Substitution of Hyp (Hyp = Si(SiMe)) at metalloid [Ge(Hyp)] clusters using phosphine stabilized Au()Cl
We present two new intermetalloid cluster compounds [( n Bu 3 P)AuGe 9 (Hyp) 2 Au(P n Bu 3 )] 2 ( 1 ) and [Au(iPr 2 POC 6 H 4 OPiPr 2 )AuGe 9 (Hyp) 2 ] 2 ( 2 ) which are obtained from the reaction of KGe 9 (Hyp) 3 (Hyp = Si(SiMe 3 ) 3 ) with the respective Au( i ) phosphine precursors. The products...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2022-09, Vol.51 (37), p.1427-14213 |
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| container_end_page | 14213 |
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| container_issue | 37 |
| container_start_page | 1427 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 51 |
| creator | Gienger, Christian Schnepf, Andreas |
| description | We present two new intermetalloid cluster compounds [(
n
Bu
3
P)AuGe
9
(Hyp)
2
Au(P
n
Bu
3
)]
2
(
1
) and [Au(iPr
2
POC
6
H
4
OPiPr
2
)AuGe
9
(Hyp)
2
]
2
(
2
) which are obtained from the reaction of KGe
9
(Hyp)
3
(Hyp = Si(SiMe
3
)
3
) with the respective Au(
i
) phosphine precursors. The products are characterized
via
X-ray crystal structure analysis and the reaction course is analysed
via
NMR spectroscopy. We also show that in the resulting compound
1
the hypersilyl substituents can be reintroduced
via
the reaction with Hyp-Cl to obtain
n
Bu
3
PAuGe
9
(Hyp)
3
.
The reaction of [Ge
9
(Hyp)
3
]
−
with (
n
Bu
3
P)AuCl leads in the presence of free
n
Bu
3
P to [(
n
Bu
3
P)AuGe
9
(Hyp)
2
Au(P
n
Bu
3
)]
2
(Hyp = Si(SiMe
3
)
3
), providing further insight into the reaction mechanism of this build-up reaction. |
| doi_str_mv | 10.1039/d2dt01665f |
| format | Article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_d2dt01665f</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>d2dt01665f</sourcerecordid><originalsourceid>FETCH-LOGICAL-r107t-609f89864fea36621a3ba146f79316e81ddda05a7fd2ab9025e08f8bc02c78893</originalsourceid><addsrcrecordid>eNpFkDtPwzAYRS0EEqWwsCN9YzIE_Ej8GBiqqLRIRQyBCaHKiW1qlCZR7Azl16MKBMu9Z7g6w0XomuBbgpm6M9RETDgv3AmakVyITFGWn_4x5efoIoRPjCnFBZ0hV011iD5O0fcd9A7WhwGSY9xD5ZPKP9k0BR1hb6Nu294beFvZ4yB9h6adQrRjgCn47gOGXR-Gne8shKhr3_ova2AxJWnZXqIzp9tgr357jl4fli_lOts8rx7LxSYbCRYx41g5qSTPndWMc0o0qzXJuROKEW4lMcZoXGjhDNW1wrSwWDpZN5g2QkrF5ujmxzuGZjuMfq_Hw_b_FPYNpq9Uhg</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Substitution of Hyp (Hyp = Si(SiMe)) at metalloid [Ge(Hyp)] clusters using phosphine stabilized Au()Cl</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Gienger, Christian ; Schnepf, Andreas</creator><creatorcontrib>Gienger, Christian ; Schnepf, Andreas</creatorcontrib><description>We present two new intermetalloid cluster compounds [(
n
Bu
3
P)AuGe
9
(Hyp)
2
Au(P
n
Bu
3
)]
2
(
1
) and [Au(iPr
2
POC
6
H
4
OPiPr
2
)AuGe
9
(Hyp)
2
]
2
(
2
) which are obtained from the reaction of KGe
9
(Hyp)
3
(Hyp = Si(SiMe
3
)
3
) with the respective Au(
i
) phosphine precursors. The products are characterized
via
X-ray crystal structure analysis and the reaction course is analysed
via
NMR spectroscopy. We also show that in the resulting compound
1
the hypersilyl substituents can be reintroduced
via
the reaction with Hyp-Cl to obtain
n
Bu
3
PAuGe
9
(Hyp)
3
.
The reaction of [Ge
9
(Hyp)
3
]
−
with (
n
Bu
3
P)AuCl leads in the presence of free
n
Bu
3
P to [(
n
Bu
3
P)AuGe
9
(Hyp)
2
Au(P
n
Bu
3
)]
2
(Hyp = Si(SiMe
3
)
3
), providing further insight into the reaction mechanism of this build-up reaction.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d2dt01665f</identifier><language>eng</language><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2022-09, Vol.51 (37), p.1427-14213</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Gienger, Christian</creatorcontrib><creatorcontrib>Schnepf, Andreas</creatorcontrib><title>Substitution of Hyp (Hyp = Si(SiMe)) at metalloid [Ge(Hyp)] clusters using phosphine stabilized Au()Cl</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>We present two new intermetalloid cluster compounds [(
n
Bu
3
P)AuGe
9
(Hyp)
2
Au(P
n
Bu
3
)]
2
(
1
) and [Au(iPr
2
POC
6
H
4
OPiPr
2
)AuGe
9
(Hyp)
2
]
2
(
2
) which are obtained from the reaction of KGe
9
(Hyp)
3
(Hyp = Si(SiMe
3
)
3
) with the respective Au(
i
) phosphine precursors. The products are characterized
via
X-ray crystal structure analysis and the reaction course is analysed
via
NMR spectroscopy. We also show that in the resulting compound
1
the hypersilyl substituents can be reintroduced
via
the reaction with Hyp-Cl to obtain
n
Bu
3
PAuGe
9
(Hyp)
3
.
