Facile synthesis of a porous polynorbornene with an azobenzene subunit: selective adsorption of 4-nitrophenol over 4-aminophenol in water
This paper reports the design and facile synthesis of porous polynorbornenes containing a 4,4′-dialkoxy-azobenzene subunit (named Azo-POP-13 and Azo-POP-14). They were synthesized by the robust reductive azo-coupling polymerization of the Ring-Opening-Metathesis-Polymerization (ROMP) product on bis-...
Gespeichert in:
| Veröffentlicht in: | Polymer chemistry 2020-10, Vol.11 (4), p.6429-6434 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 6434 |
|---|---|
| container_issue | 4 |
| container_start_page | 6429 |
| container_title | Polymer chemistry |
| container_volume | 11 |
| creator | Peng, Shan-Qing Zhang, Butian Fan, Wenhao Wang, Shuifeng Zhang, Zhi-Hao Liu, Yan Chen, Shi-Lu Huang, Mu-Hua |
| description | This paper reports the design and facile synthesis of porous polynorbornenes containing a 4,4′-dialkoxy-azobenzene subunit (named Azo-POP-13 and Azo-POP-14). They were synthesized by the robust reductive azo-coupling polymerization of the Ring-Opening-Metathesis-Polymerization (ROMP) product on bis-
para
-nitrophenylether of the norbornene diol. The polymerization rate of
exo
-NBNPE (
k
app
= 18.7 × 10
−2
s
−1
) is faster than that of
endo
-NBNPE (
k
app
= 3.64 × 10
−2
s
−1
). The as-synthesized Azo-POP-13 was found to selectively adsorb 4-nitrophenol (4-NP) over 4-aminophenol (4-AP) in water, with a selectivity up to 14.6 and good recyclability.
The azo-linked porous polynorbornene was synthesized
via
the robust reductive azo-coupling and Ring-Opening-Metathesis-Polymerization (ROMP) polymerization, which selectively adsorbed 4-nitrophenol over 4-aminophenol in water. |
| doi_str_mv | 10.1039/d0py00994f |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_rsc_p</sourceid><recordid>TN_cdi_rsc_primary_d0py00994f</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2452009099</sourcerecordid><originalsourceid>FETCH-LOGICAL-c307t-44c73c7c4001148a1e169804d47c011886fe78414541257710b49094018aacca3</originalsourceid><addsrcrecordid>eNp9kcFLwzAUxoMoOOYu3oWIN6GatK9L402mU2GgBz14KmmasowuqUm70f0H_tdmTufNd3mP7_vxHnwPoVNKrihJ-HVJmp4QzqE6QAPKUh5xPo4P93MKx2jk_YKESijEyXiAPqdC6lph35t2rrz22FZY4MY62_nQ6t5YV1hnlFF4rds5FgaLjS2U2Wwl3xWd0e0N9qpWstUrhUXprWtabc12F0TBdraZK2NrbFfKBUkstfmVtMFr0Sp3go4qUXs1-ulD9Da9f508RrPnh6fJ7SySCWFtBCBZIpkEQiiFTFBFxzwjUAKTQcmycaVYBhRSoHHKGCUFcMKB0EwIKUUyRBe7vY2zH53ybb6wnTPhZB5DGocAQ4SButxR0lnvnaryxumlcH1OSb5NO78jL-_faU8DfLaDnZd77u8bwT__z8-bskq-AC4aiIo</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2452009099</pqid></control><display><type>article</type><title>Facile synthesis of a porous polynorbornene with an azobenzene subunit: selective adsorption of 4-nitrophenol over 4-aminophenol in water</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Peng, Shan-Qing ; Zhang, Butian ; Fan, Wenhao ; Wang, Shuifeng ; Zhang, Zhi-Hao ; Liu, Yan ; Chen, Shi-Lu ; Huang, Mu-Hua</creator><creatorcontrib>Peng, Shan-Qing ; Zhang, Butian ; Fan, Wenhao ; Wang, Shuifeng ; Zhang, Zhi-Hao ; Liu, Yan ; Chen, Shi-Lu ; Huang, Mu-Hua</creatorcontrib><description>This paper reports the design and facile synthesis of porous polynorbornenes containing a 4,4′-dialkoxy-azobenzene subunit (named Azo-POP-13 and Azo-POP-14). They were synthesized by the robust reductive azo-coupling polymerization of the Ring-Opening-Metathesis-Polymerization (ROMP) product on bis-
para
-nitrophenylether of the norbornene diol. The polymerization rate of
exo
-NBNPE (
k
app
= 18.7 × 10
−2
s
−1
) is faster than that of
endo
-NBNPE (
k
app
= 3.64 × 10
−2
s
−1
). The as-synthesized Azo-POP-13 was found to selectively adsorb 4-nitrophenol (4-NP) over 4-aminophenol (4-AP) in water, with a selectivity up to 14.6 and good recyclability.
