Electrochemical sulfinylation of phenols with sulfides: a metal- and oxidant-free cross-coupling for the synthesis of aromatic sulfoxides

The site-selective C-H functionalization of arenes is of indisputable importance in organic chemistry. Herein, we have demonstrated an electrochemical regioselective oxidative cross-coupling towards the direct C(sp 2 )-H sulfinylation of phenols with sulfides under mild reaction conditions. The desi...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2023-01, Vol.59 (3), p.31-313
Hauptverfasser:	Kumar, Rakesh, Taily, Irshad Maajid, Banerjee, Prabal
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Cross coupling Organic chemistry Oxidizing agents Phenols Sulfides Sulfoxides
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container_title	Chemical communications (Cambridge, England)
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creator	Kumar, Rakesh Taily, Irshad Maajid Banerjee, Prabal
description	The site-selective C-H functionalization of arenes is of indisputable importance in organic chemistry. Herein, we have demonstrated an electrochemical regioselective oxidative cross-coupling towards the direct C(sp 2 )-H sulfinylation of phenols with sulfides under mild reaction conditions. The designed methodology furnished aryl sulfoxides in good to moderate yields under exogenous metal and oxidant-free conditions. Moreover, the exploitation of traceless electrons to carry out the tandem site-selective oxidative aryl chalcogenation is the striking feature of this methodology. Electrochemical site-selective sulfinylation of phenol.
doi_str_mv	10.1039/d2cc05207e
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subjects	Aromatic compounds Cross coupling Organic chemistry Oxidizing agents Phenols Sulfides Sulfoxides
title	Electrochemical sulfinylation of phenols with sulfides: a metal- and oxidant-free cross-coupling for the synthesis of aromatic sulfoxides
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