Atomic emission spectrometry analysis of metals and alloys using a two-jet arc plasma with spark sampling and calibration by solutions
The analytical capabilities of the method of atomic emission spectrometry on a two-jet arc plasma (TJP-OES) with the use of spark ablation and calibration using standard solutions are evaluated. Optimization of the conditions for the injection of solutions into the plasma of a two-jet arc plasmatron...
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| Veröffentlicht in: | Journal of analytical atomic spectrometry 2021-04, Vol.36 (4), p.829-835 |
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| container_title | Journal of analytical atomic spectrometry |
| container_volume | 36 |
| creator | Kuptsov, A. V Volzhenin, A. V Labusov, V. A Saprykin, A. I |
| description | The analytical capabilities of the method of atomic emission spectrometry on a two-jet arc plasma (TJP-OES) with the use of spark ablation and calibration using standard solutions are evaluated. Optimization of the conditions for the injection of solutions into the plasma of a two-jet arc plasmatron has been carried out. The effect of the concentration of matrix elements on the signal-to-background ratio was studied when solutions were injected into the plasma. Calibration was carried out using the coefficients of relative sensitivity factors and standard solutions. The use of spectral lines of analytes and an internal standard with similar energy characteristics made it possible to achieve accurate and reproducible results in determination of impurities in steel and copper samples.
For the first time, the injection of solutions into the plasma of a two-jet arc plasmatron was used for the analysis of metals and alloys. Tandem calibration was used for quantitative chemical analysis by the TJP-AES method. |
| doi_str_mv | 10.1039/d0ja00429d |
| format | Article |
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| identifier | ISSN: 0267-9477 |
| ispartof | Journal of analytical atomic spectrometry, 2021-04, Vol.36 (4), p.829-835 |
| issn | 0267-9477 1364-5544 |
| language | eng |
| recordid | cdi_rsc_primary_d0ja00429d |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Ablation Calibration Emission analysis Line spectra Mathematical analysis Optimization Plasma Scientific imaging Spectrometry Spectroscopy |
| title | Atomic emission spectrometry analysis of metals and alloys using a two-jet arc plasma with spark sampling and calibration by solutions |
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