Zinc ion trapping in a cellulose hydrogel as a solid electrolyte for a safe and flexible supercapacitor

A flexible zinc-ion hybrid supercapacitor (ZHS) was constructed using a solid-state cellulose hydrogel electrolyte containing a high concentration of ZnCl 2 . This biodegradable cellulose hydrogel electrolyte can afford a wide electrochemical potential window and excellent ionic conductivity, result...

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2020-07, Vol.8 (25), p.12314-12318
Hauptverfasser: Yang, Lvye, Song, Lian, Feng, Yi, Cao, Mengjue, Zhang, Pengcheng, Zhang, Xiong-Fei, Yao, Jianfeng
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container_end_page 12318
container_issue 25
container_start_page 12314
container_title Journal of materials chemistry. A, Materials for energy and sustainability
container_volume 8
creator Yang, Lvye
Song, Lian
Feng, Yi
Cao, Mengjue
Zhang, Pengcheng
Zhang, Xiong-Fei
Yao, Jianfeng
description A flexible zinc-ion hybrid supercapacitor (ZHS) was constructed using a solid-state cellulose hydrogel electrolyte containing a high concentration of ZnCl 2 . This biodegradable cellulose hydrogel electrolyte can afford a wide electrochemical potential window and excellent ionic conductivity, resulting in a ZHS with an extremely high capacity of 193 mA h g −1 , an energy density of 192 W h kg −1 , and a power density of 16 976 W kg −1 . The flexible ZHS also shows excellent stability and can work at low temperature of −20 °C. This work progresses the field of Zn-based electrochemical energy storage devices and gives a meaningful guide for the design of solid-state electrolytes. High concentrated ZnCl 2 is trapped in a biodegradable cellulose hydrogel as electrolyte for a flexible zinc-ion hybrid supercapacitor (ZHS). Such ZHS has a wide electrochemical potential window and extremely high energy/power density.
doi_str_mv 10.1039/d0ta04360e
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source Royal Society Of Chemistry Journals
subjects Biodegradability
Biodegradation
Cellulose
Electrochemical potential
Electrochemistry
Electrolytes
Energy storage
Flux density
Hydrogels
Ion currents
Low temperature
Molten salt electrolytes
Solid electrolytes
Solid state
Supercapacitors
Zinc chloride
title Zinc ion trapping in a cellulose hydrogel as a solid electrolyte for a safe and flexible supercapacitor
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