Li(SeO)(HO)·CuCl, a salt-inclusion diselenite structurally based on tetranuclear Li complexes
A new lithium copper diselenite chloride hydrate, Li 2 Se 2 O 5 (H 2 O) 1.5 ·CuCl 2 , was prepared from aqueous solution. Its unique 2D structure can be interpreted as Li 2 Se 2 O 5 (H 2 O) 1.5 layers with CuCl 2 hosts embedded in the interlayer space, and be considered halfway between the salt-incl...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2020-06, Vol.49 (23), p.779-7795 |
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| container_issue | 23 |
| container_start_page | 779 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 49 |
| creator | Markovski, Mishel R Siidra, Oleg I Charkin, Dmitri O Vladimirova, Victoria A Tsirlin, Alexander A Grishaev, Vasili Yu |
| description | A new lithium copper diselenite chloride hydrate, Li
2
Se
2
O
5
(H
2
O)
1.5
·CuCl
2
, was prepared from aqueous solution. Its unique 2D structure can be interpreted as Li
2
Se
2
O
5
(H
2
O)
1.5
layers with CuCl
2
hosts embedded in the interlayer space, and be considered halfway between the salt-inclusion and host-guest structures. The CuO
2
Cl
4
octahedra form chains similar to those in CuCl
2
·2H
2
O, yet water molecules are coordinated exclusively to Li
+
while Se
2
O
5
2−
and Cl
−
bridge Li
+
and Cu
2+
. The complexity of the structure is likely responsible for both very long pre-crystallization time and non-existence of the corresponding bromide analogue. Despite the relatively long Cu Cu separations, the compound exhibits weak ferromagnetic interactions along the chains of CuO
2
Cl
4
octahedra.
A new lithium copper diselenite chloride hydrate, Li
2
Se
2
O
5
(H
2
O)
1.5
·CuCl
2
, was prepared from aqueous solution. |
| doi_str_mv | 10.1039/d0dt01260b |
| format | Article |
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2
Se
2
O
5
(H
2
O)
1.5
·CuCl
2
, was prepared from aqueous solution. Its unique 2D structure can be interpreted as Li
2
Se
2
O
5
(H
2
O)
1.5
layers with CuCl
2
hosts embedded in the interlayer space, and be considered halfway between the salt-inclusion and host-guest structures. The CuO
2
Cl
4
octahedra form chains similar to those in CuCl
2
·2H
2
O, yet water molecules are coordinated exclusively to Li
+
while Se
2
O
5
2−
and Cl
−
bridge Li
+
and Cu
2+
. The complexity of the structure is likely responsible for both very long pre-crystallization time and non-existence of the corresponding bromide analogue. Despite the relatively long Cu Cu separations, the compound exhibits weak ferromagnetic interactions along the chains of CuO
2
Cl
4
octahedra.
A new lithium copper diselenite chloride hydrate, Li
2
Se
2
O
5
(H
2
O)
1.5
·CuCl
2
, was prepared from aqueous solution.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d0dt01260b</identifier><language>eng</language><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2020-06, Vol.49 (23), p.779-7795</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Markovski, Mishel R</creatorcontrib><creatorcontrib>Siidra, Oleg I</creatorcontrib><creatorcontrib>Charkin, Dmitri O</creatorcontrib><creatorcontrib>Vladimirova, Victoria A</creatorcontrib><creatorcontrib>Tsirlin, Alexander A</creatorcontrib><creatorcontrib>Grishaev, Vasili Yu</creatorcontrib><title>Li(SeO)(HO)·CuCl, a salt-inclusion diselenite structurally based on tetranuclear Li complexes</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>A new lithium copper diselenite chloride hydrate, Li
2
Se
2
O
5
(H
2
O)
1.5
·CuCl
2
, was prepared from aqueous solution. Its unique 2D structure can be interpreted as Li
2
Se
2
O
5
(H
2
O)
1.5
layers with CuCl
2
hosts embedded in the interlayer space, and be considered halfway between the salt-inclusion and host-guest structures. The CuO
2
Cl
4
octahedra form chains similar to those in CuCl
2
·2H
2
O, yet water molecules are coordinated exclusively to Li
+
while Se
2
O
5
2−
and Cl
−
bridge Li
+
and Cu
2+
. The complexity of the structure is likely responsible for both very long pre-crystallization time and non-existence of the corresponding bromide analogue. Despite the relatively long Cu Cu separations, the compound exhibits weak ferromagnetic interactions along the chains of CuO
2
Cl
4
octahedra.
