Radical-initiated P,P-metathesis reactions of diphosphanes: evidence from experimental and computational studies

By combining the diphosphanes Ar 2 P-PAr 2 , where Ar = C 6 H 5 , 4-C 6 H 4 Me, 4-C 6 H 4 OMe, 3,5-C 6 H 3 (CF 3 ) 2 , it has been shown that P,P-metathesis generally occurs rapidly under ambient conditions. DFT calculations have shown that the stability of unsymmetrical diphosphanes Z 2 P-PZ′ 2 is...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2021-05, Vol.5 (2), p.794-714
Hauptverfasser:	Branfoot, Callum, Young, Tom A, Wass, Duncan F, Pringle, Paul G
Format:	Artikel
Sprache:	eng
Schlagworte:	Chloroform Dichloromethane Electronegativity Mathematical analysis Metathesis Photolysis
Online-Zugang:	Volltext
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