Pair of chiral molecular ladders and successive hydration in single-crystal-to-single-crystal mode

Unusual successive two-step crystallization of a pair of chiral coordination polymers was carried out. Self-assembly of Zn(NO 3 ) 2 with a pair of chiral C 3 -symmetric tridentate N-donor ligands (1 S ,2 R -L and 1 R ,2 S -L) produces single crystals consisting of chiral enantiomeric 1D ladder coord...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:CrystEngComm 2021-12, Vol.23 (48), p.8546-8552
Hauptverfasser: Park, Junmyeong, Kim, Dongwon, Kim, Dongwook, Jung, Ok-Sang
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 8552
container_issue 48
container_start_page 8546
container_title CrystEngComm
container_volume 23
creator Park, Junmyeong
Kim, Dongwon
Kim, Dongwook
Jung, Ok-Sang
description Unusual successive two-step crystallization of a pair of chiral coordination polymers was carried out. Self-assembly of Zn(NO 3 ) 2 with a pair of chiral C 3 -symmetric tridentate N-donor ligands (1 S ,2 R -L and 1 R ,2 S -L) produces single crystals consisting of chiral enantiomeric 1D ladder coordination polymers, CH 2 Cl 2 ·2CH 3 CN@[Zn 3 (NO 3 ) 6 (1 S ,2 R -L) 2 ] and CH 2 Cl 2 ·2CH 3 CN@[Zn 3 (NO 3 ) 6 (1 R ,2 S -L) 2 ], after which the single crystals are transformed into new crystals in their hydrated forms, 2CH 3 CN@[Zn 3 (NO 3 ) 6 (1 S ,2 R -L) 2 (H 2 O) 2 ] and 2CH 3 CN@[Zn 3 (NO 3 ) 6 (1 R ,2 S -L) 2 (H 2 O) 2 ], respectively, under the moisture condition, in the single-crystal-to-single-crystal (SCSC) mode. The crystals consist of hexagonally packed chiral 1D coordination polymers in an enantiomeric arrangement, and their hydration shows a subtle difference depending on the chirality. Self-assembly of Zn(NO 3 ) 2 with a pair of new tridentate chiral Ls produced a pair of chiral ladder-type 1D coordination polymers, where crystals were transformed into different hydrated products of zigzag 1Ds depending on chirality in the SCSC mode.
doi_str_mv 10.1039/d1ce01332g
format Article
fullrecord <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_d1ce01332g</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2609948629</sourcerecordid><originalsourceid>FETCH-LOGICAL-c281t-feb5aa86873f949c5e2cd5d383d5c05a1578585dc8e3e7840a57fb909f7172fb3</originalsourceid><addsrcrecordid>eNpVkM9LwzAYhoMoOKcX70LAmxBNmqZNjjLnFAZ60HNJky9bRtfMpBX631ud-OP0vXw8vC88CJ0zes0oVzeWGaCM82x1gCYsLwoiKeeHf_IxOklpQynLGaMTVD9rH3Fw2Kx91A3ehgZM3-iIG20txIR1a3HqjYGU_Dvg9WCj7nxosW9x8u2qAWLikDrdkC6Q_5-xzsIpOnK6SXD2fafo9X7-Mnsgy6fF4-x2SUwmWUcc1EJrWciSO5UrIyAzVlguuRWGCs1EKYUU1kjgUMqcalG6WlHlSlZmruZTdLnv3cXw1kPqqk3oYztOVllBlcplkamRutpTJoaUIrhqF_1Wx6FitPp0WN2x2fzL4WKEL_ZwTOaH-3XMPwAT8G7g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2609948629</pqid></control><display><type>article</type><title>Pair of chiral molecular ladders and successive hydration in single-crystal-to-single-crystal mode</title><source>Royal Society Of Chemistry Journals</source><source>Alma/SFX Local Collection</source><creator>Park, Junmyeong ; Kim, Dongwon ; Kim, Dongwook ; Jung, Ok-Sang</creator><creatorcontrib>Park, Junmyeong ; Kim, Dongwon ; Kim, Dongwook ; Jung, Ok-Sang</creatorcontrib><description>Unusual successive two-step crystallization of a pair of chiral coordination polymers was carried out. Self-assembly of Zn(NO 3 ) 2 with a pair of chiral C 3 -symmetric tridentate N-donor ligands (1 S ,2 R -L and 1 R ,2 S -L) produces single crystals consisting of chiral enantiomeric 1D ladder coordination polymers, CH 2 Cl 2 ·2CH 3 CN@[Zn 3 (NO 3 ) 6 (1 S ,2 R -L) 2 ] and CH 2 Cl 2 ·2CH 3 CN@[Zn 3 (NO 3 ) 6 (1 R ,2 S -L) 2 ], after which the single crystals are transformed into new crystals in their hydrated forms, 2CH 3 CN@[Zn 3 (NO 3 ) 6 (1 S ,2 R -L) 2 (H 2 O) 2 ] and 2CH 3 CN@[Zn 3 (NO 3 ) 6 (1 R ,2 S -L) 2 (H 2 O) 2 ], respectively, under the moisture condition, in the single-crystal-to-single-crystal (SCSC) mode. The crystals consist of hexagonally packed chiral 1D coordination polymers in an enantiomeric arrangement, and their hydration shows a subtle difference depending on the chirality. Self-assembly of Zn(NO 3 ) 2 with a pair of new tridentate chiral Ls produced a pair of chiral ladder-type 1D coordination polymers, where crystals were transformed into different hydrated products of zigzag 1Ds depending on chirality in the SCSC mode.