KBH: an environment-friendly reagent for the selective reduction of aldehydes and ketones to alcohols
Selective reduction of aldehydes and ketones to their corresponding alcohols with KB 3 H 8 , an air- and moisture-stable, nontoxic, and easy-to-handle reagent, in water and THF has been explored under an air atmosphere for the first time. Control experiments illustrated the good selectivity of KB 3...
Gespeichert in:
| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2021-11, Vol.57 (95), p.12776-12779 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 12779 |
|---|---|
| container_issue | 95 |
| container_start_page | 12776 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 57 |
| creator | Li, Xinying Mi, Tongge Guo, Wenjing Ruan, Zhongrui Guo, Yu Ma, Yan-Na Chen, Xuenian |
| description | Selective reduction of aldehydes and ketones to their corresponding alcohols with KB
3
H
8
, an air- and moisture-stable, nontoxic, and easy-to-handle reagent, in water and THF has been explored under an air atmosphere for the first time. Control experiments illustrated the good selectivity of KB
3
H
8
over NaBH
4
for the reduction of 4-acetylbenzaldehyde and aromatic keto esters.
Selective reduction of aldehydes and ketones to alcohols using KB
3
H
8
was achieved in water and THF. |
| doi_str_mv | 10.1039/d1cc05638g |
| format | Article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_d1cc05638g</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>d1cc05638g</sourcerecordid><originalsourceid>FETCH-rsc_primary_d1cc05638g3</originalsourceid><addsrcrecordid>eNqFjj0LwjAURYMo-Lm4C-8PVBvS1OqoKIKrg5uE5NVW00SSKPTfG0Fw9C33cA9cHiFTms5pylYLRaVMec6Ka4cMKMuzhGfFufthvkqWLON9MvT-lsajvBgQPG4OaxAG0LxqZ02DJiSlq9Eo3YJDcY0FlNZBqBA8apShfmE06hnJGrAlCK2wahX6OKTgjsGayMFGIW1ltR-TXim0x8k3R2S23522h8R5eXm4uhGuvfx-Z__8GzkYSNs</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>KBH: an environment-friendly reagent for the selective reduction of aldehydes and ketones to alcohols</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Li, Xinying ; Mi, Tongge ; Guo, Wenjing ; Ruan, Zhongrui ; Guo, Yu ; Ma, Yan-Na ; Chen, Xuenian</creator><creatorcontrib>Li, Xinying ; Mi, Tongge ; Guo, Wenjing ; Ruan, Zhongrui ; Guo, Yu ; Ma, Yan-Na ; Chen, Xuenian</creatorcontrib><description>Selective reduction of aldehydes and ketones to their corresponding alcohols with KB
3
H
8
, an air- and moisture-stable, nontoxic, and easy-to-handle reagent, in water and THF has been explored under an air atmosphere for the first time. Control experiments illustrated the good selectivity of KB
3
H
8
over NaBH
4
for the reduction of 4-acetylbenzaldehyde and aromatic keto esters.
Selective reduction of aldehydes and ketones to alcohols using KB
3
H
8
was achieved in water and THF.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d1cc05638g</identifier><ispartof>Chemical communications (Cambridge, England), 2021-11, Vol.57 (95), p.12776-12779</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Li, Xinying</creatorcontrib><creatorcontrib>Mi, Tongge</creatorcontrib><creatorcontrib>Guo, Wenjing</creatorcontrib><creatorcontrib>Ruan, Zhongrui</creatorcontrib><creatorcontrib>Guo, Yu</creatorcontrib><creatorcontrib>Ma, Yan-Na</creatorcontrib><creatorcontrib>Chen, Xuenian</creatorcontrib><title>KBH: an environment-friendly reagent for the selective reduction of aldehydes and ketones to alcohols</title><title>Chemical communications (Cambridge, England)</title><description>Selective reduction of aldehydes and ketones to their corresponding alcohols with KB
3
H
8
, an air- and moisture-stable, nontoxic, and easy-to-handle reagent, in water and THF has been explored under an air atmosphere for the first time. Control experiments illustrated the good selectivity of KB
3
H
8
over NaBH
4
for the reduction of 4-acetylbenzaldehyde and aromatic keto esters.
