Heterolytic cleavage of a Si-H bond by a metal-ligand cooperation of a cationic iridium amido complex and hydrosilylation of aldehydes

Heterolytic cleavage of a Si-H bond was achieved mediated by a metal-ligand cooperation of a cationic iridium amido complex. The reaction was applied to the catalytic hydrosilylation of benzaldehyde and its derivatives, affording the corresponding hydrosilylated products in moderate to good yields....

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2022-08, Vol.51 (34), p.12781-12785
Hauptverfasser:	Iizuka, Kosuke, Nakajima, Yumiko, Sato, Kazuhiko
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Benzaldehyde Cations Cleavage Cooperation Hydrogen bonds Hydrosilylation Iridium Ligands
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	12785
container_issue	34
container_start_page	12781
container_title	Dalton transactions : an international journal of inorganic chemistry
container_volume	51
creator	Iizuka, Kosuke Nakajima, Yumiko Sato, Kazuhiko
description	Heterolytic cleavage of a Si-H bond was achieved mediated by a metal-ligand cooperation of a cationic iridium amido complex. The reaction was applied to the catalytic hydrosilylation of benzaldehyde and its derivatives, affording the corresponding hydrosilylated products in moderate to good yields. Heterolytic cleavage of a Si-H bond was achieved mediated by a metal-ligand cooperation of a cationic iridium amido complex. The reaction was applied to the catalytic hydrosilylation of benzaldehyde and its derivatives.
doi_str_mv	10.1039/d2dt01733d
format	Article
fullrecord	<record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_d2dt01733d</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2700638555</sourcerecordid><originalsourceid>FETCH-LOGICAL-c269t-442d24adb7c666ea21c9e41cfb17433fab3b61947d0446fdf3bce8a795c529083</originalsourceid><addsrcrecordid>eNpdkU9Lw0AQxYMoWKsX70LAiwjR_ZdNcpRWrVDwYD2Hze6kbtl0624i5gv4ud020oKneTP85jHDi6JLjO4wosW9IqpFOKNUHUUjzLIsKQhlx3tN-Gl05v0KIUJQSkbRzwxacNb0rZaxNCC-xBJiW8ciftPJLK7sWsVVH9oGWmESo5ciTKS1G3Ci1XY9wHKng4d2WumuiUWjlQ1cszHwHW93PnrlrNemN4c9oyCMwZ9HJ7UwHi7-6jh6f3pcTGbJ_PX5ZfIwTyThRZswRhRhQlWZ5JyDIFgWwLCsK5wxSmtR0YrjgmUKMcZrVdNKQi6yIpUpKVBOx9HN4Ltx9rMD35aN9hKMEWuwnS9JhhCneZqmAb3-h65s59bhukBhjhjJ6dbwdqBk-M07qMuN041wfYlRuY2knJLpYhfJNMBXA-y83HOHyOgvhXOJUA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2716042838</pqid></control><display><type>article</type><title>Heterolytic cleavage of a Si-H bond by a metal-ligand cooperation of a cationic iridium amido complex and hydrosilylation of aldehydes</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Iizuka, Kosuke ; Nakajima, Yumiko ; Sato, Kazuhiko</creator><creatorcontrib>Iizuka, Kosuke ; Nakajima, Yumiko ; Sato, Kazuhiko</creatorcontrib><description>Heterolytic cleavage of a Si-H bond was achieved mediated by a metal-ligand cooperation of a cationic iridium amido complex. The reaction was applied to the catalytic hydrosilylation of benzaldehyde and its derivatives, affording the corresponding hydrosilylated products in moderate to good yields. Heterolytic cleavage of a Si-H bond was achieved mediated by a metal-ligand cooperation of a cationic iridium amido complex. The reaction was applied to the catalytic hydrosilylation of benzaldehyde and its derivatives.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d2dt01733d</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Aldehydes ; Benzaldehyde ; Cations ; Cleavage ; Cooperation ; Hydrogen bonds ; Hydrosilylation ; Iridium ; Ligands</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2022-08, Vol.51 (34), p.12781-12785</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c269t-442d24adb7c666ea21c9e41cfb17433fab3b61947d0446fdf3bce8a795c529083</cites><orcidid>0000-0001-6813-8733</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Iizuka, Kosuke</creatorcontrib><creatorcontrib>Nakajima, Yumiko</creatorcontrib><creatorcontrib>Sato, Kazuhiko</creatorcontrib><title>Heterolytic cleavage of a Si-H bond by a metal-ligand cooperation of a cationic iridium amido complex and hydrosilylation of aldehydes</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>Heterolytic cleavage of a Si-H bond was achieved mediated by a metal-ligand cooperation of a cationic iridium amido complex. The reaction was applied to the catalytic hydrosilylation of benzaldehyde and its derivatives, affording the corresponding hydrosilylated products in moderate to good yields. Heterolytic cleavage of a Si-H bond was achieved mediated by a metal-ligand cooperation of a cationic iridium amido complex. The reaction was applied to the catalytic hydrosilylation of benzaldehyde and its derivatives.