Synthesis and properties of azamonocyclic energetic materials with geminal explosophores

Diversity-oriented synthesis of energetic pyrimidine structures with geminal explosophoric groups of geminal dinitro and azido-nitro groups via a novel reductive cleavage and oxidative coupling strategy is reported. Fluorine has also been introduced for the first time based on the nucleophilic coupl...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2021-06, Vol.5 (24), p.8338-8348
Hauptverfasser:	Yang, Kaidi, Bi, Fuqiang, Xue, Qi, Huo, Huan, Bai, Chao, Zhang, Junlin, Wang, Bozhou
Format:	Artikel
Sprache:	eng
Schlagworte:	Ammonium perchlorates Coupling Crystallography Detonation Energetic materials Fluorine Heat of formation Mathematical analysis Oxidizing agents Pyrimidines Solid propellants Synthesis
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