Kinetic square scheme in oxygen-redox battery electrodes
Integrating an anionic-redox (or oxygen-redox) capacity with a conventional cationic-redox capacity is a promising strategy for large-capacity battery cathodes exceeding present technical limits. However, most oxygen-redox cathodes exhibit a large charge/discharge voltage hysteresis (>0.5 V), res...
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| Veröffentlicht in: | Energy & environmental science 2022-06, Vol.15 (6), p.2591-26 |
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| creator | Kawai, Kosuke Shi, Xiang-Mei Takenaka, Norio Jang, Jeonguk de Boisse, Benoit Mortemard Tsuchimoto, Akihisa Asakura, Daisuke Kikkawa, Jun Nakayama, Masanobu Okubo, Masashi Yamada, Atsuo |
| description | Integrating an anionic-redox (or oxygen-redox) capacity with a conventional cationic-redox capacity is a promising strategy for large-capacity battery cathodes exceeding present technical limits. However, most oxygen-redox cathodes exhibit a large charge/discharge voltage hysteresis (>0.5 V), resulting in poor energy efficiency and impractical implementation. Here, we show that nonpolarizing O
−
↔ O
2−
(4.4 V
vs.
Li/Li
+
) and polarizing O
2
2−
→ O
2−
(3.3 V
vs.
Li/Li
+
) coexist and kinetically compete in O2-type Li
1.12-
y
Ni
0.17
Mn
0.71
O
2
. The oxygen-redox reaction is described as a square scheme, involving bond-forming 2O
−
→ O
2
2−
and bond-cleaving O
2
4
→ 2O
2−
processes, where preventing the formation of O
2
2−
is essential to realize non-polarizing and energy-efficient oxygen-redox reactions.
Kinetic formation of the peroxo-like O
2
2−
dimer is identified as the origin of a voltage hysteresis in oxygen-redox battery electrodes. |
| doi_str_mv | 10.1039/d1ee03503g |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_d1ee03503g</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2676566712</sourcerecordid><originalsourceid>FETCH-LOGICAL-c313t-5a7da2da9b44ad5039d676f8dccaacf9fc4d0a99bfd2a3a0309ad3a2ef2ddac73</originalsourceid><addsrcrecordid>eNpFkEtLw0AUhQdRsFY37oWAOyE6j2Sms5Raq1hwo-twM_dOTWmTdiaB9t8bjY_VPYuPcy4fY5eC3wqu7B0KIq5yrpZHbCRMnqW54fr4N2srT9lZjCvOteTGjtjkpaqprVwSdx0ESqL7oA0lVZ00-8OS6jQQNvukhLalcEhoTa4NDVI8Zyce1pEufu6YvT_O3qZP6eJ1_jy9X6ROCdWmORgEiWDLLAPsH7OojfYTdA7AeetdhhysLT1KUMAVt4AKJHmJCM6oMbseereh2XUU22LVdKHuJwvZN-VaGyF76magXGhiDOSLbag2EA6F4MWXmeJBzGbfZuY9fDXAIbo_7t-c-gQWOWEK</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2676566712</pqid></control><display><type>article</type><title>Kinetic square scheme in oxygen-redox battery electrodes</title><source>Royal Society Of Chemistry Journals</source><creator>Kawai, Kosuke ; Shi, Xiang-Mei ; Takenaka, Norio ; Jang, Jeonguk ; de Boisse, Benoit Mortemard ; Tsuchimoto, Akihisa ; Asakura, Daisuke ; Kikkawa, Jun ; Nakayama, Masanobu ; Okubo, Masashi ; Yamada, Atsuo</creator><creatorcontrib>Kawai, Kosuke ; Shi, Xiang-Mei ; Takenaka, Norio ; Jang, Jeonguk ; de Boisse, Benoit Mortemard ; Tsuchimoto, Akihisa ; Asakura, Daisuke ; Kikkawa, Jun ; Nakayama, Masanobu ; Okubo, Masashi ; Yamada, Atsuo</creatorcontrib><description>Integrating an anionic-redox (or oxygen-redox) capacity with a conventional cationic-redox capacity is a promising strategy for large-capacity battery cathodes exceeding present technical limits. However, most oxygen-redox cathodes exhibit a large charge/discharge voltage hysteresis (>0.5 V), resulting in poor energy efficiency and impractical implementation. Here, we show that nonpolarizing O
−
↔ O
2−
(4.4 V
vs.
Li/Li
+
) and polarizing O
2
2−
→ O
2−
(3.3 V
vs.
Li/Li
+
) coexist and kinetically compete in O2-type Li
1.12-
y
Ni
0.17
Mn
0.71
O
2
. The oxygen-redox reaction is described as a square scheme, involving bond-forming 2O
−
→ O
2
2−
and bond-cleaving O
2
4
→ 2O
2−
processes, where preventing the formation of O
2
2−
is essential to realize non-polarizing and energy-efficient oxygen-redox reactions.
