Transition structures for the oxy-ene reaction

An overlooked pericyclic reaction between allyl alcohols and alkenes to form carbonyl compounds is analyzed. It combines the characteristic features of the Alder-ene reaction and of the oxy-Cope rearrangement. This oxy-ene reaction could be involved in biosynthetic pathways. Can this occur naturally...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2022-04, Vol.58 (3), p.4751-4754
Hauptverfasser:	Yang, Shengwen, Miaskiewicz, Solène, Bour, Christophe, Alix, Aurélien, Gandon, Vincent
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols Alkenes Alkenes - chemistry Biosynthetic Pathways Carbonyl compounds Carbonyls Chemical Sciences
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	An overlooked pericyclic reaction between allyl alcohols and alkenes to form carbonyl compounds is analyzed. It combines the characteristic features of the Alder-ene reaction and of the oxy-Cope rearrangement. This oxy-ene reaction could be involved in biosynthetic pathways. Can this occur naturally? This study offers the theoretical background of an overlooked pericyclic reaction.
ISSN:	1359-7345 1364-548X
DOI:	10.1039/d2cc00687a