Merging the AuCu- and BaAl-based structure motifs: flux-assisted synthesis, crystal, and electronic structure of CaPtXP phosphide platinides (X = Al, Ti, and Zn)

Three quaternary phosphide platinides, Ca 2 Pt 7 AlP 3.00(4) , Ca 2 Pt 7 TiP 3.24(4) , and Ca 2 Pt 7 ZnP 2.78(2) , were synthesized by a high-temperature technique using lead as a flux. According to the single-crystal diffraction data, they are isotypic and crystallize in the tetragonal space group...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2022-12, Vol.51 (48), p.18583-18592
Hauptverfasser: Makhaneva, Anastasiya Yu, Zakharova, Elena Yu, Nesterenko, Sergey N, Lyssenko, Konstantin A, Kuznetsov, Alexey N
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