</description><identifier>ISSN: 1466-8033</identifier><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/d1ce01332g</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Chirality ; Coordination polymers ; Crystallization ; Dichloromethane ; Hydration ; Ladders ; Polymers ; Self-assembly ; Single crystals</subject><ispartof>CrystEngComm, 2021-12, Vol.23 (48), p.8546-8552</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c281t-feb5aa86873f949c5e2cd5d383d5c05a1578585dc8e3e7840a57fb909f7172fb3</citedby><cites>FETCH-LOGICAL-c281t-feb5aa86873f949c5e2cd5d383d5c05a1578585dc8e3e7840a57fb909f7172fb3</cites><orcidid>0000-0003-4432-371X ; 0000-0002-7218-457X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Park, Junmyeong</creatorcontrib><creatorcontrib>Kim, Dongwon</creatorcontrib><creatorcontrib>Kim, Dongwook</creatorcontrib><creatorcontrib>Jung, Ok-Sang</creatorcontrib><title>Pair of chiral molecular ladders and successive hydration in single-crystal-to-single-crystal mode</title><title>CrystEngComm</title><description>Unusual successive two-step crystallization of a pair of chiral coordination polymers was carried out. Self-assembly of Zn(NO 3 ) 2 with a pair of chiral C 3 -symmetric tridentate N-donor ligands (1 S ,2 R -L and 1 R ,2 S -L) produces single crystals consisting of chiral enantiomeric 1D ladder coordination polymers, CH 2 Cl 2 ·2CH 3 CN@[Zn 3 (NO 3 ) 6 (1 S ,2 R -L) 2 ] and CH 2 Cl 2 ·2CH 3 CN@[Zn 3 (NO 3 ) 6 (1 R ,2 S -L) 2 ], after which the single crystals are transformed into new crystals in their hydrated forms, 2CH 3 CN@[Zn 3 (NO 3 ) 6 (1 S ,2 R -L) 2 (H 2 O) 2 ] and 2CH 3 CN@[Zn 3 (NO 3 ) 6 (1 R ,2 S -L) 2 (H 2 O) 2 ], respectively, under the moisture condition, in the single-crystal-to-single-crystal (SCSC) mode. The crystals consist of hexagonally packed chiral 1D coordination polymers in an enantiomeric arrangement, and their hydration shows a subtle difference depending on the chirality. Self-assembly of Zn(NO 3 ) 2 with a pair of new tridentate chiral Ls produced a pair of chiral ladder-type 1D coordination polymers, where crystals were transformed into different hydrated products of zigzag 1Ds depending on chirality in the SCSC mode.</description><subject>Chirality</subject><subject>Coordination polymers</subject><subject>Crystallization</subject><subject>Dichloromethane</subject><subject>Hydration</subject><subject>Ladders</subject><subject>Polymers</subject><subject>Self-assembly</subject><subject>Single crystals</subject><issn>1466-8033</issn><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpVkM9LwzAYhoMoOKcX70LAmxBNmqZNjjLnFAZ60HNJky9bRtfMpBX631ud-OP0vXw8vC88CJ0zes0oVzeWGaCM82x1gCYsLwoiKeeHf_IxOklpQynLGaMTVD9rH3Fw2Kx91A3ehgZM3-iIG20txIR1a3HqjYGU_Dvg9WCj7nxosW9x8u2qAWLikDrdkC6Q_5-xzsIpOnK6SXD2fafo9X7-Mnsgy6fF4-x2SUwmWUcc1EJrWciSO5UrIyAzVlguuRWGCs1EKYUU1kjgUMqcalG6WlHlSlZmruZTdLnv3cXw1kPqqk3oYztOVllBlcplkamRutpTJoaUIrhqF_1Wx6FitPp0WN2x2fzL4WKEL_ZwTOaH-3XMPwAT8G7g</recordid><startdate>20211215</startdate><enddate>20211215</enddate><creator>Park, Junmyeong</creator><creator>Kim, Dongwon</creator><creator>Kim, Dongwook</creator><creator>Jung, Ok-Sang</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-4432-371X</orcidid><orcidid>https://orcid.org/0000-0002-7218-457X</orcidid></search><sort><creationdate>20211215</creationdate><title>Pair