Porous FeF/MWCNTs composite cathode promoting high performance aluminum storage

Rechargeable aluminum-ion batteries (RAIBs) attract great attention for stationary energy storage, but there remains a lack of suitable cathode materials for them. Here, a porous iron fluoride/multi wall carbon nanotube (FeF 3 /MWCNTs) composite as a cathode for RAIBs shows high discharge capacity (...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2022-12, Vol.58 (97), p.13495-13498
Hauptverfasser: Li, Tongge, Hu, Haoyu, Liang, Baoqiang, Liu, Xiaoqi, Zhang, Yu, Cai, Tonghui, Xing, Wei, Yan, Zifeng
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container_end_page 13498
container_issue 97
container_start_page 13495
container_title Chemical communications (Cambridge, England)
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creator Li, Tongge
Hu, Haoyu
Liang, Baoqiang
Liu, Xiaoqi
Zhang, Yu
Cai, Tonghui
Xing, Wei
Yan, Zifeng
description Rechargeable aluminum-ion batteries (RAIBs) attract great attention for stationary energy storage, but there remains a lack of suitable cathode materials for them. Here, a porous iron fluoride/multi wall carbon nanotube (FeF 3 /MWCNTs) composite as a cathode for RAIBs shows high discharge capacity (180 mA h g −1 ) and good rate performance, while MWCNTs play crucial roles in improving conductivity and cycle stability. Various characterizations elucidate its conversion-type mechanism, in particular, the Fe 3+ /Fe 2+ conversion exhibits a high operating potential of 1.75 V and discharge capacity of 123 mA h g −1 , which is very promising for practical applications. FeF 3 /MWCNTs as a cathode for rechargeable aluminum-ion batteries exhibits excellent electrochemical performance, in particular the Fe 3+ /Fe 2+ conversion reaction makes it have great application potential.
doi_str_mv 10.1039/d2cc04338f
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title Porous FeF/MWCNTs composite cathode promoting high performance aluminum storage
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