Kinetic formation of the peroxo-like O
2
2−
dimer is identified as the origin of a voltage hysteresis in oxygen-redox battery electrodes.</description><identifier>ISSN: 1754-5692</identifier><identifier>EISSN: 1754-5706</identifier><identifier>DOI: 10.1039/d1ee03503g</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Cathodes ; Electrode polarization ; Energy efficiency ; Oxygen ; Rechargeable batteries ; Redox reactions</subject><ispartof>Energy & environmental science, 2022-06, Vol.15 (6), p.2591-26</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c313t-5a7da2da9b44ad5039d676f8dccaacf9fc4d0a99bfd2a3a0309ad3a2ef2ddac73</citedby><cites>FETCH-LOGICAL-c313t-5a7da2da9b44ad5039d676f8dccaacf9fc4d0a99bfd2a3a0309ad3a2ef2ddac73</cites><orcidid>0000-0003-0659-1844 ; 0000-0001-7813-4736 ; 0000-0002-7880-5701 ; 0000-0003-3198-2660 ; 0000-0001-7502-8858 ; 0000-0002-7741-5234 ; 0000-0002-5113-053X ; 0000-0003-3840-2198</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Kawai, Kosuke</creatorcontrib><creatorcontrib>Shi, Xiang-Mei</creatorcontrib><creatorcontrib>Takenaka, Norio</creatorcontrib><creatorcontrib>Jang, Jeonguk</creatorcontrib><creatorcontrib>de Boisse, Benoit Mortemard</creatorcontrib><creatorcontrib>Tsuchimoto, Akihisa</creatorcontrib><creatorcontrib>Asakura, Daisuke</creatorcontrib><creatorcontrib>Kikkawa, Jun</creatorcontrib><creatorcontrib>Nakayama, Masanobu</creatorcontrib><creatorcontrib>Okubo, Masashi</creatorcontrib><creatorcontrib>Yamada, Atsuo</creatorcontrib><title>Kinetic square scheme in oxygen-redox battery electrodes</title><title>Energy & environmental science</title><description>Integrating an anionic-redox (or oxygen-redox) capacity with a conventional cationic-redox capacity is a promising strategy for large-capacity battery cathodes exceeding present technical limits. However, most oxygen-redox cathodes exhibit a large charge/discharge voltage hysteresis (>0.5 V), resulting in poor energy efficiency and impractical implementation. Here, we show that nonpolarizing O
−
↔ O
2−
(4.4 V
vs.
Li/Li
+
) and polarizing O
2
2−
→ O
2−
(3.3 V
vs.
Li/Li
+
) coexist and kinetically compete in O2-type Li
1.12-
y
Ni
0.17
Mn
0.71
O
2
. The oxygen-redox reaction is described as a square scheme, involving bond-forming 2O
−
→ O
2
2−
and bond-cleaving O
2
4
→ 2O
2−
processes, where preventing the formation of O
2
2−
is essential to realize non-polarizing and energy-efficient oxygen-redox reactions.
Kinetic formation of the peroxo-like O
2
2−
dimer is identified as the origin of a voltage hysteresis in oxygen-redox battery electrodes.</description><subject>Cathodes</subject><subject>Electrode polarization</subject><subject>Energy efficiency</subject><subject>Oxygen</subject><subject>Rechargeable batteries</subject><subject>Redox reactions</subject><issn>1754-5692</issn><issn>1754-5706</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpFkEtLw0AUhQdRsFY37oWAOyE6j2Sms5Raq1hwo-twM_dOTWmTdiaB9t8bjY_VPYuPcy4fY5eC3wqu7B0KIq5yrpZHbCRMnqW54fr4N2srT9lZjCvOteTGjtjkpaqprVwSdx0ESqL7oA0lVZ00-8OS6jQQNvukhLalcEhoTa4NDVI8Zyce1pEufu6YvT_O3qZP6eJ1_jy9X6ROCdWmORgEiWDLLAPsH7OojfYTdA7AeetdhhysLT1KUMAVt4AKJHmJCM6oMbseereh2XUU22LVdKHuJwvZN-VaGyF76magXGhiDOSLbag2EA6F4MWXmeJBzGbfZuY9fDXAIbo_7t-c-gQWOWEK</recordid><startdate>20220615</startdate><enddate>20220615</enddate><creator>Kawai, Kosuke</creator><creator>Shi, Xiang-Mei</creator><creator>Takenaka, Norio</creator><creator>Jang, Jeonguk</creator><creator>de Boisse, Benoit Mortemard</creator><creator>Tsuchimoto, Akihisa</creator><creator>Asakura, Daisuke</creator><creator>Kikkawa, Jun</creator><creator>Nakayama, Masanobu</creator><creator>Okubo, Masashi</creator><creator>Yamada, Atsuo</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7ST</scope><scope>7TB</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>L7M</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0003-0659-1844</orcidid><orcidid>https://orcid.org/0000-0001-7813-4736</orcidid><orcidid>https://orcid.org/0000-0002-7880-5701</orcidid><orcidid>https://orcid.org/0000-0003-3198-2660</orcidid><orcidid>https://orcid.org/0000-0001-7502-8858</orcidid><orcidid>https://orcid.org/0000-0002-7741-5234</orcidid><orcidid>https://orcid.org/0000-0002-5113-053X</orcidid><orcidid>https://orcid.org/0000-0003-3840-2198</orcidid></search><sort><creationdate>20220615</creationdate><title>Kinetic