Direct conversion of lignin to high-quality graphene-based materials catalytic carbonization

Methods for effectively utilizing lignin are necessary for the realization of a sustainable society. Herein, we report a method for directly converting lignin to graphene-based materials. Fe-supported lignin is prepared by dissolving lignin in an aqueous FeCl 2 solution, followed by freeze drying. G...

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Veröffentlicht in:RSC advances 2021-05, Vol.11 (31), p.1872-1877
Hauptverfasser: Ishii, Takafumi, Mori, Mikaru, Hisayasu, Shiguma, Tamura, Ryusuke, Ikuta, Yuki, Fujishiro, Fumito, Ozaki, Jun-ichi, Itabashi, Hideyuki, Mori, Masanobu
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container_end_page 1877
container_issue 31
container_start_page 1872
container_title RSC advances
container_volume 11
creator Ishii, Takafumi
Mori, Mikaru
Hisayasu, Shiguma
Tamura, Ryusuke
Ikuta, Yuki
Fujishiro, Fumito
Ozaki, Jun-ichi
Itabashi, Hideyuki
Mori, Masanobu
description Methods for effectively utilizing lignin are necessary for the realization of a sustainable society. Herein, we report a method for directly converting lignin to graphene-based materials. Fe-supported lignin is prepared by dissolving lignin in an aqueous FeCl 2 solution, followed by freeze drying. Graphene is then produced by catalytically carbonizing this Fe-supported lignin at 1200 °C. The characteristics of both the Fe catalyst and lignin are crucial for the production of high-quality graphene. Specifically, the lignin should disperse well in water, freeze dry, and carbonize via solid-state carbonization. The obtained graphene-based material is highly resistant to electrochemical oxidation, as observed in other graphene-based materials. The direct conversion of lignin to graphene described herein is an unprecedented method for synthesizing large amounts of graphene-based material at low cost, as well as being an excellent use for lignin. Directly converting lignin to graphene via catalytic carbonization is expected to expand the industrial use of lignin and graphene-based materials.
doi_str_mv 10.1039/d1ra02491d
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title Direct conversion of lignin to high-quality graphene-based materials catalytic carbonization
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