Organically templated zinc selenite compounds: synthesis, structural chemistry and DFT calculations

Organically templated zinc selenite compounds: synthesis, structural chemistry and DFT calculations

Novel tetranuclear zinc compounds, [Zn 4 (μ-SeO 3 ) 2 (μ 4 -SeO 3 ) 2 (bipy) 4 ]·11H 2 O ( 1 ) and [Zn 4 (μ-SeO 3 ) 2 (μ 4 -SeO 3 ) 2 (phen) 4 ]·9H 2 O ( 2 ), which are the first examples of organically templated zinc selenite compounds containing closed-frameworks, have been synthesized via solvoth...

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Veröffentlicht in:New journal of chemistry 2020-05, Vol.44 (17), p.6699-673
Hauptverfasser: Lunardi, Andressa, Nunes Cechin, Camila, Lang, Ernesto Schulz, Cargnelutti, Roberta, Ramirez Pineda, Nahum, Piquini, Paulo Cesar, Burrow, Robert Alan, Santos dos Santos, Sailer, Bortolotto, Tanize, Tirloni, Bárbara
Format: Artikel
Sprache:eng
Schlagworte:
Chemical synthesis
Chemistry
Chemistry, Multidisciplinary
Crystallography
Mathematical analysis
Physical Sciences
Science & Technology
Zinc compounds
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Zusammenfassung:Novel tetranuclear zinc compounds, [Zn 4 (μ-SeO 3 ) 2 (μ 4 -SeO 3 ) 2 (bipy) 4 ]·11H 2 O ( 1 ) and [Zn 4 (μ-SeO 3 ) 2 (μ 4 -SeO 3 ) 2 (phen) 4 ]·9H 2 O ( 2 ), which are the first examples of organically templated zinc selenite compounds containing closed-frameworks, have been synthesized via solvothermal processes. The compounds were characterized by spectroscopy, crystallographic methods and DFT calculations. The first examples of organically templated zinc selenite compounds containing closed-frameworks have been synthesized via solvothermal processes and characterized by spectroscopy, crystallographic methods and DFT calculations.
ISSN:1144-0546
1369-9261
DOI:10.1039/d0nj00343c