A porous Zn()-coordination polymer based on a tetracarboxylic acid exhibiting selective CO adsorption and iodine uptake
A porous Zn( ii )-coordination polymer, namely {[Zn 2 (μ 8 -abtc)(betib)]·DMF} n ( 1 ), was solvothermally synthesized from 3,3′,5,5′-azobenzenetetracarboxylate (abtc 4− ) and 1,4-bis(2-ethylimidazol-1-yl)butane (betib) ligands and {[Zn 2 (μ 8 -abtc)(betib)]·H 2 O} n ( 2 ) was obtained through the i...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2020-08, Vol.49 (31), p.1824-1831 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Arici, Mürsel Alp Arici, Tu ba Demiral, Hakan Ta, Murat Ye ilel, Okan Zafer |
| description | A porous Zn(
ii
)-coordination polymer, namely {[Zn
2
(μ
8
-abtc)(betib)]·DMF}
n
(
1
), was solvothermally synthesized from 3,3′,5,5′-azobenzenetetracarboxylate (abtc
4−
) and 1,4-bis(2-ethylimidazol-1-yl)butane (betib) ligands and {[Zn
2
(μ
8
-abtc)(betib)]·H
2
O}
n
(
2
) was obtained through the immersion of
1
in methanol. Compounds
1
and
2
were structurally characterized
via
numerous techniques. Both compounds displayed a 3D porous framework with a 3,6-connected sqc5381 net. Compound
2a
obtained at 140 °C from
2
exhibited gas and iodine adsorption properties. Interestingly, the compound adsorbed selectively CO
2
with the uptake capacity of 54.02 cm
3
g
−1
(13.26%) over N
2
(5.43 cm
3
g
−1
) and CH
4
(14.53 cm
3
g
−1
) at 273 K. The compound also adsorbed iodine with the weights of 19.99% and 30.26% in solution and vapor phases, respectively. The single crystal X-ray result and Raman spectra showed the presence of iodine units in the pores of the framework.
A 3D porous Zn(
ii
)-coordination polymer with a sqc5381 net adsorbed selectively CO
2
over N
2
and CH
4
at 273 K and also 19.99% and 30.26% iodine in solution and vapor phase. X-ray result and Raman spectra showed iodine units in the pores of framework. |
| doi_str_mv | 10.1039/d0dt01875a |
| format | Article |
| fullrecord | <record><control><sourceid>rsc</sourceid><recordid>TN_cdi_rsc_primary_d0dt01875a</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>d0dt01875a</sourcerecordid><originalsourceid>FETCH-rsc_primary_d0dt01875a3</originalsourceid><addsrcrecordid>eNqFjzFPwzAQhS0EEqV0YUc6NhgCjtMSOqIKxMbCxBJd7Gs5SG3r7NLm3xOhCjaY3tP7pE96Sp2V-rrU1fzGaZd1eVfP8ECNymldF3NTTQ9_urk9VicpvWttjJ6ZkdreQwwSNgle_eVVYUMQxx4zBz-Arl-TQIuJHAwDQqYsaFHasOs7toCWHdDujVvO7FeQqCOb-ZNg8QzoUpD4rULvgMNgJtjEjB90qo6W2CWa7HOszh8fXhZPhSTbROE1St_8vqnG6uIv3kS3rP5zfAHqiVrh</addsrcrecordid><sourcetype>Enrichment Source</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>A porous Zn()-coordination polymer based on a tetracarboxylic acid exhibiting selective CO adsorption and iodine uptake</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Arici, Mürsel ; Alp Arici, Tu ba ; Demiral, Hakan ; Ta, Murat ; Ye ilel, Okan Zafer</creator><creatorcontrib>Arici, Mürsel ; Alp Arici, Tu ba ; Demiral, Hakan ; Ta, Murat ; Ye ilel, Okan Zafer</creatorcontrib><description>A porous Zn(
ii
)-coordination polymer, namely {[Zn
2
(μ
8
-abtc)(betib)]·DMF}
n
(
1
), was solvothermally synthesized from 3,3′,5,5′-azobenzenetetracarboxylate (abtc
4−
) and 1,4-bis(2-ethylimidazol-1-yl)butane (betib) ligands and {[Zn
2
(μ
8
-abtc)(betib)]·H
2
O}
n
(
2
) was obtained through the immersion of
1
in methanol. Compounds
1
and
2
were structurally characterized
via
numerous techniques. Both compounds displayed a 3D porous framework with a 3,6-connected sqc5381 net. Compound
2a
obtained at 140 °C from
2
exhibited gas and iodine adsorption properties. Interestingly, the compound adsorbed selectively CO
2
with the uptake capacity of 54.02 cm
3
g
−1
(13.26%) over N
2
(5.43 cm
3
g
−1
) and CH
4
(14.53 cm
3
g
−1
) at 273 K. The compound also adsorbed iodine with the weights of 19.99% and 30.26% in solution and vapor phases, respectively. The single crystal X-ray result and Raman spectra showed the presence of iodine units in the pores of the framework.