Selective reduction of aldehydes and ketones to alcohols using KB
3
H
8
was achieved in water and THF.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjj0LwjAURYMo-Lm4C-8PVBvS1OqoKIKrg5uE5NVW00SSKPTfG0Fw9C33cA9cHiFTms5pylYLRaVMec6Ka4cMKMuzhGfFufthvkqWLON9MvT-lsajvBgQPG4OaxAG0LxqZ02DJiSlq9Eo3YJDcY0FlNZBqBA8apShfmE06hnJGrAlCK2wahX6OKTgjsGayMFGIW1ltR-TXim0x8k3R2S23522h8R5eXm4uhGuvfx-Z__8GzkYSNs</recordid><startdate>20211130</startdate><enddate>20211130</enddate><creator>Li, Xinying</creator><creator>Mi, Tongge</creator><creator>Guo, Wenjing</creator><creator>Ruan, Zhongrui</creator><creator>Guo, Yu</creator><creator>Ma, Yan-Na</creator><creator>Chen, Xuenian</creator><scope/></search><sort><creationdate>20211130</creationdate><title>KBH: an environment-friendly reagent for the selective reduction of aldehydes and ketones to alcohols</title><author>Li, Xinying ; Mi, Tongge ; Guo, Wenjing ; Ruan, Zhongrui ; Guo, Yu ; Ma, Yan-Na ; Chen, Xuenian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d1cc05638g3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><creationdate>2021</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Li, Xinying</creatorcontrib><creatorcontrib>Mi, Tongge</creatorcontrib><creatorcontrib>Guo, Wenjing</creatorcontrib><creatorcontrib>Ruan, Zhongrui</creatorcontrib><creatorcontrib>Guo, Yu</creatorcontrib><creatorcontrib>Ma, Yan-Na</creatorcontrib><creatorcontrib>Chen, Xuenian</creatorcontrib><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Xinying</au><au>Mi, Tongge</au><au>Guo, Wenjing</au><au>Ruan, Zhongrui</au><au>Guo, Yu</au><au>Ma, Yan-Na</au><au>Chen, Xuenian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>KBH: an environment-friendly reagent for the selective reduction of aldehydes and ketones to alcohols</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2021-11-30</date><risdate>2021</risdate><volume>57</volume><issue>95</issue><spage>12776</spage><epage>12779</epage><pages>12776-12779</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Selective reduction of aldehydes and ketones to their corresponding alcohols with KB
3
H
8
, an air- and moisture-stable, nontoxic, and easy-to-handle reagent, in water and THF has been explored under an air atmosphere for the first time. Control experiments illustrated the good selectivity of KB
3
H
8
over NaBH
4
for the reduction of 4-acetylbenzaldehyde and aromatic keto esters.
Selective reduction of aldehydes and ketones to alcohols using KB
3
H
8
was achieved in water and THF.</abstract><doi>10.1039/d1cc05638g</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2021-11, Vol.57 (95), p.12776-12779 |
| issn | 1359-7345 1364-548X |
| language | |
| recordid | cdi_rsc_primary_d1cc05638g |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | KBH: an environment-friendly reagent for the selective reduction of aldehydes and ketones to alcohols |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-27T02%3A54%3A30IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-rsc&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=KBH:%20an%20environment-friendly%20reagent%20for%20the%20selective%20reduction%20of%20aldehydes%20and%20ketones%20to%20alcohols&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Li,%20Xinying&rft.date=2021-11-30&rft.volume=57&rft.issue=95&rft.spage=12776&rft.epage=12779&rft.pages=12776-12779&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/d1cc05638g&rft_dat=%3Crsc%3Ed1cc05638g%3C/rsc%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |