Photoisomerization of dicyanorhodanine-functionalized thiophenes

π-Conjugated oligomers functionalized with the popular dicyanorhodanine (RCN) electron acceptor are shown to be susceptible to photo-induced Z / E isomerization. The stereochemistry of two model RCN-functionalized thiophenes is confirmed by single crystal X-ray analysis and 2D NMR, and shown to be t...

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Veröffentlicht in:	Chemical science (Cambridge) 2020-10, Vol.11 (37), p.119-1197
Hauptverfasser:	Kornman, Cory T, Li, Lei, Weldeab, Asmerom O, Ghiviriga, Ion, Abboud, Khalil A, Castellano, Ronald K
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chromatography Crystallography Density functional theory Irradiation Isomerization Isomers NMR Nuclear magnetic resonance Oligomers Single crystals Stereochemistry Structural analysis Substrates Thin layer chromatography Thiophenes Two dimensional analysis Two dimensional models X ray analysis
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