Trapping of two mononuclear silyl platinum()/palladium() complexes and a unique dinuclear bis(μ-disilene)(silyl)nickel() complex

The reaction of chelating 1,2-disilyl hydrides with transition metal precursors featuring low steric hindrance phosphine ligands always produces multinuclear frameworks through mononuclear silyl metal intermediates. Capture of intermediates is very essential to clarify the formation mechanism and st...

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Veröffentlicht in:	New journal of chemistry 2020-12, Vol.44 (46), p.2351-2357
Hauptverfasser:	Song, Hao, Zhang, Sen-Yu, Gu, Peng-Fei, Wu, Hua-Yu, Wang, Zi-Kun, Wang, Shi, Wang, Zheng, Gu, Yu-Yang, Li, Yong-Hua
Format:	Artikel
Sprache:	eng
Schlagworte:	Chelation Crystallography Nickel Palladium Phosphines Platinum Steric hindrance Transition metals Trapping
Online-Zugang:	Volltext
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