How stable can the pentanitrogen cation be in kinetics?

How stable can the pentanitrogen cation be in kinetics?

For the 22 year-old pentanitrogen cation N 5 + ( 01 ), we surprisingly found that the previously reported transition states (TSs) do not correspond to N 2 -extrusion. We located the real N 2 -extrusion TS, which can well reconcile the hitherto remaining inconsistency between the gas-phase and salt-l...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2021-05, Vol.57 (36), p.4432-4435
Hauptverfasser: Tian, Xiao, Bo, Xiao-xu, Ding, Yi-hong
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Sprache:eng
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Cations
Extrusion
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creator Tian, Xiao
Bo, Xiao-xu
Ding, Yi-hong
description For the 22 year-old pentanitrogen cation N 5 + ( 01 ), we surprisingly found that the previously reported transition states (TSs) do not correspond to N 2 -extrusion. We located the real N 2 -extrusion TS, which can well reconcile the hitherto remaining inconsistency between the gas-phase and salt-like forms of 01 both in structure and energetics. We for the first time located the real N 2 -extrusion transition state of the pentanitrogen cation N 5 + , which can reconcile the existing inconsistency between the gas-phase and salt-like kinetic stabilities both in structure and energetics.
doi_str_mv 10.1039/d1cc01250a
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subjects Cations
Extrusion
title How stable can the pentanitrogen cation be in kinetics?
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