Hydrogenation of furfural to furfuryl alcohol over MOF-derived Fe/Cu@C and FeO/Cu@C catalysts
Using Cu-MOF loaded with Fe(NO 3 ) 3 as a precursor (Fe(NO 3 ) 3 /Cu-MOF), Fe/Cu@C and Fe 3 O 4 /Cu@C catalysts were prepared via heating under a H 2 or N 2 atmosphere, respectively. When Fe(NO 3 ) 3 /Cu-MOF was heated under either atmosphere, the Cu-MOF was pyrolyzed and carbonized into porous carb...
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| Veröffentlicht in: | Reaction chemistry & engineering 2022-03, Vol.7 (4), p.994-14 |
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| creator | Li, Pei Ma, Fengmin Fu, Mengyao Lu, Shiyu Xia, Xinxin Li, Cuiqin Gao, Yuxin Li, Feng |
| description | Using Cu-MOF loaded with Fe(NO
3
)
3
as a precursor (Fe(NO
3
)
3
/Cu-MOF), Fe/Cu@C and Fe
3
O
4
/Cu@C catalysts were prepared
via
heating under a H
2
or N
2
atmosphere, respectively. When Fe(NO
3
)
3
/Cu-MOF was heated under either atmosphere, the Cu-MOF was pyrolyzed and carbonized into porous carbon-coated Cu
0
nanoparticles. Various techniques were used to study the formation of active species and the physicochemical properties of the catalysts. The catalytic performance of the as-obtained catalysts was evaluated using furfural hydrogenation. The Cu
2+
and Fe
3+
in the Fe/Cu@C catalyst were reduced to Cu
0
and Fe
0
, respectively, and Fe
0
particles were loaded onto the surface of the porous carbon. Cu
2+
and Fe
3+
in the Fe
3
O
4
/Cu@C catalyst were reduced to Cu
0
and Fe
3
O
4
, respectively, and the Fe
3
O
4
particles were embedded onto the surface of porous carbon to form an embedded structure. The catalytic furfural hydrogenation activity of Fe
3
O
4
/Cu@C was higher than that of Fe/Cu@C. The catalytic furfural hydrogenation using Fe
3
O
4
/Cu@C occurred
via
direct catalytic hydrogenation (with molecular hydrogen as the hydrogen source) and catalytic transfer hydrogenation (with i-propanol as the hydrogen donor). The direct catalytic hydrogenation activity of Fe
3
O
4
/Cu@C was superior to its catalytic transfer hydrogenation activity.
Using Cu-MOF loaded with Fe(NO
3
)
3
as a precursor (Fe(NO
3
)
3
/Cu-MOF), Fe/Cu@C and Fe
3
O
4
/Cu@C catalysts were prepared
via
heating under a H
2
or N
2
atmosphere, respectively. |
| doi_str_mv | 10.1039/d1re00543j |
| format | Article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_d1re00543j</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>d1re00543j</sourcerecordid><originalsourceid>FETCH-rsc_primary_d1re00543j3</originalsourceid><addsrcrecordid>eNqFjkELgjAcxUcQJOWle7AvYP7XsuYtkMRLdOkaMtwsZbnYprBvX5HQMXjwfj_e5SG0JLAmQNNYECMBki1tJyjYQMKilDE6Q6G1LQCQHQBl-wBdCy-MvsmOu0Z3WNe47s07XGGnR_YKc1Xpu1ZYD9Lg0zmPhDTNIAXOZZz1hwzz7sPnr1TcceWtsws0rbmyMhx7jlb58ZIVkbFV-TTNgxtf_q7Sf_sLOiRDWQ</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Hydrogenation of furfural to furfuryl alcohol over MOF-derived Fe/Cu@C and FeO/Cu@C catalysts</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Li, Pei ; Ma, Fengmin ; Fu, Mengyao ; Lu, Shiyu ; Xia, Xinxin ; Li, Cuiqin ; Gao, Yuxin ; Li, Feng</creator><creatorcontrib>Li, Pei ; Ma, Fengmin ; Fu, Mengyao ; Lu, Shiyu ; Xia, Xinxin ; Li, Cuiqin ; Gao, Yuxin ; Li, Feng</creatorcontrib><description>Using Cu-MOF loaded with Fe(NO
3
)
3
as a precursor (Fe(NO
3
)
3
/Cu-MOF), Fe/Cu@C and Fe
3
O
4
/Cu@C catalysts were prepared
via
heating under a H
2
or N
2
atmosphere, respectively. When Fe(NO
3
)
3
/Cu-MOF was heated under either atmosphere, the Cu-MOF was pyrolyzed and carbonized into porous carbon-coated Cu
0
nanoparticles. Various techniques were used to study the formation of active species and the physicochemical properties of the catalysts. The catalytic performance of the as-obtained catalysts was evaluated using furfural hydrogenation. The Cu
2+
and Fe
3+
in the Fe/Cu@C catalyst were reduced to Cu
0
and Fe
0
, respectively, and Fe
0
particles were loaded onto the surface of the porous carbon. Cu
2+
and Fe
3+
in the Fe
3
O
4
/Cu@C catalyst were reduced to Cu
0
and Fe
3
O
4
, respectively, and the Fe
3
O
4
particles were embedded onto the surface of porous carbon to form an embedded structure. The catalytic furfural hydrogenation activity of Fe
3
O
4
/Cu@C was higher than that of Fe/Cu@C. The catalytic furfural hydrogenation using Fe
3
O
4
/Cu@C occurred
via
direct catalytic hydrogenation (with molecular hydrogen as the hydrogen source) and catalytic transfer hydrogenation (with i-propanol as the hydrogen donor). The direct catalytic hydrogenation activity of Fe
3
O
4
/Cu@C was superior to its catalytic transfer hydrogenation activity.
