulfonation of densely functionalized alkenes under catalyst-free conditions is described. Alkenes possessing a hydroxy-oxindole moiety underwent hydrosulfonation on treatment with arylsulfinic acids in green media to afford the resulting sulfones in 72-86% yields with excell...
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| Veröffentlicht in: | New journal of chemistry 2022-07, Vol.46 (27), p.1295-1299 |
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| container_end_page | 1299 |
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| container_issue | 27 |
| container_start_page | 1295 |
| container_title | New journal of chemistry |
| container_volume | 46 |
| creator | Dabaria, Kamlesh Kumar Bai, Rekha Jat, Pooja Kumari Badsara, Satpal Singh |
| description | An atom-economical hydrosulfonation of densely functionalized alkenes under catalyst-free conditions is described. Alkenes possessing a hydroxy-oxindole moiety underwent hydrosulfonation on treatment with arylsulfinic acids in green media to afford the resulting sulfones in 72-86% yields with excellent diastereoselectivity.
A facile, atom-economical, catalyst-free protocol for the hydrosulfonation of densely functionalized alkenes with sulfinic acids in an environmentally benign solvent system at ambient temperature is described. |
| doi_str_mv | 10.1039/d2nj02462d |
| format | Article |
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A facile, atom-economical, catalyst-free protocol for the hydrosulfonation of densely functionalized alkenes with sulfinic acids in an environmentally benign solvent system at ambient temperature is described.</description><subject>Alkenes</subject><subject>Catalysts</subject><subject>Stereoselectivity</subject><subject>Sulfones</subject><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpFkE1LxDAQhoMouK5evAsBb2I0Sduk8bbs-smiFz2XNJlq126yNilYf71dK3qal-HhZeZB6JjRC0YTdWm5W1GeCm530IQlQhHFBdsdMktTQrNU7KODEFaUMiYFm6B-Fv2agPHOr2ujm3NsdNRNHyKpWgD81tvWh66pvNOx9g77CltwAZoeV50z251u6i-wWDfv4CBcYW0MhICjx_6zdtY3QIb-qGtXu1c8lkE4RHuVbgIc_c4perm5fp7fkeXT7f18tiSGMxYJl4nJlTYqp1wCzWwKEkrKgMuyzE1uRKYyqSrgopRC24FQLNFKpxxsxWwyRadj76b1Hx2EWKx81w5Hh4KLXMqMUZEN1NlImeHd0EJVbNp6rdu-YLTYqi0W_PHhR-1igE9GuA3mj_tXn3wDYyR4xA</recordid><startdate>20220711</startdate><enddate>20220711</enddate><creator>Dabaria, Kamlesh Kumar</creator><creator>Bai, Rekha</creator><creator>Jat, Pooja Kumari</creator><creator>Badsara, Satpal Singh</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>H9R</scope><scope>JG9</scope><scope>KA0</scope><orcidid>https://orcid.org/0000-0002-9839-5113</orcidid></search><sort><creationdate>20220711</creationdate><title>Atom-economical, catalyst-free hydrosulfonation of densely functionalized alkenes: access to oxindole-containing sulfones</title><author>Dabaria, Kamlesh Kumar ; Bai, Rekha ; Jat, Pooja Kumari ; Badsara, Satpal Singh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c211t-273c89ac98027e05d4e7eb01e27bb8c8c659579fe26b76ad05d913a9a42edf1d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Alkenes</topic><topic>Catalysts</topic><topic>Stereoselectivity</topic><topic>Sulfones</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dabaria, Kamlesh Kumar</creatorcontrib><creatorcontrib>Bai, Rekha</creatorcontrib><creatorcontrib>Jat, Pooja Kumari</creatorcontrib><creatorcontrib>Badsara, Satpal Singh</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Illustrata: Natural Sciences</collection><collection>Materials Research Database</collection><collection>ProQuest Illustrata: Technology Collection</collection><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dabaria, Kamlesh Kumar</au><au>Bai, Rekha</au><au>Jat, Pooja Kumari</au><au>Badsara, Satpal Singh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Atom-economical, catalyst-free hydrosulfonation of densely functionalized alkenes: access to oxindole-containing sulfones</atitle><jtitle>New journal of chemistry</jtitle><date>2022-07-11</date><risdate>2022</risdate><volume>46</volume><issue>27</issue><spage>1295</spage><epage>1299</epage><pages>1295-1299</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>An atom-economical hydrosulfonation of densely functionalized alkenes under catalyst-free conditions is described. Alkenes possessing a hydroxy-oxindole moiety underwent hydrosulfonation on treatment with arylsulfinic acids in green media to afford the resulting sulfones in 72-86% yields with excellent diastereoselectivity.
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| fulltext | fulltext |
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| ispartof | New journal of chemistry, 2022-07, Vol.46 (27), p.1295-1299 |
| issn | 1144-0546 1369-9261 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Alkenes Catalysts Stereoselectivity Sulfones |
| title | Atom-economical, catalyst-free hydrosulfonation of densely functionalized alkenes: access to oxindole-containing sulfones |
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