Solvolysis of benzyl phenyl ether in high-temperature aqueous methanol solution under high-pressure carbon dioxide
Alcoholysis of benzyl phenyl ether to various aromatic compounds was studied in high-temperature aqueous methanol solution under high-pressure carbon dioxide conditions. The products formed included benzyl methyl ether, benzyl alcohol, phenol and toluene. As high as 70.7 ± 0.2% yield of monocyclic a...
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| Veröffentlicht in: | Green chemistry : an international journal and green chemistry resource : GC 2021-01, Vol.23 (4), p.1658-1664 |
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| container_title | Green chemistry : an international journal and green chemistry resource : GC |
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| creator | Taniguchi, Kenkichi Nanao, Hidetaka Sato, Osamu Yamaguchi, Aritomo Shirai, Masayuki |
| description | Alcoholysis of benzyl phenyl ether to various aromatic compounds was studied in high-temperature aqueous methanol solution under high-pressure carbon dioxide conditions. The products formed included benzyl methyl ether, benzyl alcohol, phenol and toluene. As high as 70.7 ± 0.2% yield of monocyclic aromatic hydrocarbon with 16.1 ± 0.3% yield of benzyl methyl ether was obtained by treating benzyl phenyl ether with an aqueous solution with 0.2 molar fraction of methanol, under 17.7 MPa carbon dioxide for 1 h at 573 K.
Alcoholysis of benzyl phenyl ether to various aromatic compounds was studied in high-temperature aqueous methanol solution under high-pressure carbon dioxide conditions. |
| doi_str_mv | 10.1039/d0gc04008h |
| format | Article |
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Alcoholysis of benzyl phenyl ether to various aromatic compounds was studied in high-temperature aqueous methanol solution under high-pressure carbon dioxide conditions.</description><identifier>ISSN: 1463-9262</identifier><identifier>EISSN: 1463-9270</identifier><identifier>DOI: 10.1039/d0gc04008h</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Alcoholysis ; Aqueous solutions ; Aromatic compounds ; Aromatic hydrocarbons ; Benzyl alcohol ; Benzyl phenyl ether ; Carbon dioxide ; Green chemistry ; High temperature ; Methanol ; Phenols ; Solvolysis ; Toluene</subject><ispartof>Green chemistry : an international journal and green chemistry resource : GC, 2021-01, Vol.23 (4), p.1658-1664</ispartof><rights>Copyright Royal Society of Chemistry 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c420t-4f46bc7b33881077abeb99e01f09446a129a29762a9c454a4add07c63ceecccc3</citedby><cites>FETCH-LOGICAL-c420t-4f46bc7b33881077abeb99e01f09446a129a29762a9c454a4add07c63ceecccc3</cites><orcidid>0000-0001-9115-8150 ; 0000-0002-8649-304X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Taniguchi, Kenkichi</creatorcontrib><creatorcontrib>Nanao, Hidetaka</creatorcontrib><creatorcontrib>Sato, Osamu</creatorcontrib><creatorcontrib>Yamaguchi, Aritomo</creatorcontrib><creatorcontrib>Shirai, Masayuki</creatorcontrib><title>Solvolysis of benzyl phenyl ether in high-temperature aqueous methanol solution under high-pressure carbon dioxide</title><title>Green chemistry : an international journal and green chemistry resource : GC</title><description>Alcoholysis of benzyl phenyl ether to various aromatic compounds was studied in high-temperature aqueous methanol solution under high-pressure carbon dioxide conditions. The products formed included benzyl methyl ether, benzyl alcohol, phenol and toluene. As high as 70.7 ± 0.2% yield of monocyclic aromatic hydrocarbon with 16.1 ± 0.3% yield of benzyl methyl ether was obtained by treating benzyl phenyl ether with an aqueous solution with 0.2 molar fraction of methanol, under 17.7 MPa carbon dioxide for 1 h at 573 K.