Using Cu-MOF loaded with Fe(NO
3
)
3
as a precursor (Fe(NO
3
)
3
/Cu-MOF), Fe/Cu@C and Fe
3
O
4
/Cu@C catalysts were prepared
via
heating under a H
2
or N
2
atmosphere, respectively.</description><identifier>EISSN: 2058-9883</identifier><identifier>DOI: 10.1039/d1re00543j</identifier><ispartof>Reaction chemistry & engineering, 2022-03, Vol.7 (4), p.994-14</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Li, Pei</creatorcontrib><creatorcontrib>Ma, Fengmin</creatorcontrib><creatorcontrib>Fu, Mengyao</creatorcontrib><creatorcontrib>Lu, Shiyu</creatorcontrib><creatorcontrib>Xia, Xinxin</creatorcontrib><creatorcontrib>Li, Cuiqin</creatorcontrib><creatorcontrib>Gao, Yuxin</creatorcontrib><creatorcontrib>Li, Feng</creatorcontrib><title>Hydrogenation of furfural to furfuryl alcohol over MOF-derived Fe/Cu@C and FeO/Cu@C catalysts</title><title>Reaction chemistry & engineering</title><description>Using Cu-MOF loaded with Fe(NO
3
)
3
as a precursor (Fe(NO
3
)
3
/Cu-MOF), Fe/Cu@C and Fe
3
O
4
/Cu@C catalysts were prepared
via
heating under a H
2
or N
2
atmosphere, respectively. When Fe(NO
3
)
3
/Cu-MOF was heated under either atmosphere, the Cu-MOF was pyrolyzed and carbonized into porous carbon-coated Cu
0
nanoparticles. Various techniques were used to study the formation of active species and the physicochemical properties of the catalysts. The catalytic performance of the as-obtained catalysts was evaluated using furfural hydrogenation. The Cu
2+
and Fe
3+
in the Fe/Cu@C catalyst were reduced to Cu
0
and Fe
0
, respectively, and Fe
0
particles were loaded onto the surface of the porous carbon. Cu
2+
and Fe
3+
in the Fe
3
O
4
/Cu@C catalyst were reduced to Cu
0
and Fe
3
O
4
, respectively, and the Fe
3
O
4
particles were embedded onto the surface of porous carbon to form an embedded structure. The catalytic furfural hydrogenation activity of Fe
3
O
4
/Cu@C was higher than that of Fe/Cu@C. The catalytic furfural hydrogenation using Fe
3
O
4
/Cu@C occurred
via
direct catalytic hydrogenation (with molecular hydrogen as the hydrogen source) and catalytic transfer hydrogenation (with i-propanol as the hydrogen donor). The direct catalytic hydrogenation activity of Fe
3
O
4
/Cu@C was superior to its catalytic transfer hydrogenation activity.
