Polymers with advanced structural and supramolecular features synthesized through topochemical polymerization
Polymers are an integral part of our daily life. Hence, there are constant efforts towards synthesizing novel polymers with unique properties. As the composition and packing of polymer chains influence polymer's properties, sophisticated control over the molecular and supramolecular structure o...
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Veröffentlicht in: | Chemical science (Cambridge) 2021-04, Vol.12 (15), p.5361-538 |
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creator | Hema, Kuntrapakam Ravi, Arthi Raju, Cijil Sureshan, Kana M |
description | Polymers are an integral part of our daily life. Hence, there are constant efforts towards synthesizing novel polymers with unique properties. As the composition and packing of polymer chains influence polymer's properties, sophisticated control over the molecular and supramolecular structure of the polymer helps tailor its properties as desired. However, such precise control
via
conventional solution-state synthesis is challenging. Topochemical polymerization (TP), a solvent- and catalyst-free reaction that occurs under the confinement of a crystal lattice, offers profound control over the molecular structure and supramolecular architecture of a polymer and usually results in ordered polymers. In particular, single-crystal-to-single-crystal (SCSC) TP is advantageous as we can correlate the structure and packing of polymer chains with their properties. By designing molecules appended with suitable reactive moieties and utilizing the principles of supramolecular chemistry to align them in a reactive orientation, the synthesis of higher-dimensional polymers and divergent topologies has been achieved
via
TP. Though there are a few reviews on TP in the literature, an exclusive review showcasing the topochemical synthesis of polymers with advanced structural features is not available. In this perspective, we present selected examples of the topochemical synthesis of organic polymers with sophisticated structures like ladders, tubular polymers, alternating copolymers, polymer blends, and other interesting topologies. We also detail some strategies adopted for obtaining distinct polymers from the same monomer. Finally, we highlight the main challenges and prospects for developing advanced polymers
via
TP and inspire future directions in this area.
This perspective showcases the potential of topochemical polymerization as an effective tool for synthesizing polymers with advanced molecular and supramolecular structures. |
doi_str_mv | 10.1039/d0sc07066a |
format | Article |
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via
conventional solution-state synthesis is challenging. Topochemical polymerization (TP), a solvent- and catalyst-free reaction that occurs under the confinement of a crystal lattice, offers profound control over the molecular structure and supramolecular architecture of a polymer and usually results in ordered polymers. In particular, single-crystal-to-single-crystal (SCSC) TP is advantageous as we can correlate the structure and packing of polymer chains with their properties. By designing molecules appended with suitable reactive moieties and utilizing the principles of supramolecular chemistry to align them in a reactive orientation, the synthesis of higher-dimensional polymers and divergent topologies has been achieved
via
TP. Though there are a few reviews on TP in the literature, an exclusive review showcasing the topochemical synthesis of polymers with advanced structural features is not available. In this perspective, we present selected examples of the topochemical synthesis of organic polymers with sophisticated structures like ladders, tubular polymers, alternating copolymers, polymer blends, and other interesting topologies. We also detail some strategies adopted for obtaining distinct polymers from the same monomer. Finally, we highlight the main challenges and prospects for developing advanced polymers
via
TP and inspire future directions in this area.
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via
conventional solution-state synthesis is challenging. Topochemical polymerization (TP), a solvent- and catalyst-free reaction that occurs under the confinement of a crystal lattice, offers profound control over the molecular structure and supramolecular architecture of a polymer and usually results in ordered polymers. In particular, single-crystal-to-single-crystal (SCSC) TP is advantageous as we can correlate the structure and packing of polymer chains with their properties. By designing molecules appended with suitable reactive moieties and utilizing the principles of supramolecular chemistry to align them in a reactive orientation, the synthesis of higher-dimensional polymers and divergent topologies has been achieved
via
TP. Though there are a few reviews on TP in the literature, an exclusive review showcasing the topochemical synthesis of polymers with advanced structural features is not available. In this perspective, we present selected examples of the topochemical synthesis of organic polymers with sophisticated structures like ladders, tubular polymers, alternating copolymers, polymer blends, and other interesting topologies. We also detail some strategies adopted for obtaining distinct polymers from the same monomer. Finally, we highlight the main challenges and prospects for developing advanced polymers
via
TP and inspire future directions in this area.
This perspective showcases the potential of topochemical polymerization as an effective tool for synthesizing polymers with advanced molecular and supramolecular structures.</description><subject>Chains (polymeric)</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Copolymers</subject><subject>Crystal lattices</subject><subject>Crystal structure</subject><subject>Ladders</subject><subject>Literature reviews</subject><subject>Molecular structure</subject><subject>Polymer blends</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Single crystals</subject><subject>Topology</subject><issn>2041-6520</issn><issn>2041-6539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpdkstLJDEQxoOsqKgX7y4NXhZhNOm8OhdBZt1dQVhBPYdMptqOdHd683AZ__qNOzr7yCWpql99VPEFoSOCzwim6nyJo8USC2G20F6NGZkJTtWHzbvGu-gwxidcDqWE13IH7VJGRCMbsoeGW9-vBgix-ulSV5nlsxktLKuYQrYpB9NXZixhnoIZfA829yZULZhSg1jF1Zg6iO6ltKQu-PzYVclP3nYwOFuap7W8ezHJ-fEAbbemj3D4du-jhy9X9_Nvs5vvX6_nlzczy-omzcAS0jTAWk4EFrU1ykom-aJkpKyVWciWSyqgbSRhtGUSKyYJNgshRQkV3UcXa90pLwZYWhhT2URPwQ0mrLQ3Tv9bGV2nH_2zbohUAr8KfHoTCP5Hhpj04KKFvjcj-Bx1zRnnSnAlC3ryH_rkcxjLeoUiXApRuEKdrikbfIwB2s0wBOtXI_VnfDf_beRlgT_-Pf4GfbetAMdrIES7qf75CfQXzGmlfA</recordid><startdate>20210421</startdate><enddate>20210421</enddate><creator>Hema, Kuntrapakam</creator><creator>Ravi, Arthi</creator><creator>Raju, Cijil</creator><creator>Sureshan, Kana M</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-9801-7772</orcidid><orcidid>https://orcid.org/0000-0002-8416-9764</orcidid><orcidid>https://orcid.org/0000-0002-6398-5383</orcidid><orcidid>https://orcid.org/0000-0002-4005-3655</orcidid></search><sort><creationdate>20210421</creationdate><title>Polymers with advanced structural and supramolecular features synthesized through topochemical polymerization</title><author>Hema, Kuntrapakam ; Ravi, Arthi ; Raju, Cijil ; Sureshan, Kana M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c428t-ec1188e4f516062ca9c7475be4f7729ab7f5736ef87143f47094710ab6763f493</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chains (polymeric)</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Copolymers</topic><topic>Crystal lattices</topic><topic>Crystal structure</topic><topic>Ladders</topic><topic>Literature reviews</topic><topic>Molecular structure</topic><topic>Polymer blends</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Single crystals</topic><topic>Topology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hema, Kuntrapakam</creatorcontrib><creatorcontrib>Ravi, Arthi</creatorcontrib><creatorcontrib>Raju, Cijil</creatorcontrib><creatorcontrib>Sureshan, Kana M</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Chemical science (Cambridge)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hema, Kuntrapakam</au><au>Ravi, Arthi</au><au>Raju, Cijil</au><au>Sureshan, Kana M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polymers with advanced structural and supramolecular features synthesized through topochemical polymerization</atitle><jtitle>Chemical science (Cambridge)</jtitle><addtitle>Chem Sci</addtitle><date>2021-04-21</date><risdate>2021</risdate><volume>12</volume><issue>15</issue><spage>5361</spage><epage>538</epage><pages>5361-538</pages><issn>2041-6520</issn><eissn>2041-6539</eissn><abstract>Polymers are an integral part of our daily life. Hence, there are constant efforts towards synthesizing novel polymers with unique properties. As the composition and packing of polymer chains influence polymer's properties, sophisticated control over the molecular and supramolecular structure of the polymer helps tailor its properties as desired. However, such precise control
via
conventional solution-state synthesis is challenging. Topochemical polymerization (TP), a solvent- and catalyst-free reaction that occurs under the confinement of a crystal lattice, offers profound control over the molecular structure and supramolecular architecture of a polymer and usually results in ordered polymers. In particular, single-crystal-to-single-crystal (SCSC) TP is advantageous as we can correlate the structure and packing of polymer chains with their properties. By designing molecules appended with suitable reactive moieties and utilizing the principles of supramolecular chemistry to align them in a reactive orientation, the synthesis of higher-dimensional polymers and divergent topologies has been achieved
via
TP. Though there are a few reviews on TP in the literature, an exclusive review showcasing the topochemical synthesis of polymers with advanced structural features is not available. In this perspective, we present selected examples of the topochemical synthesis of organic polymers with sophisticated structures like ladders, tubular polymers, alternating copolymers, polymer blends, and other interesting topologies. We also detail some strategies adopted for obtaining distinct polymers from the same monomer. Finally, we highlight the main challenges and prospects for developing advanced polymers
via
TP and inspire future directions in this area.
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subjects | Chains (polymeric) Chemical synthesis Chemistry Copolymers Crystal lattices Crystal structure Ladders Literature reviews Molecular structure Polymer blends Polymerization Polymers Single crystals Topology |
title | Polymers with advanced structural and supramolecular features synthesized through topochemical polymerization |
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