Vibrational CD study on the solution phase structures of the MacMillan catalyst and its corresponding iminium ion

We demonstrate that VCD spectroscopy can reveal insights into the conformational preferences of the iminium ion obtained from MacMillan's imidazolidinone catalyst. For both the isolated and in situ generated iminium ion, the comparison of experimental and computed VCD spectra directly confirms...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2021-11, Vol.23 (44), p.25162-25169
Hauptverfasser:	Golub, Tino P, Merten, Christian
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysts Solvents Spectral signatures Spectrum analysis
Online-Zugang:	Volltext
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