Using Cu-MOF loaded with Fe(NO
3
)
3
as a precursor (Fe(NO
3
)
3
/Cu-MOF), Fe/Cu@C and Fe
3
O
4
/Cu@C catalysts were prepared
via
heating under a H
2
or N
2
atmosphere, respectively.</description><issn>2058-9883</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjkELgjAcxUcQJOWle7AvYP7XsuYtkMRLdOkaMtwsZbnYprBvX5HQMXjwfj_e5SG0JLAmQNNYECMBki1tJyjYQMKilDE6Q6G1LQCQHQBl-wBdCy-MvsmOu0Z3WNe47s07XGGnR_YKc1Xpu1ZYD9Lg0zmPhDTNIAXOZZz1hwzz7sPnr1TcceWtsws0rbmyMhx7jlb58ZIVkbFV-TTNgxtf_q7Sf_sLOiRDWQ</recordid><startdate>20220329</startdate><enddate>20220329</enddate><creator>Li, Pei</creator><creator>Ma, Fengmin</creator><creator>Fu, Mengyao</creator><creator>Lu, Shiyu</creator><creator>Xia, Xinxin</creator><creator>Li, Cuiqin</creator><creator>Gao, Yuxin</creator><creator>Li, Feng</creator><scope/></search><sort><creationdate>20220329</creationdate><title>Hydrogenation of furfural to furfuryl alcohol over MOF-derived Fe/Cu@C and FeO/Cu@C catalysts</title><author>Li, Pei ; Ma, Fengmin ; Fu, Mengyao ; Lu, Shiyu ; Xia, Xinxin ; Li, Cuiqin ; Gao, Yuxin ; Li, Feng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d1re00543j3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2022</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Pei</creatorcontrib><creatorcontrib>Ma, Fengmin</creatorcontrib><creatorcontrib>Fu, Mengyao</creatorcontrib><creatorcontrib>Lu, Shiyu</creatorcontrib><creatorcontrib>Xia, Xinxin</creatorcontrib><creatorcontrib>Li, Cuiqin</creatorcontrib><creatorcontrib>Gao, Yuxin</creatorcontrib><creatorcontrib>Li, Feng</creatorcontrib><jtitle>Reaction chemistry & engineering</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Pei</au><au>Ma, Fengmin</au><au>Fu, Mengyao</au><au>Lu, Shiyu</au><au>Xia, Xinxin</au><au>Li, Cuiqin</au><au>Gao, Yuxin</au><au>Li, Feng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrogenation of furfural to furfuryl alcohol over MOF-derived Fe/Cu@C and FeO/Cu@C catalysts</atitle><jtitle>Reaction chemistry & engineering</jtitle><date>2022-03-29</date><risdate>2022</risdate><volume>7</volume><issue>4</issue><spage>994</spage><epage>14</epage><pages>994-14</pages><eissn>2058-9883</eissn><abstract>Using Cu-MOF loaded with Fe(NO
3
)
3
as a precursor (Fe(NO
3
)
3
/Cu-MOF), Fe/Cu@C and Fe
3
O
4
/Cu@C catalysts were prepared
via
heating under a H
2
or N
2
atmosphere, respectively. When Fe(NO
3
)
3
/Cu-MOF was heated under either atmosphere, the Cu-MOF was pyrolyzed and carbonized into porous carbon-coated Cu
0
nanoparticles. Various techniques were used to study the formation of active species and the physicochemical properties of the catalysts. The catalytic performance of the as-obtained catalysts was evaluated using furfural hydrogenation. The Cu
2+
and Fe
3+
in the Fe/Cu@C catalyst were reduced to Cu
0
and Fe
0
, respectively, and Fe
0
particles were loaded onto the surface of the porous carbon. Cu
2+
and Fe
3+
in the Fe
3
O
4
/Cu@C catalyst were reduced to Cu
0
and Fe
3
O
4
, respectively, and the Fe
3
O
4
particles were embedded onto the surface of porous carbon to form an embedded structure. The catalytic furfural hydrogenation activity of Fe
3
O
4
/Cu@C was higher than that of Fe/Cu@C. The catalytic furfural hydrogenation using Fe
3
O
4
/Cu@C occurred
via
direct catalytic hydrogenation (with molecular hydrogen as the hydrogen source) and catalytic transfer hydrogenation (with i-propanol as the hydrogen donor). The direct catalytic hydrogenation activity of Fe
3
O
4
/Cu@C was superior to its catalytic transfer hydrogenation activity.
Using Cu-MOF loaded with Fe(NO
3
)
3
as a precursor (Fe(NO
3
)
3
/Cu-MOF), Fe/Cu@C and Fe
3
O
4
/Cu@C catalysts were prepared
via
heating under a H
2
or N
2
atmosphere, respectively.</abstract><doi>10.1039/d1re00543j</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | EISSN: 2058-9883 |
| ispartof | Reaction chemistry & engineering, 2022-03, Vol.7 (4), p.994-14 |
| issn | 2058-9883 |
| language | |
| recordid | cdi_rsc_primary_d1re00543j |
| source | Royal Society Of Chemistry Journals 2008- |
| title | Hydrogenation of furfural to furfuryl alcohol over MOF-derived Fe/Cu@C and FeO/Cu@C catalysts |
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