Dual vis-NIR emissive bimetallic naphthoates of Eu-Yb-Gd: a new approach toward Yb luminescence intensity increase through Eu → Yb energy transfer
Homo- and heteroligand mono-, bi-, and trimetallic lanthanide naphtoates Eu x Yb y Gd 1− x − y (naph) 3 (Phen) n ( n = 0, 1) were obtained and thoroughly investigated. Homoligand naphthoates of the new phase were obtained as anhydrous powders from water. The photophysical properties of the obtained...
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| Veröffentlicht in: | Physical chemistry chemical physics : PCCP 2021-03, Vol.23 (12), p.7213-7219 |
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| creator | Kim, Jae Hoon Lepnev, Leonid S Utochnikova, Valentina V |
| description | Homo- and heteroligand mono-, bi-, and trimetallic lanthanide naphtoates Eu
x
Yb
y
Gd
1−
x
−
y
(naph)
3
(Phen)
n
(
n
= 0, 1) were obtained and thoroughly investigated. Homoligand naphthoates of the new phase were obtained as anhydrous powders from water. The photophysical properties of the obtained compounds were studied in detail. The first example of Eu-to-Yb energy transfer was found in these systems. Careful selection of the metal ratio allowed a dual vis-NIR emissive complex with a ytterbium quantum yield of 1.5% to be obtained.
The first example of Eu-to-Yb energy transfer was found in bimetallic naphthoates. Dual vis-NIR emissive complexes with a ytterbium quantum yield of 1.5% were obtained. |
| doi_str_mv | 10.1039/d1cp00029b |
| format | Article |
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x
Yb
y
Gd
1−
x
−
y
(naph)
3
(Phen)
n
(
n
= 0, 1) were obtained and thoroughly investigated. Homoligand naphthoates of the new phase were obtained as anhydrous powders from water. The photophysical properties of the obtained compounds were studied in detail. The first example of Eu-to-Yb energy transfer was found in these systems. Careful selection of the metal ratio allowed a dual vis-NIR emissive complex with a ytterbium quantum yield of 1.5% to be obtained.
The first example of Eu-to-Yb energy transfer was found in bimetallic naphthoates. Dual vis-NIR emissive complexes with a ytterbium quantum yield of 1.5% were obtained.</description><identifier>ISSN: 1463-9076</identifier><identifier>EISSN: 1463-9084</identifier><identifier>DOI: 10.1039/d1cp00029b</identifier><identifier>PMID: 33876081</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Bimetals ; Energy transfer ; Gadolinium ; Ytterbium</subject><ispartof>Physical chemistry chemical physics : PCCP, 2021-03, Vol.23 (12), p.7213-7219</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c374t-ed3806dcbda0847d0a04359f5229867e89f3db628dc6a4152adcd64ef493505d3</citedby><cites>FETCH-LOGICAL-c374t-ed3806dcbda0847d0a04359f5229867e89f3db628dc6a4152adcd64ef493505d3</cites><orcidid>0000-0002-0830-1268</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/33876081$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Kim, Jae Hoon</creatorcontrib><creatorcontrib>Lepnev, Leonid S</creatorcontrib><creatorcontrib>Utochnikova, Valentina V</creatorcontrib><title>Dual vis-NIR emissive bimetallic naphthoates of Eu-Yb-Gd: a new approach toward Yb luminescence intensity increase through Eu → Yb energy transfer</title><title>Physical chemistry chemical physics : PCCP</title><addtitle>Phys Chem Chem Phys</addtitle><description>Homo- and heteroligand mono-, bi-, and trimetallic lanthanide naphtoates Eu
x
Yb
y
Gd
1−
x
−
y
(naph)
3
(Phen)
n
(
n
= 0, 1) were obtained and thoroughly investigated. Homoligand naphthoates of the new phase were obtained as anhydrous powders from water. The photophysical properties of the obtained compounds were studied in detail. The first example of Eu-to-Yb energy transfer was found in these systems. Careful selection of the metal ratio allowed a dual vis-NIR emissive complex with a ytterbium quantum yield of 1.5% to be obtained.
