A yolk-shell structured metal-organic framework with encapsulated iron-porphyrin and its derived bimetallic nitrogen-doped porous carbon for an efficient oxygen reduction reaction

A yolk-shell structured metal-organic framework (MOF) with encapsulated 5,10,15,20-tetraphenylporphyrinatoiron (FeTPP) in a zeolitic imidazolate framework (ZIF)-L-ZIF-8 is reported. ZIF-L with leaf-like morphology is used as a core, and FeTPP molecules will induce the partial decomposition of ZIF-L....

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Veröffentlicht in:	Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2020-05, Vol.8 (19), p.9536-9544
Hauptverfasser:	Zhang, Chaochao, Yang, Hao, Zhong, Dan, Xu, Yang, Wang, Yanzhi, Yuan, Qi, Liang, Zuozhong, Wang, Bin, Zhang, Wei, Zheng, Haoquan, Cheng, Tao, Cao, Rui
Format:	Artikel
Sprache:	eng
Schlagworte:	Bimetals Carbon Chemical reduction Density functional theory Encapsulation Energy conversion Energy storage Free energy Heat of formation Iron Metal air batteries Metal-organic frameworks Morphology Nitrogen Oxygen reduction reactions Pyrolysis Shells (structural forms) Yolk Zeolites Zinc Zinc-oxygen batteries
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