Zn/Cu complexes constructed through selective Br-Cl exchange: synthesis, structures, properties, and DFT insights into the Cu-catalyzed mechanism

Two coordination polymers (CPs), [Cu 2 (L 1 )(μ 3 -OH)(H 2 O)] n ( 1 ) and {[Zn 4 (L) 2 (4,4′-bipy) 3 ]·4H 2 O} n ( 2 ), were synthesized under solvothermal conditions. Unexpectedly, the transformation of aryl-Br to aryl-Cl (Br-Cl exchange) was observed in the formation of complex 1 , which was succ...

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Veröffentlicht in:	CrystEngComm 2022-04, Vol.24 (16), p.326-334
Hauptverfasser:	Si, Chang-Dai, Zhang, Jian-Bin, Pan, Feng-Feng, Wang, Peng, Liao, Tian-Lu, Zheng, Wan-He, Liu, Jia-Cheng, Yuan, Kun
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