The reaction of [Ge
9
(Hyp)
3
]
−
with (
n
Bu
3
P)AuCl leads in the presence of free
n
Bu
3
P to [(
n
Bu
3
P)AuGe
9
(Hyp)
2
Au(P
n
Bu
3
)]
2
(Hyp = Si(SiMe
3
)
3
), providing further insight into the reaction mechanism of this build-up reaction.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNpFkDtPwzAYRS0EEqWwsCN9YzIE_Ej8GBiqqLRIRQyBCaHKiW1qlCZR7Azl16MKBMu9Z7g6w0XomuBbgpm6M9RETDgv3AmakVyITFGWn_4x5efoIoRPjCnFBZ0hV011iD5O0fcd9A7WhwGSY9xD5ZPKP9k0BR1hb6Nu294beFvZ4yB9h6adQrRjgCn47gOGXR-Gne8shKhr3_ova2AxJWnZXqIzp9tgr357jl4fli_lOts8rx7LxSYbCRYx41g5qSTPndWMc0o0qzXJuROKEW4lMcZoXGjhDNW1wrSwWDpZN5g2QkrF5ujmxzuGZjuMfq_Hw_b_FPYNpq9Uhg</recordid><startdate>20220926</startdate><enddate>20220926</enddate><creator>Gienger, Christian</creator><creator>Schnepf, Andreas</creator><scope/></search><sort><creationdate>20220926</creationdate><title>Substitution of Hyp (Hyp = Si(SiMe)) at metalloid [Ge(Hyp)] clusters using phosphine stabilized Au()Cl</title><author>Gienger, Christian ; Schnepf, Andreas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-r107t-609f89864fea36621a3ba146f79316e81ddda05a7fd2ab9025e08f8bc02c78893</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gienger, Christian</creatorcontrib><creatorcontrib>Schnepf, Andreas</creatorcontrib><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gienger, Christian</au><au>Schnepf, Andreas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Substitution of Hyp (Hyp = Si(SiMe)) at metalloid [Ge(Hyp)] clusters using phosphine stabilized Au()Cl</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2022-09-26</date><risdate>2022</risdate><volume>51</volume><issue>37</issue><spage>1427</spage><epage>14213</epage><pages>1427-14213</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>We present two new intermetalloid cluster compounds [(
n
Bu
3
P)AuGe
9
(Hyp)
2
Au(P
n
Bu
3
)]
2
(
1
) and [Au(iPr
2
POC
6
H
4
OPiPr
2
)AuGe
9
(Hyp)
2
]
2
(
2
) which are obtained from the reaction of KGe
9
(Hyp)
3
(Hyp = Si(SiMe
3
)
3
) with the respective Au(
i
) phosphine precursors. The products are characterized
via
X-ray crystal structure analysis and the reaction course is analysed
via
NMR spectroscopy. We also show that in the resulting compound
1
the hypersilyl substituents can be reintroduced
via
the reaction with Hyp-Cl to obtain
n
Bu
3
PAuGe
9
(Hyp)
3
.
The reaction of [Ge
9
(Hyp)
3
]
−
with (
n
Bu
3
P)AuCl leads in the presence of free
n
Bu
3
P to [(
n
Bu
3
P)AuGe
9
(Hyp)
2
Au(P
n
Bu
3
)]
2
(Hyp = Si(SiMe
3
)
3
), providing further insight into the reaction mechanism of this build-up reaction.</abstract><doi>10.1039/d2dt01665f</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2022-09, Vol.51 (37), p.1427-14213 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_rsc_primary_d2dt01665f |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Substitution of Hyp (Hyp = Si(SiMe)) at metalloid [Ge(Hyp)] clusters using phosphine stabilized Au()Cl |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-19T20%3A35%3A22IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-rsc&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Substitution%20of%20Hyp%20(Hyp%20=%20Si(SiMe))%20at%20metalloid%20%5BGe(Hyp)%5D%20clusters%20using%20phosphine%20stabilized%20Au()Cl&rft.jtitle=Dalton%20transactions%20:%20an%20international%20journal%20of%20inorganic%20chemistry&rft.au=Gienger,%20Christian&rft.date=2022-09-26&rft.volume=51&rft.issue=37&rft.spage=1427&rft.epage=14213&rft.pages=1427-14213&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/d2dt01665f&rft_dat=%3Crsc%3Ed2dt01665f%3C/rsc%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |