Unusual binary aggregates of perylene bisimide revealed by their electronic transitions in helium nanodroplets and DFT calculations

The S1 ← S0 electronic transition of perylene bisimide (PBI) and its binary aggregates were investigated using a combination of helium nanodroplet isolation spectroscopy and computational methods. First, well-resolved vibronic bands of the PBI monomer obtained under the superfluid helium nanodroplet...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2021-06, Vol.23 (25), p.13862-13872
Hauptverfasser:	Izadnia, S, LaForge, A. C, Stienkemeier, F, Cheeseman, James R, Bloino, Julien, Cheramy, J, Jäger, Wolfgang, Xu, Yunjie
Format:	Artikel
Sprache:	eng
Schlagworte:	Adducts Aggregates Anharmonicity Banded structure Dimers Dipole moments Fluids Helium Liquid helium Monomers Origins Spectrum analysis Superfluidity T shape
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