Formation of a mixed-valence Cu()/Cu() metal-organic framework with the full light spectrum and high selectivity of CO photoreduction into CH

Based upon the hetero-N,O ligand of pyrimidine-5-carboxylic acid (Hpmc), a new semiconductive Cu( i )/Cu( ii ) mixed-valence MOF with the full light spectrum and a novel topology of {4 3 ·6 12 ·8 6 } 2 {4 3 ·6 3 } 2 {6 3 } 6 {6 4 ·8 2 } 3 , {(Cu 4 I 4 ) 2.5 [Cu 3 (μ 4 -O) (μ 3 -I) (pmc) 3 (Dabco) 3...

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Veröffentlicht in:	Chemical science (Cambridge) 2020-09, Vol.11 (37), p.1143-1148
Hauptverfasser:	Gao, Yajun, Zhang, Lei, Gu, Yuming, Zhang, Wenwei, Pan, Yi, Fang, Weihai, Ma, Jing, Lan, Ya-Qian, Bai, Junfeng
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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