The azo-linked porous polynorbornene was synthesized
via
the robust reductive azo-coupling and Ring-Opening-Metathesis-Polymerization (ROMP) polymerization, which selectively adsorbed 4-nitrophenol over 4-aminophenol in water.</description><identifier>ISSN: 1759-9954</identifier><identifier>EISSN: 1759-9962</identifier><identifier>DOI: 10.1039/d0py00994f</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Aminophenol ; Azo compounds ; Metathesis ; Nitrophenol ; Polymer chemistry ; Polymerization ; Polynorbornene ; Recyclability ; Ring opening polymerization ; Selective adsorption ; Selectivity</subject><ispartof>Polymer chemistry, 2020-10, Vol.11 (4), p.6429-6434</ispartof><rights>Copyright Royal Society of Chemistry 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c307t-44c73c7c4001148a1e169804d47c011886fe78414541257710b49094018aacca3</citedby><cites>FETCH-LOGICAL-c307t-44c73c7c4001148a1e169804d47c011886fe78414541257710b49094018aacca3</cites><orcidid>0000-0002-7187-9062 ; 0000-0002-3563-7381</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Peng, Shan-Qing</creatorcontrib><creatorcontrib>Zhang, Butian</creatorcontrib><creatorcontrib>Fan, Wenhao</creatorcontrib><creatorcontrib>Wang, Shuifeng</creatorcontrib><creatorcontrib>Zhang, Zhi-Hao</creatorcontrib><creatorcontrib>Liu, Yan</creatorcontrib><creatorcontrib>Chen, Shi-Lu</creatorcontrib><creatorcontrib>Huang, Mu-Hua</creatorcontrib><title>Facile synthesis of a porous polynorbornene with an azobenzene subunit: selective adsorption of 4-nitrophenol over 4-aminophenol in water</title><title>Polymer chemistry</title><description>This paper reports the design and facile synthesis of porous polynorbornenes containing a 4,4′-dialkoxy-azobenzene subunit (named Azo-POP-13 and Azo-POP-14). They were synthesized by the robust reductive azo-coupling polymerization of the Ring-Opening-Metathesis-Polymerization (ROMP) product on bis-
para
-nitrophenylether of the norbornene diol. The polymerization rate of
exo
-NBNPE (
k
app
= 18.7 × 10
−2
s
−1
) is faster than that of
endo
-NBNPE (
k
app
= 3.64 × 10
−2
s
−1
). The as-synthesized Azo-POP-13 was found to selectively adsorb 4-nitrophenol (4-NP) over 4-aminophenol (4-AP) in water, with a selectivity up to 14.6 and good recyclability.
The azo-linked porous polynorbornene was synthesized
via
the robust reductive azo-coupling and Ring-Opening-Metathesis-Polymerization (ROMP) polymerization, which selectively adsorbed 4-nitrophenol over 4-aminophenol in water.</description><subject>Aminophenol</subject><subject>Azo compounds</subject><subject>Metathesis</subject><subject>Nitrophenol</subject><subject>Polymer chemistry</subject><subject>Polymerization</subject><subject>Polynorbornene</subject><subject>Recyclability</subject><subject>Ring opening polymerization</subject><subject>Selective adsorption</subject><subject>Selectivity</subject><issn>1759-9954</issn><issn>1759-9962</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kcFLwzAUxoMoOOYu3oWIN6GatK9L402mU2GgBz14KmmasowuqUm70f0H_tdmTufNd3mP7_vxHnwPoVNKrihJ-HVJmp4QzqE6QAPKUh5xPo4P93MKx2jk_YKESijEyXiAPqdC6lph35t2rrz22FZY4MY62_nQ6t5YV1hnlFF4rds5FgaLjS2U2Wwl3xWd0e0N9qpWstUrhUXprWtabc12F0TBdraZK2NrbFfKBUkstfmVtMFr0Sp3go4qUXs1-ulD9Da9f508RrPnh6fJ7SySCWFtBCBZIpkEQiiFTFBFxzwjUAKTQcmycaVYBhRSoHHKGCUFcMKB0EwIKUUyRBe7vY2zH53ybb6wnTPhZB5DGocAQ4SButxR0lnvnaryxumlcH1OSb5NO78jL-_faU8DfLaDnZd77u8bwT__z8-bskq-AC4aiIo</recordid><startdate>20201028</startdate><enddate>20201028</enddate><creator>Peng, Shan-Qing</creator><creator>Zhang, Butian</creator><creator>Fan, Wenhao</creator><creator>Wang, Shuifeng</creator><creator>Zhang, Zhi-Hao</creator><creator>Liu, Yan</creator><creator>Chen, Shi-Lu</creator><creator>Huang, Mu-Hua</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-7187-9062</orcidid><orcidid>https://orcid.org/0000-0002-3563-7381</orcidid></search><sort><creationdate>20201028</creationdate><title>Facile synthesis of a porous polynorbornene with an azobenzene subunit: selective adsorption of 4-nitrophenol over 4-aminophenol in