Water-stable lanthanide-based metal-organic gel for the detection of organic amines and white-light emission
Highly luminous lanthanide metal-organic gels (Ln-MOGs) can act as fluorescent probes for the detection of organic amines and can also be used to build white-light emitting materials based on the different luminescent properties of lanthanide ions. Here, we reported a Ln-MOG constructed with a 3,5-d...
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| Veröffentlicht in: | Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2020-10, Vol.8 (39), p.13648-13654 |
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| container_title | Journal of materials chemistry. C, Materials for optical and electronic devices |
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| creator | Gu, Dongxu Yang, Weiting Lin, Duoyu Qin, Xudong Yang, Yonghang Wang, Fuxiang Pan, Qinhe Su, Zhongmin |
| description | Highly luminous lanthanide metal-organic gels (Ln-MOGs) can act as fluorescent probes for the detection of organic amines and can also be used to build white-light emitting materials based on the different luminescent properties of lanthanide ions. Here, we reported a Ln-MOG constructed with a 3,5-di(2′,4′-dicarboxylphenyl)benozoic acid (DPBA) ligand and Tb
3+
. Tb-MOG has an excellent fluorescence detection effect on organic amines including ethylenediamine, triethylamine, diisopropylamine and aniline in aqueous solution, and their detection limits reach a sub-ppm level. Considering the practicality, a Tb-MOG testing paper was prepared by a spin coating process, which can detect volatile organic amine vapors with good recyclability. Additionally, a single-phase white-light Tb
0.84
Eu
0.16
-MOG material was realized by
in situ
doping of Tb-MOG with Eu
3+
and reasonably utilizing the blue emission of DPBA.
A lanthanide metal-organic gel was prepared as a fluorescent probe for detecting organic amines and serving as a white-light emitting material based on the different luminescence characteristics of its lanthanide ions and organic ligands. |
| doi_str_mv | 10.1039/d0tc03266b |
| format | Article |
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3+
. Tb-MOG has an excellent fluorescence detection effect on organic amines including ethylenediamine, triethylamine, diisopropylamine and aniline in aqueous solution, and their detection limits reach a sub-ppm level. Considering the practicality, a Tb-MOG testing paper was prepared by a spin coating process, which can detect volatile organic amine vapors with good recyclability. Additionally, a single-phase white-light Tb
0.84
Eu
0.16
-MOG material was realized by
in situ
doping of Tb-MOG with Eu
3+
and reasonably utilizing the blue emission of DPBA.
A lanthanide metal-organic gel was prepared as a fluorescent probe for detecting organic amines and serving as a white-light emitting material based on the different luminescence characteristics of its lanthanide ions and organic ligands.</description><identifier>ISSN: 2050-7526</identifier><identifier>EISSN: 2050-7534</identifier><identifier>DOI: 10.1039/d0tc03266b</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Amines ; Aniline ; Aqueous solutions ; Construction materials ; Ethylenediamine ; Fluorescent indicators ; Gels ; Light emission ; Optical properties ; Recyclability ; Spin coating ; Triethylamine ; White light</subject><ispartof>Journal of materials chemistry. C, Materials for optical and electronic devices, 2020-10, Vol.8 (39), p.13648-13654</ispartof><rights>Copyright Royal Society of Chemistry 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c344t-40b120751f4994572a5cd5b25a844ff9fe0357933355f144855cb0b40104225d3</citedby><cites>FETCH-LOGICAL-c344t-40b120751f4994572a5cd5b25a844ff9fe0357933355f144855cb0b40104225d3</cites><orcidid>0000-0002-7335-3814 ; 0000-0002-8875-2762 ; 0000-0003-0156-7191</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Gu, Dongxu</creatorcontrib><creatorcontrib>Yang, Weiting</creatorcontrib><creatorcontrib>Lin, Duoyu</creatorcontrib><creatorcontrib>Qin, Xudong</creatorcontrib><creatorcontrib>Yang, Yonghang</creatorcontrib><creatorcontrib>Wang, Fuxiang</creatorcontrib><creatorcontrib>Pan, Qinhe</creatorcontrib><creatorcontrib>Su, Zhongmin</creatorcontrib><title>Water-stable lanthanide-based metal-organic gel for the detection of organic amines and white-light emission</title><title>Journal of materials chemistry. C, Materials for optical and electronic devices</title><description>Highly luminous lanthanide metal-organic gels (Ln-MOGs) can act as fluorescent probes for the detection of organic amines and can also be used to build white-light emitting materials based on the different luminescent properties of lanthanide ions. Here, we reported a Ln-MOG constructed with a 3,5-di(2′,4′-dicarboxylphenyl)benozoic acid (DPBA) ligand and Tb
3+
. Tb-MOG has an excellent fluorescence detection effect on organic amines including ethylenediamine, triethylamine, diisopropylamine and aniline in aqueous solution, and their detection limits reach a sub-ppm level. Considering the practicality, a Tb-MOG testing paper was prepared by a spin coating process, which can detect volatile organic amine vapors with good recyclability. Additionally, a single-phase white-light Tb
0.84
Eu
0.16
-MOG material was realized by
in situ
doping of Tb-MOG with Eu
3+
and reasonably utilizing the blue emission of DPBA.