The first example of Eu-to-Yb energy transfer was found in bimetallic naphthoates. Dual vis-NIR emissive complexes with a ytterbium quantum yield of 1.5% were obtained.</description><subject>Bimetals</subject><subject>Energy transfer</subject><subject>Gadolinium</subject><subject>Ytterbium</subject><issn>1463-9076</issn><issn>1463-9084</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpdkcFu1TAQRS1ERUthwx5kiU2FFLDj2EnY0dfSVqoAIVh0FU3sSeMqcYLttHo_wAegfmG_BJdXHhKrGWnOXM2dS8gLzt5yJup3huuZMZbX7SOyxwslsppVxeNtX6pd8jSEq8RwycUTsitEVSpW8T1ye7TAQK9tyD6dfaU42hDsNdLWjhhhGKymDuY-9hNEDHTq6PGSXbTZiXlPgTq8oTDPfgLd0zjdgDf0oqXDMlqHQaPTSK2L6IKN69RpjxCQxt5Py2WfpOjdz1_3G-jQX65p9OBCh_4Z2elgCPj8oe6T7x-Pv61Os_PPJ2erD-eZFmURMzSiYsro1kDyWxoGrBCy7mSe15Uqsao7YVqVV0YrKLjMwWijCuyKWkgmjdgnBxvdZOHHgiE2yb_GYQCH0xKaXHKpKqVykdDX_6FX0-Jdui5R6cNSMq4S9WZDaT-F4LFrZm9H8OuGs-Y-q-aIr778yeowwa8eJJd2RLNF_4aTgJcbwAe9nf4LW_wG-5-aIA</recordid><startdate>20210328</startdate><enddate>20210328</enddate><creator>Kim, Jae Hoon</creator><creator>Lepnev, Leonid S</creator><creator>Utochnikova, Valentina V</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-0830-1268</orcidid></search><sort><creationdate>20210328</creationdate><title>Dual vis-NIR emissive bimetallic naphthoates of Eu-Yb-Gd: a new approach toward Yb luminescence intensity increase through Eu → Yb energy transfer</title><author>Kim, Jae Hoon ; Lepnev, Leonid S ; Utochnikova, Valentina V</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c374t-ed3806dcbda0847d0a04359f5229867e89f3db628dc6a4152adcd64ef493505d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Bimetals</topic><topic>Energy transfer</topic><topic>Gadolinium</topic><topic>Ytterbium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Jae Hoon</creatorcontrib><creatorcontrib>Lepnev, Leonid S</creatorcontrib><creatorcontrib>Utochnikova, Valentina V</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Physical chemistry chemical physics : PCCP</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Jae Hoon</au><au>Lepnev, Leonid S</au><au>Utochnikova, Valentina V</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dual vis-NIR emissive bimetallic naphthoates of Eu-Yb-Gd: a new approach toward Yb luminescence intensity increase through Eu → Yb energy transfer</atitle><jtitle>Physical chemistry chemical physics : PCCP</jtitle><addtitle>Phys Chem Chem Phys</addtitle><date>2021-03-28</date><risdate>2021</risdate><volume>23</volume><issue>12</issue><spage>7213</spage><epage>7219</epage><pages>7213-7219</pages><issn>1463-9076</issn><eissn>1463-9084</eissn><abstract>Homo- and heteroligand mono-, bi-, and trimetallic lanthanide naphtoates Eu
x
Yb
y
Gd
1−
x
−
y
(naph)
3
(Phen)
n
(
n
= 0, 1) were obtained and thoroughly investigated. Homoligand naphthoates of the new phase were obtained as anhydrous powders from water. The photophysical properties of the obtained compounds were studied in detail. The first example of Eu-to-Yb energy transfer was found in these systems. Careful selection of the metal ratio allowed a dual vis-NIR emissive complex with a ytterbium quantum yield of 1.5% to be obtained.
The first example of Eu-to-Yb energy transfer was found in bimetallic naphthoates. Dual vis-NIR emissive complexes with a ytterbium quantum yield of 1.5% were obtained.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>33876081</pmid><doi>10.1039/d1cp00029b</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-0830-1268</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1463-9076 |
| ispartof | Physical chemistry chemical physics : PCCP, 2021-03, Vol.23 (12), p.7213-7219 |
| issn | 1463-9076 1463-9084 |
| language | eng |
| recordid | cdi_rsc_primary_d1cp00029b |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Bimetals Energy transfer Gadolinium Ytterbium |
| title | Dual vis-NIR emissive bimetallic naphthoates of Eu-Yb-Gd: a new approach toward Yb luminescence intensity increase through Eu → Yb energy transfer |
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