Ruthenium-catalyzed -alkylation of amino-1,3,5-triazines using alcohols
An efficient ruthenium-catalyzed N -alkylation of amino 1,3,5-triazines with alcohols was achieved via a BH/HA strategy. Following this simple, facile, and high atom economical protocol, a broad range of products was prepared in moderate to good yields and heterocyclic or benzylic alcohols containin...
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Veröffentlicht in: | New journal of chemistry 2021-09, Vol.45 (35), p.15776-15779 |
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container_issue | 35 |
container_start_page | 15776 |
container_title | New journal of chemistry |
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creator | Zhao, Junna Zhong, Pengzhen Xie, Zhongpao Zhou, Wei Zhang, Chen Cui, Dong-Mei |
description | An efficient ruthenium-catalyzed
N
-alkylation of amino 1,3,5-triazines with alcohols was achieved
via
a BH/HA strategy. Following this simple, facile, and high atom economical protocol, a broad range of products was prepared in moderate to good yields and heterocyclic or benzylic alcohols containing various functionalities were tolerated. The application of the reaction is also further demonstrated by the synthesis of alkylated secondary amine-1,3,5-triazines from olefinated amino-1,3,5-triazines and alcohols
via
a one pot
N
-alkylation and reductive reactions.
An efficient ruthenium-catalyzed
N
-alkylation of amino-1,3,5-triazines with alcohols was achieved
via
BH/HA strategy. |
doi_str_mv | 10.1039/d1nj03116c |
format | Article |
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N
-alkylation of amino 1,3,5-triazines with alcohols was achieved
via
a BH/HA strategy. Following this simple, facile, and high atom economical protocol, a broad range of products was prepared in moderate to good yields and heterocyclic or benzylic alcohols containing various functionalities were tolerated. The application of the reaction is also further demonstrated by the synthesis of alkylated secondary amine-1,3,5-triazines from olefinated amino-1,3,5-triazines and alcohols
via
a one pot
N
-alkylation and reductive reactions.
An efficient ruthenium-catalyzed
N
-alkylation of amino-1,3,5-triazines with alcohols was achieved
via
BH/HA strategy.</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/d1nj03116c</identifier><ispartof>New journal of chemistry, 2021-09, Vol.45 (35), p.15776-15779</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids></links><search><creatorcontrib>Zhao, Junna</creatorcontrib><creatorcontrib>Zhong, Pengzhen</creatorcontrib><creatorcontrib>Xie, Zhongpao</creatorcontrib><creatorcontrib>Zhou, Wei</creatorcontrib><creatorcontrib>Zhang, Chen</creatorcontrib><creatorcontrib>Cui, Dong-Mei</creatorcontrib><title>Ruthenium-catalyzed -alkylation of amino-1,3,5-triazines using alcohols</title><title>New journal of chemistry</title><description>An efficient ruthenium-catalyzed
N
-alkylation of amino 1,3,5-triazines with alcohols was achieved
via
a BH/HA strategy. Following this simple, facile, and high atom economical protocol, a broad range of products was prepared in moderate to good yields and heterocyclic or benzylic alcohols containing various functionalities were tolerated. The application of the reaction is also further demonstrated by the synthesis of alkylated secondary amine-1,3,5-triazines from olefinated amino-1,3,5-triazines and alcohols
via
a one pot
N
-alkylation and reductive reactions.
An efficient ruthenium-catalyzed
N
-alkylation of amino-1,3,5-triazines with alcohols was achieved
via
BH/HA strategy.</description><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjrsKwjAUQIMoWB-Lu5APMJpr2khn8TGLe7n0YVPTRJJ0aL9eB8HR6Rw4yyFkBXwLXKS7AkzDBYDMRyQCIVOW7iWMPw5xzHgSyymZed9wDnCQEJHLrQt1aVTXshwD6n4oC8pQP3uNQVlDbUWxVcYy2IhNwoJTOChTetp5ZR4UdW5rq_2CTCrUvlx-OSfr8-l-vDLn8-zlVIuuz3534l9_A3RfPS4</recordid><startdate>20210913</startdate><enddate>20210913</enddate><creator>Zhao, Junna</creator><creator>Zhong, Pengzhen</creator><creator>Xie, Zhongpao</creator><creator>Zhou, Wei</creator><creator>Zhang, Chen</creator><creator>Cui, Dong-Mei</creator><scope/></search><sort><creationdate>20210913</creationdate><title>Ruthenium-catalyzed -alkylation of amino-1,3,5-triazines using alcohols</title><author>Zhao, Junna ; Zhong, Pengzhen ; Xie, Zhongpao ; Zhou, Wei ; Zhang, Chen ; Cui, Dong-Mei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d1nj03116c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2021</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhao, Junna</creatorcontrib><creatorcontrib>Zhong, Pengzhen</creatorcontrib><creatorcontrib>Xie, Zhongpao</creatorcontrib><creatorcontrib>Zhou, Wei</creatorcontrib><creatorcontrib>Zhang, Chen</creatorcontrib><creatorcontrib>Cui, Dong-Mei</creatorcontrib><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhao, Junna</au><au>Zhong, Pengzhen</au><au>Xie, Zhongpao</au><au>Zhou, Wei</au><au>Zhang, Chen</au><au>Cui, Dong-Mei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ruthenium-catalyzed -alkylation of amino-1,3,5-triazines using alcohols</atitle><jtitle>New journal of chemistry</jtitle><date>2021-09-13</date><risdate>2021</risdate><volume>45</volume><issue>35</issue><spage>15776</spage><epage>15779</epage><pages>15776-15779</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>An efficient ruthenium-catalyzed
N
-alkylation of amino 1,3,5-triazines with alcohols was achieved
via
a BH/HA strategy. Following this simple, facile, and high atom economical protocol, a broad range of products was prepared in moderate to good yields and heterocyclic or benzylic alcohols containing various functionalities were tolerated. The application of the reaction is also further demonstrated by the synthesis of alkylated secondary amine-1,3,5-triazines from olefinated amino-1,3,5-triazines and alcohols
via
a one pot
N
-alkylation and reductive reactions.
An efficient ruthenium-catalyzed
N
-alkylation of amino-1,3,5-triazines with alcohols was achieved
via
BH/HA strategy.</abstract><doi>10.1039/d1nj03116c</doi><tpages>4</tpages></addata></record> |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
title | Ruthenium-catalyzed -alkylation of amino-1,3,5-triazines using alcohols |
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