Synthesis and melt-spinning of partly bio-based thermoplastic poly(cycloacetal-urethane)s toward sustainable textiles

A rigid diol with a cyclic acetal structure was synthesized by facile acetalation of fructose-based 5-hydroxymethyl furfural (HMF) and partly bio-based di-trimethylolpropane (di-TMP). This diol (Monomer T) was copolymerized with potentially bio-based flexible polytetrahydrofuran and diisocyanates to...

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Veröffentlicht in:	Polymer chemistry 2021, Vol.12 (34), p.4942-4953
Hauptverfasser:	Warlin, Niklas, Nilsson, Erik, Guo, Zengwei, Mankar, Smita V, Valsange, Nitin G, Rehnberg, Nicola, Lundmark, Stefan, Jannasch, Patric, Zhang, Baozhong
Format:	Artikel
Sprache:	eng
Schlagworte:	Acidic conditions Chemical building blocks Chemical Engineering Chemical Sciences Copolymerization Diisocyanates Engineering and Technology Esters Fire resistance Flame resistance Furfural Glass transition Glass transition temperature High molecular weight Kemi Kemiteknik Materialkemi Materials Chemistry Materials Engineering Materialteknik Measuring instruments Melt spinning Natural Sciences Naturvetenskap Polymer Chemistry Polymer Technologies Polymerkemi Polymerteknologi Polytetrahydrofuran Processing windows Pyrolysis Reinforced plastics Rheological properties Rheology Solution polymerization Spinning (fibers) Sustainable textiles Teknik Textil-, gummi- och polymermaterial Textile, Rubber and Polymeric Materials Textiles Thermal stability Thermogravimetric analysis Trimethylolpropane
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