</description><subject>Aldehydes</subject><subject>Benzaldehyde</subject><subject>Cations</subject><subject>Cleavage</subject><subject>Cooperation</subject><subject>Hydrogen bonds</subject><subject>Hydrosilylation</subject><subject>Iridium</subject><subject>Ligands</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpdkU9Lw0AQxYMoWKsX70LAiwjR_ZdNcpRWrVDwYD2Hze6kbtl0624i5gv4ud020oKneTP85jHDi6JLjO4wosW9IqpFOKNUHUUjzLIsKQhlx3tN-Gl05v0KIUJQSkbRzwxacNb0rZaxNCC-xBJiW8ciftPJLK7sWsVVH9oGWmESo5ciTKS1G3Ci1XY9wHKng4d2WumuiUWjlQ1cszHwHW93PnrlrNemN4c9oyCMwZ9HJ7UwHi7-6jh6f3pcTGbJ_PX5ZfIwTyThRZswRhRhQlWZ5JyDIFgWwLCsK5wxSmtR0YrjgmUKMcZrVdNKQi6yIpUpKVBOx9HN4Ltx9rMD35aN9hKMEWuwnS9JhhCneZqmAb3-h65s59bhukBhjhjJ6dbwdqBk-M07qMuN041wfYlRuY2knJLpYhfJNMBXA-y83HOHyOgvhXOJUA</recordid><startdate>20220830</startdate><enddate>20220830</enddate><creator>Iizuka, Kosuke</creator><creator>Nakajima, Yumiko</creator><creator>Sato, Kazuhiko</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-6813-8733</orcidid></search><sort><creationdate>20220830</creationdate><title>Heterolytic cleavage of a Si-H bond by a metal-ligand cooperation of a cationic iridium amido complex and hydrosilylation of aldehydes</title><author>Iizuka, Kosuke ; Nakajima, Yumiko ; Sato, Kazuhiko</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c269t-442d24adb7c666ea21c9e41cfb17433fab3b61947d0446fdf3bce8a795c529083</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aldehydes</topic><topic>Benzaldehyde</topic><topic>Cations</topic><topic>Cleavage</topic><topic>Cooperation</topic><topic>Hydrogen bonds</topic><topic>Hydrosilylation</topic><topic>Iridium</topic><topic>Ligands</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Iizuka, Kosuke</creatorcontrib><creatorcontrib>Nakajima, Yumiko</creatorcontrib><creatorcontrib>Sato, Kazuhiko</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Iizuka, Kosuke</au><au>Nakajima, Yumiko</au><au>Sato, Kazuhiko</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Heterolytic cleavage of a Si-H bond by a metal-ligand cooperation of a cationic iridium amido complex and hydrosilylation of aldehydes</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2022-08-30</date><risdate>2022</risdate><volume>51</volume><issue>34</issue><spage>12781</spage><epage>12785</epage><pages>12781-12785</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Heterolytic cleavage of a Si-H bond was achieved mediated by a metal-ligand cooperation of a cationic iridium amido complex. The reaction was applied to the catalytic hydrosilylation of benzaldehyde and its derivatives, affording the corresponding hydrosilylated products in moderate to good yields. Heterolytic cleavage of a Si-H bond was achieved mediated by a metal-ligand cooperation of a cationic iridium amido complex. The reaction was applied to the catalytic hydrosilylation of benzaldehyde and its derivatives.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2dt01733d</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0001-6813-8733</orcidid></addata></record>
fulltext	fulltext
identifier	ISSN: 1477-9226
ispartof	Dalton transactions : an international journal of inorganic chemistry, 2022-08, Vol.51 (34), p.12781-12785
issn	1477-9226 1477-9234
language	eng
recordid	cdi_rsc_primary_d2dt01733d
source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Aldehydes Benzaldehyde Cations Cleavage Cooperation Hydrogen bonds Hydrosilylation Iridium Ligands
title	Heterolytic cleavage of a Si-H bond by a metal-ligand cooperation of a cationic iridium amido complex and hydrosilylation of aldehydes
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-02T08%3A49%3A09IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_rsc_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Heterolytic%20cleavage%20of%20a%20Si-H%20bond%20by%20a%20metal-ligand%20cooperation%20of%20a%20cationic%20iridium%20amido%20complex%20and%20hydrosilylation%20of%20aldehydes&rft.jtitle=Dalton%20transactions%20:%20an%20international%20journal%20of%20inorganic%20chemistry&rft.au=Iizuka,%20Kosuke&rft.date=2022-08-30&rft.volume=51&rft.issue=34&rft.spage=12781&rft.epage=12785&rft.pages=12781-12785&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/d2dt01733d&rft_dat=%3Cproquest_rsc_p%3E2700638555%3C/proquest_rsc_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2716042838&rft_id=info:pmid/&rfr_iscdi=true