Alcoholysis of benzyl phenyl ether to various aromatic compounds was studied in high-temperature aqueous methanol solution under high-pressure carbon dioxide conditions.</description><subject>Alcoholysis</subject><subject>Aqueous solutions</subject><subject>Aromatic compounds</subject><subject>Aromatic hydrocarbons</subject><subject>Benzyl alcohol</subject><subject>Benzyl phenyl ether</subject><subject>Carbon dioxide</subject><subject>Green chemistry</subject><subject>High temperature</subject><subject>Methanol</subject><subject>Phenols</subject><subject>Solvolysis</subject><subject>Toluene</subject><issn>1463-9262</issn><issn>1463-9270</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpFkNFLwzAQxoMoOKcvvgsB34TqpcmS5VGmbsLAB_W5pOl17eiamrTi_OvNnMx7-Q7u990dHyGXDG4ZcH1XwMqCAJhWR2TEhOSJThUcH3qZnpKzENYAjCkpRsS_uubTNdtQB-pKmmP7vW1oV2EbBfsKPa1bWtWrKulx06E3_eCRmo8B3RDoJiKmdQ0Nrhn62rV0aIvo-TV0HkPY0db4PI6K2n3VBZ6Tk9I0AS_-dEzenx7fZotk-TJ_nt0vEytS6BNRCplblXM-nTJQyuSYa43AStBCSMNSbVKtZGq0FRNhhCkKUFZyi2hj8TG53u_tvIvvhj5bu8G38WSWCi0YZ3qiInWzp6x3IXgss87XG-O3GYNsl2n2APPZb6aLCF_tYR_sgfvPnP8Agix2Aw</recordid><startdate>20210101</startdate><enddate>20210101</enddate><creator>Taniguchi, Kenkichi</creator><creator>Nanao, Hidetaka</creator><creator>Sato, Osamu</creator><creator>Yamaguchi, Aritomo</creator><creator>Shirai, Masayuki</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7ST</scope><scope>7U6</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-9115-8150</orcidid><orcidid>https://orcid.org/0000-0002-8649-304X</orcidid></search><sort><creationdate>20210101</creationdate><title>Solvolysis of benzyl phenyl ether in high-temperature aqueous methanol solution under high-pressure carbon dioxide</title><author>Taniguchi, Kenkichi ; Nanao, Hidetaka ; Sato, Osamu ; Yamaguchi, Aritomo ; Shirai, Masayuki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c420t-4f46bc7b33881077abeb99e01f09446a129a29762a9c454a4add07c63ceecccc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Alcoholysis</topic><topic>Aqueous solutions</topic><topic>Aromatic compounds</topic><topic>Aromatic hydrocarbons</topic><topic>Benzyl alcohol</topic><topic>Benzyl phenyl ether</topic><topic>Carbon dioxide</topic><topic>Green chemistry</topic><topic>High temperature</topic><topic>Methanol</topic><topic>Phenols</topic><topic>Solvolysis</topic><topic>Toluene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Taniguchi, Kenkichi</creatorcontrib><creatorcontrib>Nanao, Hidetaka</creatorcontrib><creatorcontrib>Sato, Osamu</creatorcontrib><creatorcontrib>Yamaguchi, Aritomo</creatorcontrib><creatorcontrib>Shirai, Masayuki</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Taniguchi, Kenkichi</au><au>Nanao, Hidetaka</au><au>Sato, Osamu</au><au>Yamaguchi, Aritomo</au><au>Shirai, Masayuki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solvolysis of benzyl phenyl ether in high-temperature aqueous methanol solution under high-pressure carbon dioxide</atitle><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle><date>2021-01-01</date><risdate>2021</risdate><volume>23</volume><issue>4</issue><spage>1658</spage><epage>1664</epage><pages>1658-1664</pages><issn>1463-9262</issn><eissn>1463-9270</eissn><abstract>Alcoholysis of benzyl phenyl ether to various aromatic compounds was studied in high-temperature aqueous methanol solution under high-pressure carbon dioxide conditions. The products formed included benzyl methyl ether, benzyl alcohol, phenol and toluene. As high as 70.7 ± 0.2% yield of monocyclic aromatic hydrocarbon with 16.1 ± 0.3% yield of benzyl methyl ether was obtained by treating benzyl phenyl ether with an aqueous solution with 0.2 molar fraction of methanol, under 17.7 MPa carbon dioxide for 1 h at 573 K.
Alcoholysis of benzyl phenyl ether to various aromatic compounds was studied in high-temperature aqueous methanol solution under high-pressure carbon dioxide conditions.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d0gc04008h</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0001-9115-8150</orcidid><orcidid>https://orcid.org/0000-0002-8649-304X</orcidid><oa>free_for_read</oa></addata></record> |
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| identifier | ISSN: 1463-9262 |
| ispartof | Green chemistry : an international journal and green chemistry resource : GC, 2021-01, Vol.23 (4), p.1658-1664 |
| issn | 1463-9262 1463-9270 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Alcoholysis Aqueous solutions Aromatic compounds Aromatic hydrocarbons Benzyl alcohol Benzyl phenyl ether Carbon dioxide Green chemistry High temperature Methanol Phenols Solvolysis Toluene |
| title | Solvolysis of benzyl phenyl ether in high-temperature aqueous methanol solution under high-pressure carbon dioxide |
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