Effect of HSiF modification of IM-5 on catalytic performance in benzene alkylation with ethylene

Ethylbenzene (EB) is an important bulk chemical intermediate. The vapor-phase process is considered to be more efficient than the liquid-phase process when using dilute ethylene ( e.g. FCC or DCC off-gas) as the feed due to its high ethylene space velocity. However, realizing a balance between reducing the xylene formation and enhancing the EB selectivity is still a challenge due to the poor performance of ZSM-5 at low reaction temperature. This study concerns an IM-5 zeolite (IMF topology) modified by H 2 SiF 6 , with 89% ethylbenzene selectivity, 98.6% total EB + DEB selectivity and only 540 ppm of xylene at 330 °C. IM-5 zeolites with different Si/Al 2 ratios (40-170) were prepared by H 2 SiF 6 modification and their catalytic performance in vapor phase alkylation of benzene with ethylene was investigated. There was an obvious decrease in the acid sites and acid strength of IM-5 in the H 2 SiF 6 treatment process, which led to a slight decrease in ethylbenzene selectivity and a significant decline in xylene yield. Under the conditions of complete ethylene conversion, the selectivity to EB + DEB increased from 96.1% to 98.6% in the parent I-40 and modified IM-5. Compared with ZSM-5 that has a similar acidity, the slightly bigger channel opening makes IM-5 more conductive to the formation and diffusion of DEB while xylene may present adverse effects. The 120 hour-lifetime test showed that IM-5 (I-110) has superior activity, equivalent stability, higher DEB selectivity and a much lower xylene selectivity in comparison with ZSM-5. The catalytic performance of the IM-5 zeolite in the vapor phase process provides a new choice for the production of ethylbenzene. IM-5 zeolite modified by H 2 SiF 6 has superior activity, equivalent stability, higher DEB selectivity and a lower xylene selectivity in comparison of ZSM-5 with similar Si/Al 2 ratio. The process provides a new way to make ethylbenzene in the vapor phase.