Evaluating electrochemical accessibility of 4f5d and 4f Ln() ions in (CHSiMe)Ln and (CMeH)Ln complexes

The reduction potentials (reported vs. Fc + /Fc) for a series of Cp′ 3 Ln complexes (Cp′ = C 5 H 4 SiMe 3 , Ln = lanthanide) were determined via electrochemistry in THF with [ n Bu 4 N][BPh 4 ] as the supporting electrolyte. The Ln( iii )/Ln( ii ) reduction potentials for Ln = Eu, Yb, Sm, and Tm (−1...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2021-10, Vol.5 (4), p.14384-14389
Hauptverfasser:	Trinh, Michael T, Wedal, Justin C, Evans, William J
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