A 3D porous Zn(
ii
)-coordination polymer with a sqc5381 net adsorbed selectively CO
2
over N
2
and CH
4
at 273 K and also 19.99% and 30.26% iodine in solution and vapor phase. X-ray result and Raman spectra showed iodine units in the pores of framework.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d0dt01875a</identifier><language>eng</language><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2020-08, Vol.49 (31), p.1824-1831</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Arici, Mürsel</creatorcontrib><creatorcontrib>Alp Arici, Tu ba</creatorcontrib><creatorcontrib>Demiral, Hakan</creatorcontrib><creatorcontrib>Ta, Murat</creatorcontrib><creatorcontrib>Ye ilel, Okan Zafer</creatorcontrib><title>A porous Zn()-coordination polymer based on a tetracarboxylic acid exhibiting selective CO adsorption and iodine uptake</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>A porous Zn(
ii
)-coordination polymer, namely {[Zn
2
(μ
8
-abtc)(betib)]·DMF}
n
(
1
), was solvothermally synthesized from 3,3′,5,5′-azobenzenetetracarboxylate (abtc
4−
) and 1,4-bis(2-ethylimidazol-1-yl)butane (betib) ligands and {[Zn
2
(μ
8
-abtc)(betib)]·H
2
O}
n
(
2
) was obtained through the immersion of
1
in methanol. Compounds
1
and
2
were structurally characterized
via
numerous techniques. Both compounds displayed a 3D porous framework with a 3,6-connected sqc5381 net. Compound
2a
obtained at 140 °C from
2
exhibited gas and iodine adsorption properties. Interestingly, the compound adsorbed selectively CO
2
with the uptake capacity of 54.02 cm
3
g
−1
(13.26%) over N
2
(5.43 cm
3
g
−1
) and CH
4
(14.53 cm
3
g
−1
) at 273 K. The compound also adsorbed iodine with the weights of 19.99% and 30.26% in solution and vapor phases, respectively. The single crystal X-ray result and Raman spectra showed the presence of iodine units in the pores of the framework.
A 3D porous Zn(
ii
)-coordination polymer with a sqc5381 net adsorbed selectively CO
2
over N
2
and CH
4
at 273 K and also 19.99% and 30.26% iodine in solution and vapor phase. X-ray result and Raman spectra showed iodine units in the pores of framework.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjzFPwzAQhS0EEqV0YUc6NhgCjtMSOqIKxMbCxBJd7Gs5SG3r7NLm3xOhCjaY3tP7pE96Sp2V-rrU1fzGaZd1eVfP8ECNymldF3NTTQ9_urk9VicpvWttjJ6ZkdreQwwSNgle_eVVYUMQxx4zBz-Arl-TQIuJHAwDQqYsaFHasOs7toCWHdDujVvO7FeQqCOb-ZNg8QzoUpD4rULvgMNgJtjEjB90qo6W2CWa7HOszh8fXhZPhSTbROE1St_8vqnG6uIv3kS3rP5zfAHqiVrh</recordid><startdate>20200811</startdate><enddate>20200811</enddate><creator>Arici, Mürsel</creator><creator>Alp Arici, Tu ba</creator><creator>Demiral, Hakan</creator><creator>Ta, Murat</creator><creator>Ye ilel, Okan Zafer</creator><scope/></search><sort><creationdate>20200811</creationdate><title>A porous Zn()-coordination polymer based on a tetracarboxylic acid exhibiting selective CO adsorption and iodine uptake</title><author>Arici, Mürsel ; Alp Arici, Tu ba ; Demiral, Hakan ; Ta, Murat ; Ye ilel, Okan Zafer</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d0dt01875a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Arici, Mürsel</creatorcontrib><creatorcontrib>Alp Arici, Tu ba</creatorcontrib><creatorcontrib>Demiral, Hakan</creatorcontrib><creatorcontrib>Ta, Murat</creatorcontrib><creatorcontrib>Ye ilel, Okan Zafer</creatorcontrib><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Arici, Mürsel</au><au>Alp Arici, Tu ba</au><au>Demiral, Hakan</au><au>Ta, Murat</au><au>Ye ilel, Okan Zafer</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A porous Zn()-coordination polymer based on a tetracarboxylic acid exhibiting selective CO adsorption and iodine uptake</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2020-08-11</date><risdate>2020</risdate><volume>49</volume><issue>31</issue><spage>1824</spage><epage>1831</epage><pages>1824-1831</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A porous Zn(
ii
)-coordination polymer, namely {[Zn
2
(μ
8
-abtc)(betib)]·DMF}
n
(
1
), was solvothermally synthesized from 3,3′,5,5′-azobenzenetetracarboxylate (abtc
4−
) and 1,4-bis(2-ethylimidazol-1-yl)butane (betib) ligands and {[Zn
2
(μ
8
-abtc)(betib)]·H
2
O}
n
(
2
) was obtained through the immersion of
1
in methanol. Compounds
1
and
2
were structurally characterized
via
numerous techniques. Both compounds displayed a 3D porous framework with a 3,6-connected sqc5381 net. Compound
2a
obtained at 140 °C from
2
exhibited gas and iodine adsorption properties. Interestingly, the compound adsorbed selectively CO
2
with the uptake capacity of 54.02 cm
3
g
−1
(13.26%) over N
2
(5.43 cm
3
g
−1
) and CH
4
(14.53 cm
3
g
−1
) at 273 K. The compound also adsorbed iodine with the weights of 19.99% and 30.26% in solution and vapor phases, respectively. The single crystal X-ray result and Raman spectra showed the presence of iodine units in the pores of the framework.
A 3D porous Zn(
ii
)-coordination polymer with a sqc5381 net adsorbed selectively CO
2
over N
2
and CH
4
at 273 K and also 19.99% and 30.26% iodine in solution and vapor phase. X-ray result and Raman spectra showed iodine units in the pores of framework.</abstract><doi>10.1039/d0dt01875a</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2020-08, Vol.49 (31), p.1824-1831 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_rsc_primary_d0dt01875a |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | A porous Zn()-coordination polymer based on a tetracarboxylic acid exhibiting selective CO adsorption and iodine uptake |
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