A fluoride-free siliceous STW-type zeolite synthesized using a designed organic structure-directing agent

A fluoride-free siliceous STW-type zeolite synthesized using a designed organic structure-directing agent

A pure silica STW zeolite is synthesized with no impurities under a wide range of synthesis conditions with and without fluoride by using easily available 1-methyl-1,5-diazabicyclo[4.3.0]non-5-ene (MDBN) as a template. MDBN having an appropriate size and geometry fits well in the STW cage, leading t...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-02, Vol.59 (12), p.1649-1652
Hauptverfasser: Jiao, Feng, Zhang, Jun, Cai, Xianshu, Li, Hao, Xu, Yanan, Zhao, Yue, Du, Hongbin
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Synthesis
Zeolites
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container_issue 12
container_start_page 1649
container_title Chemical communications (Cambridge, England)
container_volume 59
creator Jiao, Feng
Zhang, Jun
Cai, Xianshu
Li, Hao
Xu, Yanan
Zhao, Yue
Du, Hongbin
description A pure silica STW zeolite is synthesized with no impurities under a wide range of synthesis conditions with and without fluoride by using easily available 1-methyl-1,5-diazabicyclo[4.3.0]non-5-ene (MDBN) as a template. MDBN having an appropriate size and geometry fits well in the STW cage, leading to its high specificity in structure-directing formation of zeolite STW. Organic cation MDBN fits well in the STW cage and possesses strong guest-host interactions, which enables the templated synthesis of a chiral silica STW zeolite by a fluoride-free route.
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subjects Synthesis
Zeolites
title A fluoride-free siliceous STW-type zeolite synthesized using a designed organic structure-directing agent
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