Alkane C-H activation and ligand exchange on silica supported d metal alkylidenes: relevance to alkane metathesis

In this work, we study the ligand exchange process between an alkane and a series of silica supported metal alkylidenes, which may occur by different pathways: C-H addition, σ-bond metathesis, and α-H abstraction. The results indicate that the α-H abstraction pathway is the preferred one, regardless...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2022-04, Vol.51 (16), p.6416-6426
Hauptverfasser:	Núñez-Zarur, Francisco, Díaz López, Estefanía, Restrepo, Albeiro
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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