square scheme in oxygen-redox battery electrodes</title><author>Kawai, Kosuke ; Shi, Xiang-Mei ; Takenaka, Norio ; Jang, Jeonguk ; de Boisse, Benoit Mortemard ; Tsuchimoto, Akihisa ; Asakura, Daisuke ; Kikkawa, Jun ; Nakayama, Masanobu ; Okubo, Masashi ; Yamada, Atsuo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c313t-5a7da2da9b44ad5039d676f8dccaacf9fc4d0a99bfd2a3a0309ad3a2ef2ddac73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Cathodes</topic><topic>Electrode polarization</topic><topic>Energy efficiency</topic><topic>Oxygen</topic><topic>Rechargeable batteries</topic><topic>Redox reactions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kawai, Kosuke</creatorcontrib><creatorcontrib>Shi, Xiang-Mei</creatorcontrib><creatorcontrib>Takenaka, Norio</creatorcontrib><creatorcontrib>Jang, Jeonguk</creatorcontrib><creatorcontrib>de Boisse, Benoit Mortemard</creatorcontrib><creatorcontrib>Tsuchimoto, Akihisa</creatorcontrib><creatorcontrib>Asakura, Daisuke</creatorcontrib><creatorcontrib>Kikkawa, Jun</creatorcontrib><creatorcontrib>Nakayama, Masanobu</creatorcontrib><creatorcontrib>Okubo, Masashi</creatorcontrib><creatorcontrib>Yamada, Atsuo</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Environment Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>Energy & environmental science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kawai, Kosuke</au><au>Shi, Xiang-Mei</au><au>Takenaka, Norio</au><au>Jang, Jeonguk</au><au>de Boisse, Benoit Mortemard</au><au>Tsuchimoto, Akihisa</au><au>Asakura, Daisuke</au><au>Kikkawa, Jun</au><au>Nakayama, Masanobu</au><au>Okubo, Masashi</au><au>Yamada, Atsuo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Kinetic square scheme in oxygen-redox battery electrodes</atitle><jtitle>Energy & environmental science</jtitle><date>2022-06-15</date><risdate>2022</risdate><volume>15</volume><issue>6</issue><spage>2591</spage><epage>26</epage><pages>2591-26</pages><issn>1754-5692</issn><eissn>1754-5706</eissn><abstract>Integrating an anionic-redox (or oxygen-redox) capacity with a conventional cationic-redox capacity is a promising strategy for large-capacity battery cathodes exceeding present technical limits. However, most oxygen-redox cathodes exhibit a large charge/discharge voltage hysteresis (>0.5 V), resulting in poor energy efficiency and impractical implementation. Here, we show that nonpolarizing O
−
↔ O
2−
(4.4 V
vs.
Li/Li
+
) and polarizing O
2
2−
→ O
2−
(3.3 V
vs.
Li/Li
+
) coexist and kinetically compete in O2-type Li
1.12-
y
Ni
0.17
Mn
0.71
O
2
. The oxygen-redox reaction is described as a square scheme, involving bond-forming 2O
−
→ O
2
2−
and bond-cleaving O
2
4
→ 2O
2−
processes, where preventing the formation of O
2
2−
is essential to realize non-polarizing and energy-efficient oxygen-redox reactions.
Kinetic formation of the peroxo-like O
2
2−
dimer is identified as the origin of a voltage hysteresis in oxygen-redox battery electrodes.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1ee03503g</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0003-0659-1844</orcidid><orcidid>https://orcid.org/0000-0001-7813-4736</orcidid><orcidid>https://orcid.org/0000-0002-7880-5701</orcidid><orcidid>https://orcid.org/0000-0003-3198-2660</orcidid><orcidid>https://orcid.org/0000-0001-7502-8858</orcidid><orcidid>https://orcid.org/0000-0002-7741-5234</orcidid><orcidid>https://orcid.org/0000-0002-5113-053X</orcidid><orcidid>https://orcid.org/0000-0003-3840-2198</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1754-5692 |
| ispartof | Energy & environmental science, 2022-06, Vol.15 (6), p.2591-26 |
| issn | 1754-5692 1754-5706 |
| language | eng |
| recordid | cdi_rsc_primary_d1ee03503g |
| source | Royal Society Of Chemistry Journals |
| subjects | Cathodes Electrode polarization Energy efficiency Oxygen Rechargeable batteries Redox reactions |
| title | Kinetic square scheme in oxygen-redox battery electrodes |
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