of chiral molecular ladders and successive hydration in single-crystal-to-single-crystal mode</title><author>Park, Junmyeong ; Kim, Dongwon ; Kim, Dongwook ; Jung, Ok-Sang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c281t-feb5aa86873f949c5e2cd5d383d5c05a1578585dc8e3e7840a57fb909f7172fb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chirality</topic><topic>Coordination polymers</topic><topic>Crystallization</topic><topic>Dichloromethane</topic><topic>Hydration</topic><topic>Ladders</topic><topic>Polymers</topic><topic>Self-assembly</topic><topic>Single crystals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Park, Junmyeong</creatorcontrib><creatorcontrib>Kim, Dongwon</creatorcontrib><creatorcontrib>Kim, Dongwook</creatorcontrib><creatorcontrib>Jung, Ok-Sang</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Park, Junmyeong</au><au>Kim, Dongwon</au><au>Kim, Dongwook</au><au>Jung, Ok-Sang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pair of chiral molecular ladders and successive hydration in single-crystal-to-single-crystal mode</atitle><jtitle>CrystEngComm</jtitle><date>2021-12-15</date><risdate>2021</risdate><volume>23</volume><issue>48</issue><spage>8546</spage><epage>8552</epage><pages>8546-8552</pages><issn>1466-8033</issn><eissn>1466-8033</eissn><abstract>Unusual successive two-step crystallization of a pair of chiral coordination polymers was carried out. Self-assembly of Zn(NO 3 ) 2 with a pair of chiral C 3 -symmetric tridentate N-donor ligands (1 S ,2 R -L and 1 R ,2 S -L) produces single crystals consisting of chiral enantiomeric 1D ladder coordination polymers, CH 2 Cl 2 ·2CH 3 CN@[Zn 3 (NO 3 ) 6 (1 S ,2 R -L) 2 ] and CH 2 Cl 2 ·2CH 3 CN@[Zn 3 (NO 3 ) 6 (1 R ,2 S -L) 2 ], after which the single crystals are transformed into new crystals in their hydrated forms, 2CH 3 CN@[Zn 3 (NO 3 ) 6 (1 S ,2 R -L) 2 (H 2 O) 2 ] and 2CH 3 CN@[Zn 3 (NO 3 ) 6 (1 R ,2 S -L) 2 (H 2 O) 2 ], respectively, under the moisture condition, in the single-crystal-to-single-crystal (SCSC) mode. The crystals consist of hexagonally packed chiral 1D coordination polymers in an enantiomeric arrangement, and their hydration shows a subtle difference depending on the chirality. Self-assembly of Zn(NO 3 ) 2 with a pair of new tridentate chiral Ls produced a pair of chiral ladder-type 1D coordination polymers, where crystals were transformed into different hydrated products of zigzag 1Ds depending on chirality in the SCSC mode.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d1ce01332g</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-4432-371X</orcidid><orcidid>https://orcid.org/0000-0002-7218-457X</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1466-8033
ispartof CrystEngComm, 2021-12, Vol.23 (48), p.8546-8552
issn 1466-8033
1466-8033
language eng
recordid cdi_rsc_primary_d1ce01332g
source Royal Society Of Chemistry Journals; Alma/SFX Local Collection
subjects Chirality
Coordination polymers
Crystallization
Dichloromethane
Hydration
Ladders
Polymers
Self-assembly
Single crystals
title Pair of chiral molecular ladders and successive hydration in single-crystal-to-single-crystal mode
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T11%3A25%3A59IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_rsc_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Pair%20of%20chiral%20molecular%20ladders%20and%20successive%20hydration%20in%20single-crystal-to-single-crystal%20mode&rft.jtitle=CrystEngComm&rft.au=Park,%20Junmyeong&rft.date=2021-12-15&rft.volume=23&rft.issue=48&rft.spage=8546&rft.epage=8552&rft.pages=8546-8552&rft.issn=1466-8033&rft.eissn=1466-8033&rft_id=info:doi/10.1039/d1ce01332g&rft_dat=%3Cproquest_rsc_p%3E2609948629%3C/proquest_rsc_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2609948629&rft_id=info:pmid/&rfr_iscdi=true