How stable can the pentanitrogen cation be in kinetics?

For the 22 year-old pentanitrogen cation N 5 + ( 01 ), we surprisingly found that the previously reported transition states (TSs) do not correspond to N 2 -extrusion. We located the real N 2 -extrusion TS, which can well reconcile the hitherto remaining inconsistency between the gas-phase and salt-l...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2021-05, Vol.57 (36), p.4432-4435
Hauptverfasser: Tian, Xiao, Bo, Xiao-xu, Ding, Yi-hong
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Sprache:eng
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