Synthesis and optoelectronic properties of radical conjugated polyfluorenes
A novel redox-active fluorene monomer is synthesized and copolymerized with 9,9-dioctylfluorene and benzo[ c ][1,2,5]thiadiazole via Suzuki cross-coupling to produce alternating and tertiary copolymers. Electrochemical and chemical reduction of the copolymers generates organic polymeric radical anio...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2022-08, Vol.58 (62), p.863-8633 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Cheng, Susan Battaglia, Alicia M Imperiale, Christian J Lough, Alan Wilson, Mark W. B Seferos, Dwight S |
| description | A novel redox-active fluorene monomer is synthesized and copolymerized with 9,9-dioctylfluorene and benzo[
c
][1,2,5]thiadiazole
via
Suzuki cross-coupling to produce alternating and tertiary copolymers. Electrochemical and chemical reduction of the copolymers generates organic polymeric radical anions. Electrochemical, spectroscopic, and photophysical characterization grant insight into the structure-property relationship for open-shell conjugated polymers.
A novel redox-active fluorene monomer is synthesized and copolymerized with 9,9-dioctylfluorene and benzo[
c
][1,2,5]thiadiazole
via
Suzuki cross-coupling to produce alternating and tertiary copolymers. |
| doi_str_mv | 10.1039/d2cc02406c |
| format | Article |
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c
][1,2,5]thiadiazole
via
Suzuki cross-coupling to produce alternating and tertiary copolymers. Electrochemical and chemical reduction of the copolymers generates organic polymeric radical anions. Electrochemical, spectroscopic, and photophysical characterization grant insight into the structure-property relationship for open-shell conjugated polymers.
A novel redox-active fluorene monomer is synthesized and copolymerized with 9,9-dioctylfluorene and benzo[
c
][1,2,5]thiadiazole
via
Suzuki cross-coupling to produce alternating and tertiary copolymers.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d2cc02406c</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Chemical reduction ; Copolymerization ; Copolymers ; Cross coupling ; Optoelectronics ; Thiadiazoles</subject><ispartof>Chemical communications (Cambridge, England), 2022-08, Vol.58 (62), p.863-8633</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c314t-bc608d6adba859e5d5699fc422e96d4916fa74aac9ee53d6fb51b51cb53cb0933</citedby><cites>FETCH-LOGICAL-c314t-bc608d6adba859e5d5699fc422e96d4916fa74aac9ee53d6fb51b51cb53cb0933</cites><orcidid>0000-0001-9504-7394 ; 0000-0002-1957-2979 ; 0000-0001-8742-8058</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Cheng, Susan</creatorcontrib><creatorcontrib>Battaglia, Alicia M</creatorcontrib><creatorcontrib>Imperiale, Christian J</creatorcontrib><creatorcontrib>Lough, Alan</creatorcontrib><creatorcontrib>Wilson, Mark W. B</creatorcontrib><creatorcontrib>Seferos, Dwight S</creatorcontrib><title>Synthesis and optoelectronic properties of radical conjugated polyfluorenes</title><title>Chemical communications (Cambridge, England)</title><description>A novel redox-active fluorene monomer is synthesized and copolymerized with 9,9-dioctylfluorene and benzo[
c
][1,2,5]thiadiazole
via
Suzuki cross-coupling to produce alternating and tertiary copolymers. Electrochemical and chemical reduction of the copolymers generates organic polymeric radical anions. Electrochemical, spectroscopic, and photophysical characterization grant insight into the structure-property relationship for open-shell conjugated polymers.
A novel redox-active fluorene monomer is synthesized and copolymerized with 9,9-dioctylfluorene and benzo[
c
][1,2,5]thiadiazole
via
Suzuki cross-coupling to produce alternating and tertiary copolymers.</description><subject>Chemical reduction</subject><subject>Copolymerization</subject><subject>Copolymers</subject><subject>Cross coupling</subject><subject>Optoelectronics</subject><subject>Thiadiazoles</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpd0E1LxDAQBuAgCq6rF-9CwYsI1aT5aHOU-okLHlTwVtLJVLt0m5q0h_33Zl1RMAyZOTwMw0vIMaMXjHJ9aTMAmgmqYIfMGFcilaJ4293MUqc5F3KfHISwpPExWczI4_O6Hz8wtCExvU3cMDrsEEbv-haSwbsB_dhiSFyTeGNbMF0Crl9O72ZEmwyuWzfd5Dz2GA7JXmO6gEc_fU5eb29eyvt08XT3UF4tUuBMjGkNihZWGVubQmqUViqtGxBZhlpZoZlqTC6MAY0ouVVNLVksqCWHmmrO5-Rsuzee9zlhGKtVGwC7zvToplBlqtAqj7-M9PQfXbrJ9_G6qHROI6Q0qvOtAu9C8NhUg29Xxq8rRqtNrtV1VpbfuZYRn2yxD_Dr_nLnX1H3dcI</recordid><startdate>20220802</startdate><enddate>20220802</enddate><creator>Cheng, Susan</creator><creator>Battaglia, Alicia M</creator><creator>Imperiale, Christian J</creator><creator>Lough, Alan</creator><creator>Wilson, Mark W. B</creator><creator>Seferos, Dwight S</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-9504-7394</orcidid><orcidid>https://orcid.org/0000-0002-1957-2979</orcidid><orcidid>https://orcid.org/0000-0001-8742-8058</orcidid></search><sort><creationdate>20220802</creationdate><title>Synthesis and optoelectronic properties of radical conjugated polyfluorenes</title><author>Cheng, Susan ; Battaglia, Alicia M ; Imperiale, Christian J ; Lough, Alan ; Wilson, Mark W. B ; Seferos, Dwight S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c314t-bc608d6adba859e5d5699fc422e96d4916fa74aac9ee53d6fb51b51cb53cb0933</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Chemical reduction</topic><topic>Copolymerization</topic><topic>Copolymers</topic><topic>Cross coupling</topic><topic>Optoelectronics</topic><topic>Thiadiazoles</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cheng, Susan</creatorcontrib><creatorcontrib>Battaglia, Alicia M</creatorcontrib><creatorcontrib>Imperiale, Christian J</creatorcontrib><creatorcontrib>Lough, Alan</creatorcontrib><creatorcontrib>Wilson, Mark W. B</creatorcontrib><creatorcontrib>Seferos, Dwight S</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cheng, Susan</au><au>Battaglia, Alicia M</au><au>Imperiale, Christian J</au><au>Lough, Alan</au><au>Wilson, Mark W. B</au><au>Seferos, Dwight S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and optoelectronic properties of radical conjugated polyfluorenes</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2022-08-02</date><risdate>2022</risdate><volume>58</volume><issue>62</issue><spage>863</spage><epage>8633</epage><pages>863-8633</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A novel redox-active fluorene monomer is synthesized and copolymerized with 9,9-dioctylfluorene and benzo[
c
][1,2,5]thiadiazole
via
Suzuki cross-coupling to produce alternating and tertiary copolymers. Electrochemical and chemical reduction of the copolymers generates organic polymeric radical anions. Electrochemical, spectroscopic, and photophysical characterization grant insight into the structure-property relationship for open-shell conjugated polymers.
A novel redox-active fluorene monomer is synthesized and copolymerized with 9,9-dioctylfluorene and benzo[
c
][1,2,5]thiadiazole
via
Suzuki cross-coupling to produce alternating and tertiary copolymers.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2cc02406c</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-9504-7394</orcidid><orcidid>https://orcid.org/0000-0002-1957-2979</orcidid><orcidid>https://orcid.org/0000-0001-8742-8058</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2022-08, Vol.58 (62), p.863-8633 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_rsc_primary_d2cc02406c |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Chemical reduction Copolymerization Copolymers Cross coupling Optoelectronics Thiadiazoles |
| title | Synthesis and optoelectronic properties of radical conjugated polyfluorenes |
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