water</title><author>Peng, Shan-Qing ; Zhang, Butian ; Fan, Wenhao ; Wang, Shuifeng ; Zhang, Zhi-Hao ; Liu, Yan ; Chen, Shi-Lu ; Huang, Mu-Hua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c307t-44c73c7c4001148a1e169804d47c011886fe78414541257710b49094018aacca3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Aminophenol</topic><topic>Azo compounds</topic><topic>Metathesis</topic><topic>Nitrophenol</topic><topic>Polymer chemistry</topic><topic>Polymerization</topic><topic>Polynorbornene</topic><topic>Recyclability</topic><topic>Ring opening polymerization</topic><topic>Selective adsorption</topic><topic>Selectivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Peng, Shan-Qing</creatorcontrib><creatorcontrib>Zhang, Butian</creatorcontrib><creatorcontrib>Fan, Wenhao</creatorcontrib><creatorcontrib>Wang, Shuifeng</creatorcontrib><creatorcontrib>Zhang, Zhi-Hao</creatorcontrib><creatorcontrib>Liu, Yan</creatorcontrib><creatorcontrib>Chen, Shi-Lu</creatorcontrib><creatorcontrib>Huang, Mu-Hua</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Peng, Shan-Qing</au><au>Zhang, Butian</au><au>Fan, Wenhao</au><au>Wang, Shuifeng</au><au>Zhang, Zhi-Hao</au><au>Liu, Yan</au><au>Chen, Shi-Lu</au><au>Huang, Mu-Hua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Facile synthesis of a porous polynorbornene with an azobenzene subunit: selective adsorption of 4-nitrophenol over 4-aminophenol in water</atitle><jtitle>Polymer chemistry</jtitle><date>2020-10-28</date><risdate>2020</risdate><volume>11</volume><issue>4</issue><spage>6429</spage><epage>6434</epage><pages>6429-6434</pages><issn>1759-9954</issn><eissn>1759-9962</eissn><abstract>This paper reports the design and facile synthesis of porous polynorbornenes containing a 4,4′-dialkoxy-azobenzene subunit (named Azo-POP-13 and Azo-POP-14). They were synthesized by the robust reductive azo-coupling polymerization of the Ring-Opening-Metathesis-Polymerization (ROMP) product on bis-
para
-nitrophenylether of the norbornene diol. The polymerization rate of
exo
-NBNPE (
k
app
= 18.7 × 10
−2
s
−1
) is faster than that of
endo
-NBNPE (
k
app
= 3.64 × 10
−2
s
−1
). The as-synthesized Azo-POP-13 was found to selectively adsorb 4-nitrophenol (4-NP) over 4-aminophenol (4-AP) in water, with a selectivity up to 14.6 and good recyclability.
The azo-linked porous polynorbornene was synthesized
via
the robust reductive azo-coupling and Ring-Opening-Metathesis-Polymerization (ROMP) polymerization, which selectively adsorbed 4-nitrophenol over 4-aminophenol in water.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d0py00994f</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-7187-9062</orcidid><orcidid>https://orcid.org/0000-0002-3563-7381</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1759-9954 |
| ispartof | Polymer chemistry, 2020-10, Vol.11 (4), p.6429-6434 |
| issn | 1759-9954 1759-9962 |
| language | eng |
| recordid | cdi_rsc_primary_d0py00994f |
| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Aminophenol Azo compounds Metathesis Nitrophenol Polymer chemistry Polymerization Polynorbornene Recyclability Ring opening polymerization Selective adsorption Selectivity |
| title | Facile synthesis of a porous polynorbornene with an azobenzene subunit: selective adsorption of 4-nitrophenol over 4-aminophenol in water |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-25T13%3A06%3A39IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_rsc_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Facile%20synthesis%20of%20a%20porous%20polynorbornene%20with%20an%20azobenzene%20subunit:%20selective%20adsorption%20of%204-nitrophenol%20over%204-aminophenol%20in%20water&rft.jtitle=Polymer%20chemistry&rft.au=Peng,%20Shan-Qing&rft.date=2020-10-28&rft.volume=11&rft.issue=4&rft.spage=6429&rft.epage=6434&rft.pages=6429-6434&rft.issn=1759-9954&rft.eissn=1759-9962&rft_id=info:doi/10.1039/d0py00994f&rft_dat=%3Cproquest_rsc_p%3E2452009099%3C/proquest_rsc_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2452009099&rft_id=info:pmid/&rfr_iscdi=true |