Self-assembly of [Sn(OPMe)(CFSO)] metallocyclic Sn() hexamer stacks with CF-lined channel interiors
[Sn(OPMe 3 ) 3 (CF 3 SO 3 ) 2 ] 6 ( 1 ) self-assembles to form a highly unusual hexagonal metallocyclic array with bridging CF 3 SO 3 − groups. The discrete hexamers stack along the c -axis to form hydrophobic CF 3 -lined channels with an F F distance across the channel diameter of 0.8 nm. This Sn(...
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| Veröffentlicht in: | CrystEngComm 2022-09, Vol.24 (35), p.6137-614 |
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| container_issue | 35 |
| container_start_page | 6137 |
| container_title | CrystEngComm |
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| creator | Cairns, Kelsey R King, Rhys P Levason, William Reid, Gillian |
| description | [Sn(OPMe
3
)
3
(CF
3
SO
3
)
2
]
6
(
1
) self-assembles to form a highly unusual hexagonal metallocyclic array with bridging CF
3
SO
3
−
groups. The discrete hexamers stack along the
c
-axis to form hydrophobic CF
3
-lined channels with an F F distance across the channel diameter of 0.8 nm. This Sn(
ii
) complex is different from its Pb(
ii
) analogue, which instead forms a discrete, doubly CF
3
SO
3
-bridged dimer of formula, [{Pb(OPMe
3
)
3
(CF
3
SO
3
)}
2
(μ-CF
3
SO
3
)
2
] (
3
).
The preparation, spectroscopic and structural characterisation of a [Sn(OPMe
3
)
3
(CF
3
SO
3
)
2
]
6
, a Sn(
ii
)-based metallocyclic hexamer, containing hydrophobic CF
3
-lined 8.0 Å diameter channels is reported. |
| doi_str_mv | 10.1039/d2ce01029a |
| format | Article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_d2ce01029a</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>d2ce01029a</sourcerecordid><originalsourceid>FETCH-rsc_primary_d2ce01029a3</originalsourceid><addsrcrecordid>eNqFzjsLwjAUQOEgCD4Xd-GO7VBNrBQ7F4uLVKibSInxlkbTVHIL2n-vg-DodIZvOYzNBF8IHsbL60ohF3wVyx4binUUBRsehgM2IrpxLtZC8CFTOZoykERYX0wHTQmn3HrZYY--l6R55p-hxlYa06hOGa3goz5U-JI1OqBWqjvBU7cVJGlgtMUrqEpaiwa0bdHpxtGE9UtpCKffjtk83R6TXeBIFQ-na-m64ncb_vM3jpVD3w</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Self-assembly of [Sn(OPMe)(CFSO)] metallocyclic Sn() hexamer stacks with CF-lined channel interiors</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Cairns, Kelsey R ; King, Rhys P ; Levason, William ; Reid, Gillian</creator><creatorcontrib>Cairns, Kelsey R ; King, Rhys P ; Levason, William ; Reid, Gillian</creatorcontrib><description>[Sn(OPMe
3
)
3
(CF
3
SO
3
)
2
]
6
(
1
) self-assembles to form a highly unusual hexagonal metallocyclic array with bridging CF
3
SO
3
−
groups. The discrete hexamers stack along the
c
-axis to form hydrophobic CF
3
-lined channels with an F F distance across the channel diameter of 0.8 nm. This Sn(
ii
) complex is different from its Pb(
ii
) analogue, which instead forms a discrete, doubly CF
3
SO
3
-bridged dimer of formula, [{Pb(OPMe
3
)
3
(CF
3
SO
3
)}
2
(μ-CF
3
SO
3
)
2
] (
3
).
