Divergent oxidative dearomatization coupling reactions to construct polycyclic cyclohexadienones
Highly selective divergent oxidative dearomatization coupling reactions, in which the chemoselectivity is controlled by catalysts and bases, are reported herein. Three different kinds of polycyclic cyclohexadienones are produced from the same reactants (41 examples, 85-99% yield). Our method marks a...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2022-03, Vol.58 (27), p.4348-4351 |
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| container_issue | 27 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Pu, Qian Huo, Mingming Liang, Guojuan Bai, Lijuan Chen, Genhui Li, Hongjiao Xiang, Peng Zhou, Hui Zhou, Jing |
| description | Highly selective divergent oxidative dearomatization coupling reactions, in which the chemoselectivity is controlled by catalysts and bases, are reported herein. Three different kinds of polycyclic cyclohexadienones are produced from the same reactants (41 examples, 85-99% yield). Our method marks a novel copper- and palladium-catalyzed C-H oxidative dearomatization of phenolic derivatives.
Divergent oxidative dearomatization coupling reactions, in which the chemoselectivity is controlled by catalysts and bases, are reported. Our method marks a novel copper- and palladium-catalyzed C-H oxidative dearomatization of phenolic derivatives. |
| doi_str_mv | 10.1039/d2cc00183g |
| format | Article |
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Divergent oxidative dearomatization coupling reactions, in which the chemoselectivity is controlled by catalysts and bases, are reported. Our method marks a novel copper- and palladium-catalyzed C-H oxidative dearomatization of phenolic derivatives.</description><subject>Chemical reactions</subject><subject>Coupling</subject><subject>Palladium</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpdkcFLwzAUxoMobk4v3pWCFxGqSZO0yVE6ncLAyw7eavqazo6umUkrm3-9qZsTfBDey3s_Pl6-IHRO8C3BVN4VEQDGRND5ARoSGrOQM_F62NdchgllfIBOnFtgH4SLYzSgPJJU4niI3sbVp7Zz3bSBWVeFav01KLSyZunrL39ME4DpVnXVzAOrFfQdF7TGdxvX2g7aYGXqDWygriDok3nXa1VUujGNdqfoqFS102e7PEKzx4dZ-hROXybP6f00BEqTNtSi5IIKKSTgJJe4ZICJjJhkcZwzShgURSQjRQSwWEEMImeSywS0ivxr6Qhdb2VX1nx02rXZsnKg61o12nQui2KGMeOYJB69-ocuTGcbv1xPcUZjnlBP3WwpsMY5q8tsZaulspuM4Ky3PRtHafpj-8TDlzvJLl_qYo_--uyBiy1gHeynf_9GvwEG-4gO</recordid><startdate>20220331</startdate><enddate>20220331</enddate><creator>Pu, Qian</creator><creator>Huo, Mingming</creator><creator>Liang, Guojuan</creator><creator>Bai, Lijuan</creator><creator>Chen, Genhui</creator><creator>Li, Hongjiao</creator><creator>Xiang, Peng</creator><creator>Zhou, Hui</creator><creator>Zhou, Jing</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-3780-6107</orcidid><orcidid>https://orcid.org/0000-0001-7018-3277</orcidid></search><sort><creationdate>20220331</creationdate><title>Divergent oxidative dearomatization coupling reactions to construct polycyclic cyclohexadienones</title><author>Pu, Qian ; Huo, Mingming ; Liang, Guojuan ; Bai, Lijuan ; Chen, Genhui ; Li, Hongjiao ; Xiang, Peng ; Zhou, Hui ; Zhou, Jing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-e8f5838989c07b90f4c019249466b4314cdd292a18c46ac6c8b49597cea25483</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Chemical reactions</topic><topic>Coupling</topic><topic>Palladium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pu, Qian</creatorcontrib><creatorcontrib>Huo, Mingming</creatorcontrib><creatorcontrib>Liang, Guojuan</creatorcontrib><creatorcontrib>Bai, Lijuan</creatorcontrib><creatorcontrib>Chen, Genhui</creatorcontrib><creatorcontrib>Li, Hongjiao</creatorcontrib><creatorcontrib>Xiang, Peng</creatorcontrib><creatorcontrib>Zhou, Hui</creatorcontrib><creatorcontrib>Zhou, Jing</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pu, Qian</au><au>Huo, Mingming</au><au>Liang, Guojuan</au><au>Bai, Lijuan</au><au>Chen, Genhui</au><au>Li, Hongjiao</au><au>Xiang, Peng</au><au>Zhou, Hui</au><au>Zhou, Jing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Divergent oxidative dearomatization coupling reactions to construct polycyclic cyclohexadienones</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2022-03-31</date><risdate>2022</risdate><volume>58</volume><issue>27</issue><spage>4348</spage><epage>4351</epage><pages>4348-4351</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Highly selective divergent oxidative dearomatization coupling reactions, in which the chemoselectivity is controlled by catalysts and bases, are reported herein. Three different kinds of polycyclic cyclohexadienones are produced from the same reactants (41 examples, 85-99% yield). Our method marks a novel copper- and palladium-catalyzed C-H oxidative dearomatization of phenolic derivatives.
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| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2022-03, Vol.58 (27), p.4348-4351 |
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| language | eng |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Chemical reactions Coupling Palladium |
| title | Divergent oxidative dearomatization coupling reactions to construct polycyclic cyclohexadienones |
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