Synthesis of cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tags as an efficient catalyst and its application for the synthesis of bicyclic -aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines
Cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tag [Co(TPPASO 3 H)]Cl was produced and catalyzed the synthesis of ortho -aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines. The synthesis of 2-amino-3-cyanopyridines by using [Co(TPPASO 3 H)]Cl proceeded via a coop...
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| Veröffentlicht in: | RSC advances 2020-07, Vol.1 (46), p.27824-27834 |
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| container_title | RSC advances |
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| creator | Dashteh, Mohammad Zolfigol, Mohammad Ali Khazaei, Ardeshir Baghery, Saeed Yarie, Meysam Makhdoomi, Sajjad Safaiee, Maliheh |
| description | Cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tag [Co(TPPASO
3
H)]Cl was produced and catalyzed the synthesis of
ortho
-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines. The synthesis of 2-amino-3-cyanopyridines by using [Co(TPPASO
3
H)]Cl proceeded
via
a cooperative vinylogous anomeric based oxidation mechanism. [Co(TPPASO
3
H)]Cl can be recycled and reused six times with a marginal decreasing of its catalytic activity.
ortho
-Aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines were synthesized by [Co(TPPASO
3
H)]Cl as an efficient pyridiniumporphyrazinato based catalyst. |
| doi_str_mv | 10.1039/d0ra02172e |
| format | Article |
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3
H)]Cl was produced and catalyzed the synthesis of
ortho
-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines. The synthesis of 2-amino-3-cyanopyridines by using [Co(TPPASO
3
H)]Cl proceeded
via
a cooperative vinylogous anomeric based oxidation mechanism. [Co(TPPASO
3
H)]Cl can be recycled and reused six times with a marginal decreasing of its catalytic activity.
ortho
-Aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines were synthesized by [Co(TPPASO
3
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3
H)]Cl was produced and catalyzed the synthesis of
ortho
-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines. The synthesis of 2-amino-3-cyanopyridines by using [Co(TPPASO
3
H)]Cl proceeded
via
a cooperative vinylogous anomeric based oxidation mechanism. [Co(TPPASO
3
H)]Cl can be recycled and reused six times with a marginal decreasing of its catalytic activity.
ortho
-Aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines were synthesized by [Co(TPPASO
3
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3
H)]Cl was produced and catalyzed the synthesis of
ortho
-aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines. The synthesis of 2-amino-3-cyanopyridines by using [Co(TPPASO
3
H)]Cl proceeded
via
a cooperative vinylogous anomeric based oxidation mechanism. [Co(TPPASO
3
H)]Cl can be recycled and reused six times with a marginal decreasing of its catalytic activity.
ortho
-Aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines were synthesized by [Co(TPPASO
3
H)]Cl as an efficient pyridiniumporphyrazinato based catalyst.</abstract><doi>10.1039/d0ra02172e</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | EISSN: 2046-2069 |
| ispartof | RSC advances, 2020-07, Vol.1 (46), p.27824-27834 |
| issn | 2046-2069 |
| language | eng |
| recordid | cdi_rsc_primary_d0ra02172e |
| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; PubMed Central Open Access |
| title | Synthesis of cobalt tetra-2,3-pyridiniumporphyrazinato with sulfonic acid tags as an efficient catalyst and its application for the synthesis of bicyclic -aminocarbonitriles, cyclohexa-1,3-dienamines and 2-amino-3-cyanopyridines |
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