A new lithium copper diselenite chloride hydrate, Li
2
Se
2
O
5
(H
2
O)
1.5
·CuCl
2
, was prepared from aqueous solution.</description><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqFjrsKAjEQRYMo-GzshdgpuJrN-sB6USwEC61dYjJCZFyXTAL6ZfZ-mRainVbnwrnFYawdi2EskvnICONFLKfiUGK1eDybRXOZjMufLadVVic6CSGlmMga269tbwubfm-16T_uaUhxwBUnhT6yucZA9pJzYwkQcuuBk3dB--AU4o0fFIHhr4MH71QeNIJyfG25vpwLhCtQk1WOCglabzZYZ7nYpavIkc4KZ8_K3bJvdPLfd3_5rDDH5AmAfVFr</recordid><startdate>20200616</startdate><enddate>20200616</enddate><creator>Markovski, Mishel R</creator><creator>Siidra, Oleg I</creator><creator>Charkin, Dmitri O</creator><creator>Vladimirova, Victoria A</creator><creator>Tsirlin, Alexander A</creator><creator>Grishaev, Vasili Yu</creator><scope/></search><sort><creationdate>20200616</creationdate><title>Li(SeO)(HO)·CuCl, a salt-inclusion diselenite structurally based on tetranuclear Li complexes</title><author>Markovski, Mishel R ; Siidra, Oleg I ; Charkin, Dmitri O ; Vladimirova, Victoria A ; Tsirlin, Alexander A ; Grishaev, Vasili Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-rsc_primary_d0dt01260b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Markovski, Mishel R</creatorcontrib><creatorcontrib>Siidra, Oleg I</creatorcontrib><creatorcontrib>Charkin, Dmitri O</creatorcontrib><creatorcontrib>Vladimirova, Victoria A</creatorcontrib><creatorcontrib>Tsirlin, Alexander A</creatorcontrib><creatorcontrib>Grishaev, Vasili Yu</creatorcontrib><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Markovski, Mishel R</au><au>Siidra, Oleg I</au><au>Charkin, Dmitri O</au><au>Vladimirova, Victoria A</au><au>Tsirlin, Alexander A</au><au>Grishaev, Vasili Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Li(SeO)(HO)·CuCl, a salt-inclusion diselenite structurally based on tetranuclear Li complexes</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2020-06-16</date><risdate>2020</risdate><volume>49</volume><issue>23</issue><spage>779</spage><epage>7795</epage><pages>779-7795</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A new lithium copper diselenite chloride hydrate, Li
2
Se
2
O
5
(H
2
O)
1.5
·CuCl
2
, was prepared from aqueous solution. Its unique 2D structure can be interpreted as Li
2
Se
2
O
5
(H
2
O)
1.5
layers with CuCl
2
hosts embedded in the interlayer space, and be considered halfway between the salt-inclusion and host-guest structures. The CuO
2
Cl
4
octahedra form chains similar to those in CuCl
2
·2H
2
O, yet water molecules are coordinated exclusively to Li
+
while Se
2
O
5
2−
and Cl
−
bridge Li
+
and Cu
2+
. The complexity of the structure is likely responsible for both very long pre-crystallization time and non-existence of the corresponding bromide analogue. Despite the relatively long Cu Cu separations, the compound exhibits weak ferromagnetic interactions along the chains of CuO
2
Cl
4
octahedra.
A new lithium copper diselenite chloride hydrate, Li
2
Se
2
O
5
(H
2
O)
1.5
·CuCl
2
, was prepared from aqueous solution.</abstract><doi>10.1039/d0dt01260b</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2020-06, Vol.49 (23), p.779-7795 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_rsc_primary_d0dt01260b |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Li(SeO)(HO)·CuCl, a salt-inclusion diselenite structurally based on tetranuclear Li complexes |
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