Mesoporous TiO layer suppresses ion accumulation in perovskite solar cells

Ion accumulation in perovskite solar cells can be highly suppressed by a mesoporous TiO 2 layer. This is evidenced by the decrease of the ion-related electrostatic potential with increasing the thickness of the mesoporous layer, accounted for by the electron population in the shallow trap states of...

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Veröffentlicht in:Physical chemistry chemical physics : PCCP 2022-09, Vol.24 (35), p.2689-2693
Hauptverfasser: Miao, Shaoshuai, Yuan, Shuai, Zhu, Dongping, Cai, Qingbin, Wang, Hao-Yi, Wang, Yi, Qin, Yujun, Ai, Xi-Cheng
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container_issue 35
container_start_page 2689
container_title Physical chemistry chemical physics : PCCP
container_volume 24
creator Miao, Shaoshuai
Yuan, Shuai
Zhu, Dongping
Cai, Qingbin
Wang, Hao-Yi
Wang, Yi
Qin, Yujun
Ai, Xi-Cheng
description Ion accumulation in perovskite solar cells can be highly suppressed by a mesoporous TiO 2 layer. This is evidenced by the decrease of the ion-related electrostatic potential with increasing the thickness of the mesoporous layer, accounted for by the electron population in the shallow trap states of the TiO 2 nanocrystals. The TiO 2 -nanoparticle scaffold suppresses ion accumulation in mesoporous perovskite solar cells by reducing the electrostatic interaction between the conductive substrate and the perovskite active layer.
doi_str_mv 10.1039/d2cp02037h
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title Mesoporous TiO layer suppresses ion accumulation in perovskite solar cells
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