The preparation, spectroscopic and structural characterisation of a [Sn(OPMe
3
)
3
(CF
3
SO
3
)
2
]
6
, a Sn(
ii
)-based metallocyclic hexamer, containing hydrophobic CF
3
-lined 8.0 Å diameter channels is reported.</description><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/d2ce01029a</identifier><ispartof>CrystEngComm, 2022-09, Vol.24 (35), p.6137-614</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27906,27907</link.rule.ids></links><search><creatorcontrib>Cairns, Kelsey R</creatorcontrib><creatorcontrib>King, Rhys P</creatorcontrib><creatorcontrib>Levason, William</creatorcontrib><creatorcontrib>Reid, Gillian</creatorcontrib><title>Self-assembly of [Sn(OPMe)(CFSO)] metallocyclic Sn() hexamer stacks with CF-lined channel interiors</title><title>CrystEngComm</title><description>[Sn(OPMe
3
)
3
(CF
3
SO
3
)
2
]
6
(
1
) self-assembles to form a highly unusual hexagonal metallocyclic array with bridging CF
3
SO
3
−
groups. The discrete hexamers stack along the
c
-axis to form hydrophobic CF
3
-lined channels with an F F distance across the channel diameter of 0.8 nm. This Sn(
ii
) complex is different from its Pb(
ii
) analogue, which instead forms a discrete, doubly CF
3
SO
3
-bridged dimer of formula, [{Pb(OPMe
3
)
3
(CF
3
SO
3
)}
2
(μ-CF
3
SO
3
)
2
] (
3
).
The preparation, spectroscopic and structural characterisation of a [Sn(OPMe
3
)
3
(CF
3
SO
3
)
2
]
6
, a Sn(
ii
)-based metallocyclic hexamer, containing hydrophobic CF
3
-lined 8.0 Å diameter channels is reported.</description><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFzjsLwjAUQOEgCD4Xd-GO7VBNrBQ7F4uLVKibSInxlkbTVHIL2n-vg-DodIZvOYzNBF8IHsbL60ohF3wVyx4binUUBRsehgM2IrpxLtZC8CFTOZoykERYX0wHTQmn3HrZYY--l6R55p-hxlYa06hOGa3goz5U-JI1OqBWqjvBU7cVJGlgtMUrqEpaiwa0bdHpxtGE9UtpCKffjtk83R6TXeBIFQ-na-m64ncb_vM3jpVD3w</recordid><startdate>20220912</startdate><enddate>20220912</enddate><creator>Cairns, Kelsey R</creator><creator>King, Rhys P</creator><creator>Levason, William</creator><creator>Reid, Gillian</creator><scope/></search><sort><creationdate>20220912</creationdate><title>Self-assembly of [Sn(OPMe)(CFSO)] metallocyclic Sn() hexamer stacks with CF-lined channel interiors</title><author>Cairns, Kelsey R ; King, Rhys P ; Levason, William ; Reid, Gillian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d2ce01029a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2022</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cairns, Kelsey R</creatorcontrib><creatorcontrib>King, Rhys P</creatorcontrib><creatorcontrib>Levason, William</creatorcontrib><creatorcontrib>Reid, Gillian</creatorcontrib><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cairns, Kelsey R</au><au>King, Rhys P</au><au>Levason, William</au><au>Reid, Gillian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Self-assembly of [Sn(OPMe)(CFSO)] metallocyclic Sn() hexamer stacks with CF-lined channel interiors</atitle><jtitle>CrystEngComm</jtitle><date>2022-09-12</date><risdate>2022</risdate><volume>24</volume><issue>35</issue><spage>6137</spage><epage>614</epage><pages>6137-614</pages><eissn>1466-8033</eissn><abstract>[Sn(OPMe
3
)
3
(CF
3
SO
3
)
2
]
6
(
1
) self-assembles to form a highly unusual hexagonal metallocyclic array with bridging CF
3
SO
3
−
groups. The discrete hexamers stack along the
c
-axis to form hydrophobic CF
3
-lined channels with an F F distance across the channel diameter of 0.8 nm. This Sn(
ii
) complex is different from its Pb(
ii
) analogue, which instead forms a discrete, doubly CF
3
SO
3
-bridged dimer of formula, [{Pb(OPMe
3
)
3
(CF
3
SO
3
)}
2
(μ-CF
3
SO
3
)
2
] (
3
).
The preparation, spectroscopic and structural characterisation of a [Sn(OPMe
3
)
3
(CF
3
SO
3
)
2
]
6
, a Sn(
ii
)-based metallocyclic hexamer, containing hydrophobic CF
3
-lined 8.0 Å diameter channels is reported.</abstract><doi>10.1039/d2ce01029a</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | EISSN: 1466-8033 |
| ispartof | CrystEngComm, 2022-09, Vol.24 (35), p.6137-614 |
| issn | 1466-8033 |
| language | |
| recordid | cdi_rsc_primary_d2ce01029a |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Self-assembly of [Sn(OPMe)(CFSO)] metallocyclic Sn() hexamer stacks with CF-lined channel interiors |
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