A lanthanide metal-organic gel was prepared as a fluorescent probe for detecting organic amines and serving as a white-light emitting material based on the different luminescence characteristics of its lanthanide ions and organic ligands.</description><subject>Amines</subject><subject>Aniline</subject><subject>Aqueous solutions</subject><subject>Construction materials</subject><subject>Ethylenediamine</subject><subject>Fluorescent indicators</subject><subject>Gels</subject><subject>Light emission</subject><subject>Optical properties</subject><subject>Recyclability</subject><subject>Spin coating</subject><subject>Triethylamine</subject><subject>White light</subject><issn>2050-7526</issn><issn>2050-7534</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kMtLAzEQxoMoWGov3oWINyGa5z6OWp9Q8FLxuGSTSXfLPmoSEf97o9V6cy4zzPdjPuZD6JjRC0ZFeWlpNFTwLKv30IRTRUmuhNzfzTw7RLMQ1jRVwbIiKyeoe9ERPAlR1x3gTg-x0UNrgdQ6gMU9RN2R0a_S0uAVdNiNHscGsIUIJrbjgEeHfwHdtwMErAeL35s2AunaVRMx9G0ICT1CB053AWY_fYqe726X8weyeLp_nF8tiBFSRiJpzTjNFXOyLKXKuVbGqporXUjpXOmACpWXQgilHJOyUMrUtJaUUcm5smKKzrZ3N358fYMQq_X45odkWXGpWHpesjxR51vK-DEED67a-LbX_qNitPoKtLqhy_l3oNcJPtnCPpgd9xd40k__06uNdeITgPN8lw</recordid><startdate>20201021</startdate><enddate>20201021</enddate><creator>Gu, Dongxu</creator><creator>Yang, Weiting</creator><creator>Lin, Duoyu</creator><creator>Qin, Xudong</creator><creator>Yang, Yonghang</creator><creator>Wang, Fuxiang</creator><creator>Pan, Qinhe</creator><creator>Su, Zhongmin</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-7335-3814</orcidid><orcidid>https://orcid.org/0000-0002-8875-2762</orcidid><orcidid>https://orcid.org/0000-0003-0156-7191</orcidid></search><sort><creationdate>20201021</creationdate><title>Water-stable lanthanide-based metal-organic gel for the detection of organic amines and white-light emission</title><author>Gu, Dongxu ; Yang, Weiting ; Lin, Duoyu ; Qin, Xudong ; Yang, Yonghang ; Wang, Fuxiang ; Pan, Qinhe ; Su, Zhongmin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c344t-40b120751f4994572a5cd5b25a844ff9fe0357933355f144855cb0b40104225d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Amines</topic><topic>Aniline</topic><topic>Aqueous solutions</topic><topic>Construction materials</topic><topic>Ethylenediamine</topic><topic>Fluorescent indicators</topic><topic>Gels</topic><topic>Light emission</topic><topic>Optical properties</topic><topic>Recyclability</topic><topic>Spin coating</topic><topic>Triethylamine</topic><topic>White light</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gu, Dongxu</creatorcontrib><creatorcontrib>Yang, Weiting</creatorcontrib><creatorcontrib>Lin, Duoyu</creatorcontrib><creatorcontrib>Qin, Xudong</creatorcontrib><creatorcontrib>Yang, Yonghang</creatorcontrib><creatorcontrib>Wang, Fuxiang</creatorcontrib><creatorcontrib>Pan, Qinhe</creatorcontrib><creatorcontrib>Su, Zhongmin</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gu, Dongxu</au><au>Yang, Weiting</au><au>Lin, Duoyu</au><au>Qin, Xudong</au><au>Yang, Yonghang</au><au>Wang, Fuxiang</au><au>Pan, Qinhe</au><au>Su, Zhongmin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Water-stable lanthanide-based metal-organic gel for the detection of organic amines and white-light emission</atitle><jtitle>Journal of materials chemistry. C, Materials for optical and electronic devices</jtitle><date>2020-10-21</date><risdate>2020</risdate><volume>8</volume><issue>39</issue><spage>13648</spage><epage>13654</epage><pages>13648-13654</pages><issn>2050-7526</issn><eissn>2050-7534</eissn><abstract>Highly luminous lanthanide metal-organic gels (Ln-MOGs) can act as fluorescent probes for the detection of organic amines and can also be used to build white-light emitting materials based on the different luminescent properties of lanthanide ions. Here, we reported a Ln-MOG constructed with a 3,5-di(2′,4′-dicarboxylphenyl)benozoic acid (DPBA) ligand and Tb
3+
. Tb-MOG has an excellent fluorescence detection effect on organic amines including ethylenediamine, triethylamine, diisopropylamine and aniline in aqueous solution, and their detection limits reach a sub-ppm level. Considering the practicality, a Tb-MOG testing paper was prepared by a spin coating process, which can detect volatile organic amine vapors with good recyclability. Additionally, a single-phase white-light Tb
0.84
Eu
0.16
-MOG material was realized by
in situ
doping of Tb-MOG with Eu
3+
and reasonably utilizing the blue emission of DPBA.
A lanthanide metal-organic gel was prepared as a fluorescent probe for detecting organic amines and serving as a white-light emitting material based on the different luminescence characteristics of its lanthanide ions and organic ligands.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d0tc03266b</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-7335-3814</orcidid><orcidid>https://orcid.org/0000-0002-8875-2762</orcidid><orcidid>https://orcid.org/0000-0003-0156-7191</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2050-7526 |
| ispartof | Journal of materials chemistry. C, Materials for optical and electronic devices, 2020-10, Vol.8 (39), p.13648-13654 |
| issn | 2050-7526 2050-7534 |
| language | eng |
| recordid | cdi_rsc_primary_d0tc03266b |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Amines Aniline Aqueous solutions Construction materials Ethylenediamine Fluorescent indicators Gels Light emission Optical properties Recyclability Spin coating Triethylamine White light |
| title | Water-stable lanthanide-based metal-organic gel for the detection of organic amines and white-light emission |
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